1 Essential Ideas 2 Atoms, Molecules, And Ions 3 Electronic Structure And Periodic Properties Of Elements 4 Chemical Bonding And Molecular Geometry 5 Advanced Theories Of Bonding 6 Composition Of Substances And Solutions 7 Stoichiometry Of Chemical Reactions 8 Gases 9 Thermochemistry 10 Liquids And Solids 11 Solutions And Colloids 12 Thermodynamics 13 Fundamental Equilibrium Concepts 14 Acid-base Equilibria 15 Equilibria Of Other Reaction Classes 16 Electrochemistry 17 Kinetics 18 Representative Metals, Metalloids, And Nonmetals 19 Transition Metals And Coordination Chemistry 20 Nuclear Chemistry 21 Organic Chemistry expand_more
Chapter Questions expand_more
Problem 1E: Explain how σ and bonds are similar and how they are different. Problem 2E: Use valence bond theory to explain the bonding in F2, HF, and C1Br. Sketch the overlap of the atomic... Problem 3E: Use valence bond theory to explain the bonding in O2. Sketch the overlap of the atomic orbitals... Problem 4E: How many and bonds are present in the molecule HCN? Problem 5E: A friend tell you N2 has three bonds due to overlap of the threep -orbitals on each N atom. Do you... Problem 6E: Draw the Lewis Structures for CO2andCO , and predict the number of and bonds for each molecule.... Problem 7E: Why is the concept of hybridization required in valence bond theory? Problem 8E: Give the shape that describes each hybrid orbital set: (a) sp2 (b) sp3d (c) sp (d) sp3d2 Problem 9E: Explain why a carbon atom cannot from five bonds using sp3d hybrid orbitals. Problem 10E: What is the hybridization of the central atom in each of the following? (a) BeH2 (b) SF6 (c) PO43... Problem 11E: A molecule with the formula AB3 could have one of four different shapes. Give the shape and the... Problem 12E: Methionine, CH3SCH2CH2CH(NH2)CO2H, is an amino acid found in proteins. The Lewis structure of... Problem 13E: Sulfuric acid is manufactured by a series of reactions represented by the following equations:... Problem 14E: Two important industrial chemicals, ethene,C2H4,andpropene,C3H6 , are produced by the steam (or... Problem 15E: Analysis of a compound indicates that it contains 77.55%Xeand22.45% F by mass. (a) What is the... Problem 16E: Consider nitrous acid, HNO2(HONO). (a) Write a Lewis structure. (b) What are the electron pair and... Problem 17E: Strike-anywhere matches contain a layer of KC1O3 and a layer of P4S3 . The heat produced by the... Problem 18E: Identify the hybridization of each carbon atom in the following molecule. (The arrangement of atoms... Problem 19E: Write Lewis structures for NF3andPF5 . On the basis of hybrid orbitals, explain the fact that... Problem 20E: In addition to NF3, two other fluoro derivatives of nitrogen are known: N2F4 and N2F2 . What shapes... Problem 21E: The bond energy of a C-C single bond averages 347kJmol-1; that of a CC triple bond averages... Problem 22E: For the carbonate ion, CO32 -, draw all of the resonance structures. Identify which orbitals overlap... Problem 23E: A useful solvent that will dissolve salts as well as organic compounds is the compound acetonitrile,... Problem 24E: For the molecule allene, H2C=C=CH2, give the hybridization of each carbon atom. Will the hydrogen... Problem 25E: Identify the hybridization of the central atom in each of the following molecules and ions that... Problem 26E: Describe the molecular geometry and hybridization of the N, P, or S atoms in each of the following... Problem 27E: For each of the following molecules, indicate the hybridization requested and whether or not the... Problem 28E: For each of the following structures, determine the hybridization requested and whether the... Problem 29E: Draw the orbital diagram for carbon in CO2 showing how many carbon atom electrons are in each... Problem 30E: Sketch the distribution of electron density in the bonding and antibonding molecular orbitals formed... Problem 31E: How are the following similar, and how do they differ? (a) molecular orbitals and molecular... Problem 32E: If molecular orbitals are created by combining five atomic orbitals from atom A and five atomic... Problem 33E: Can a molecule with an odd number of electrons ever be diamagnetic? Explain why or why not. Problem 34E: Can a molecule with an even number of electrons ever be paramagnetic? Explain why or why not. Problem 35E: Why are bonding molecular orbital lower in energy than the parent atomic orbitals? Problem 36E: Calculate the bond order for an ion with this configuration: (2s)2(*2s)2(2px)2(2py,2pz)4(2py,2pz)3 Problem 37E: Explain why an electron in the bonding molecular orbital in the H2 molecule has a lower energy than... Problem 38E: Predict the valence electron molecular orbital configurations for the following, and state whether... Problem 39E: Determine the bond order of each member of the following groups, and determine which member of each... Problem 40E: For the first ionizations energy for an N2 molecule, what molecular orbital is the electron removed... Problem 41E: Compare the atomic and molecular orbitaI diagrams to identify the member of each of the following... Problem 42E: Which of the period 2 homonuclear diatomic molecules are predicted to be paramagnetic? Problem 43E: A friend tells you that the 2s orbital for fluorine starts off at a much lower energy than the 2s... Problem 44E: True or false: Boron contains 2s22p1 valence electrons, so only onep orbital is needed to form... Problem 45E: What charge would be needed on F2 to generate an ion with a bond order of 2? Problem 46E: Predict whether the MO diagram for S2 would show s-p mixing or not. Problem 47E: Explain why N22+ is diamagnetic, while O24+, which has the same number of valence electrons, is... Problem 48E: Using the MO diagrams, predict the bond order for the stronger bond in each pair: (a) B2orB2+ (b)... format_list_bulleted