The improvement in S/N in progressing from spectrum A to spectrum D in figure 5-15 needs to be calculated. Concept introduction: Signal-to-noise ratio (S/N) is a scale used in engineering and science to compare the level of the signal to the background noise. It is defined as ratio of power of signal to the noise and it is expressed in decibels.

Question

It is not unexpected that the methoxyl substituent on a cyclohexane ring prefers to adopt the equatorial conformation. OMe H A G₂ = +0.6 kcal/mol OMe What is unexpected is that the closely related 2-methoxytetrahydropyran prefers the axial conformation: H H OMe OMe A Gp=-0.6 kcal/mol Methoxy: CH3O group Please be specific and clearly write the reason why this is observed. This effect that provides stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO interacting with anti-bonding MO...]

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Question

Chapter 5, Problem 5.12QAP

Interpretation Introduction

Interpretation:

The improvement in S/N in progressing from spectrum A to spectrum D in figure 5-15 needs to be calculated.

Concept introduction:

Signal-to-noise ratio (S/N) is a scale used in engineering and science to compare the level of the signal to the background noise. It is defined as ratio of power of signal to the noise and it is expressed in decibels.

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It is not unexpected that the methoxyl substituent on a cyclohexane ring prefers to adopt the equatorial conformation. OMe H A G₂ = +0.6 kcal/mol OMe What is unexpected is that the closely related 2-methoxytetrahydropyran prefers the axial conformation: H H OMe OMe A Gp=-0.6 kcal/mol Methoxy: CH3O group Please be specific and clearly write the reason why this is observed. This effect that provides stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO interacting with anti-bonding MO...]

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