(a) Interpretation: The given compounds are to be labeled as chiral or achiral. Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Question

יווי 10 20 30 40 50 60 70 3.5 3 2.5 2 1.5 1 [ppm] 3.5 3 2.5 2 1.5 1 6 [ppm] 1 1.5 -2.5 3.5

Answer 1

Question

Chapter 5, Problem 5.72P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

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יווי 10 20 30 40 50 60 70 3.5 3 2.5 2 1.5 1 [ppm] 3.5 3 2.5 2 1.5 1 6 [ppm] 1 1.5 -2.5 3.5

2H2S(g)+3O2(g)→2SO2(g)+2H2O(g) A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion. Question Which of the following predicts the theoretical yield of SO2(g) from the reaction? Responses 1.2 g Answer A: 1.2 grams A 41 g Answer B: 41 grams B 77 g Answer C: 77 grams C 154 g Answer D: 154 grams D

Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Answer 2

Question

Chapter 5, Problem 5.72P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

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Answer 3

Question

Chapter 5, Problem 5.72P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

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Answer 4

Question

Chapter 5, Problem 5.72P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

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Answer 5

Chapter 5, Problem 5.72P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Answer 6

Chapter 5, Problem 5.72P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Answer 7

Chapter 5, Problem 5.72P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Answer 10

Interpretation Introduction

(c)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Answer 11

Interpretation Introduction

(c)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Answer 12

Interpretation Introduction

(d)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Answer 13

Interpretation Introduction

(d)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Answer 14

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Answer 15

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Answer 25

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Draw the mirror image of each compound. Label each...Ch. 5 - Prob. 5.4P Ch. 5 - A molecule is achiral if it has a plane of...Ch. 5 - Problem 5.6 Locate the stereogenic centers in each...Ch. 5 - The facts in section 5.4A can be used to locate...Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

(a) Interpretation: The given compounds are to be labeled as chiral or achiral. Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Solution Summary: The author explains that the organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds.

(a)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

(b)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

(c)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

(d)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Chapter 5 Solutions

(a) Interpretation: The given compounds are to be labeled as chiral or achiral. Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Solution Summary: The author explains that the organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds.

(a) Interpretation: The given compounds are to be labeled as chiral or achiral. Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

(b) Interpretation: The given compounds are to be labeled as chiral or achiral. Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

(c) Interpretation: The given compounds are to be labeled as chiral or achiral. Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

(d) Interpretation: The given compounds are to be labeled as chiral or achiral. Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

Chapter 5 Solutions

(a)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

(b)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

(c)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.

(d)

Interpretation: The given compounds are to be labeled as chiral or achiral.

Concept introduction: The organic compounds in which two rings are bonded to each other through one carbon atom are known as spiro compounds. The asymmetrically substituted spiro carbons show chiral nature.