(a)
Interpretation:
The type of noises that can be reduced by decreasing the temperature of measurement needs to be determined.
Concept introduction:
Chemical analyses are related with two types of noise which are chemical noise and instrumental noise. Chemical noise is due to reasons that affect the chemistry of the system being analyzed. Instrumental noise is components of the instrument. There are four types of instrumental noise and they are thermal noise, shot noise, flicker noise and environmental noise.
(b)
Interpretation:
The type of noise that can be reduced by increasing the frequency used for measurement needs to be determined.
Concept introduction:
Chemical analyses are related with two types of noise which are chemical noise and instrumental noise. Chemical noise is due to reasons that affect the chemistry of the system being analyzed. Instrumental noise is components of the instrument. There are four types of instrumental noise and they are thermal noise, shot noise, flicker noise and environmental noise. Among them flicker noise and environmental noise are frequency dependent thermal noise and shot noise are frequency independent.
(c)
Interpretation:
The type of noise that can be reduced by decreasing the band width of the measurement needs to be determined.
Concept introduction:
Radiation does not only come from human-made sources, but it can also come from natural sources.
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Chapter 5 Solutions
Principles of Instrumental Analysis, 6th Edition
- 2. Please consider the two all 'cis' isomers of trimethylcyclohexane drawn below. Draw the two chair conformers of each stereoisomer below (1 and 2) and calculate their torsional interaction energies in order to identify the lower energy conformer for each stereoisomer. Based on your calculations, state which of the two stereoisomers 1 and 2 is less stable and which is more stable. [1,3-diaxial CH3 CH3 = 3.7kcal/mol; 1,3-diaxial CH3 H = 0.88kcal/mol; cis-1,2 (axial:equatorial) CH3 CH3 = 0.88kcal/mol; trans-1,2-diequatorial CH3 CH3 = 0.88kcal/mol) all-cis-1,2,3- 1 all-cis-1,2,4- 2arrow_forwardNonearrow_forwardWhat is the mechanism by which the 1,4 product is created? Please draw it by hand with arrows and stuff.arrow_forward
- What is the relationship between A and B? H3C A Br Cl H3C B Br relationship (check all that apply) O same molecule O enantiomer O diastereomer structural isomer O stereoisomer isomer O need more information to decide O same molecule ☐ enantiomer Br Br Br CH3 Br CI CH3 O diastereomer ☐ structural isomer ☐ stereoisomer isomer O need more information to decide O same molecule O enantiomer Odiastereomer structural isomer O stereoisomer ☐ isomer O need more information to decidearrow_forwardb. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 4arrow_forwardc. Serricornin, the female-produced sex pheromone of the cigarette beetle, has the following structure. OH What is the maximum number of possible stereoisomers? Is this structure a meso compound? d. Please consider the natural product alkaloids shown below. Are these two structures enantiomers, diastereomers or conformers? H HO H H HN HO HN R R с R=H cinchonidine R=ET cinchonine Harrow_forward
- Nail polish remover containing acetone was spilled in a room 5.23 m × 3.28 m × 2.76 m. Measurements indicated that 2,250 mg of acetone evaporated. Calculate the acetone concentration in micrograms per cubic meter.arrow_forwardPlease help me answer number 1. 1. If your graphs revealed a mathematical relationship between specific heat and atomic mass, write down an equation for the relationship. I also don't understand, is the equation from the line regression the one that I'm suppose use to show the relationship? If so could you work it all the way out?arrow_forwardDescribe the principle of resonance and give a set of Lewis Structures to illustrate your explanation.arrow_forward
- Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning