Explain how Ïƒ and π bonds are similar and how they are different.

Question

Want to see more full solutions like this?

Answer 1

Textbook Question

Chapter 5, Problem 1E

Explain how Ïƒ and π bonds are similar and how they are different.

Expert Solution & Answer

Interpretation Introduction

Interpretation:

The similarity and difference between s and p bonds is to be explained.

Concept Introduction:

There are two types of bonds that are formed between the atoms-

a) Covalent bond- the bond formed by the sharing of electrons between the atoms.

b) Ionic bond- When atoms gain/loss electrons and become ions, the electrostatic attraction between the oppositely charged ions is known as ionic bond.

Electron in atoms occupy atomic orbitals while in molecule, electrons occupy molecular orbitals. These molecular orbitals are formed by the combination of the atomic orbitals and they can be bonding molecular orbitals and ant-bonding molecular orbitals.
The process of mixing of atomic orbitals of similar energy to produce new molecular orbitals of equivalent energy is known as hybridization.

Answer to Problem 1E

Similarity-They both are chemical covalent bonds and are formed by the overlapping of the atomic orbitals.

Differences-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Explanation of Solution

Sigma (s) bonds- It is a type of covalent bond which is formed by the end to end overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 1

Pi (p)bonds -It is a type of covalent bond which is formed by the side wise overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 2

Therefore, differences between sigma and pi bonds are-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Conclusion

However, the only similarity between these two are that they both are chemical covalent bonds and are formed by the overlapping the atomic orbitals, and the main difference is that sigma bond is formed by the axial overlap of the atomic orbitals, whereas, pi bond is formed by the sideways overlapping of atomic orbitals.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Students have asked these similar questions

19) Which metal is most commonly used in galvanization to protect steel structures from oxidation? Lead a. b. Tin C. Nickel d. Zinc 20) The following molecule is an example of a: R₁ R2- -N-R3 a. Secondary amine b. Secondary amide c. Tertiary amine d. Tertiary amide

pls help

Indicate the product of the reaction OH OH CH3-CC- Ph + H2SO4 a 20°C | CH3 Ph

Answer 2

Textbook Question

Chapter 5, Problem 1E

Explain how Ïƒ and π bonds are similar and how they are different.

Expert Solution & Answer

Interpretation Introduction

Interpretation:

The similarity and difference between s and p bonds is to be explained.

Concept Introduction:

There are two types of bonds that are formed between the atoms-

a) Covalent bond- the bond formed by the sharing of electrons between the atoms.

b) Ionic bond- When atoms gain/loss electrons and become ions, the electrostatic attraction between the oppositely charged ions is known as ionic bond.

Electron in atoms occupy atomic orbitals while in molecule, electrons occupy molecular orbitals. These molecular orbitals are formed by the combination of the atomic orbitals and they can be bonding molecular orbitals and ant-bonding molecular orbitals.
The process of mixing of atomic orbitals of similar energy to produce new molecular orbitals of equivalent energy is known as hybridization.

Answer to Problem 1E

Similarity-They both are chemical covalent bonds and are formed by the overlapping of the atomic orbitals.

Differences-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Explanation of Solution

Sigma (s) bonds- It is a type of covalent bond which is formed by the end to end overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 1

Pi (p)bonds -It is a type of covalent bond which is formed by the side wise overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 2

Therefore, differences between sigma and pi bonds are-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Conclusion

However, the only similarity between these two are that they both are chemical covalent bonds and are formed by the overlapping the atomic orbitals, and the main difference is that sigma bond is formed by the axial overlap of the atomic orbitals, whereas, pi bond is formed by the sideways overlapping of atomic orbitals.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Textbook Question

Chapter 5, Problem 1E

Explain how Ïƒ and π bonds are similar and how they are different.

Expert Solution & Answer

Interpretation Introduction

Interpretation:

The similarity and difference between s and p bonds is to be explained.

Concept Introduction:

There are two types of bonds that are formed between the atoms-

a) Covalent bond- the bond formed by the sharing of electrons between the atoms.

b) Ionic bond- When atoms gain/loss electrons and become ions, the electrostatic attraction between the oppositely charged ions is known as ionic bond.

Electron in atoms occupy atomic orbitals while in molecule, electrons occupy molecular orbitals. These molecular orbitals are formed by the combination of the atomic orbitals and they can be bonding molecular orbitals and ant-bonding molecular orbitals.
The process of mixing of atomic orbitals of similar energy to produce new molecular orbitals of equivalent energy is known as hybridization.

Answer to Problem 1E

Similarity-They both are chemical covalent bonds and are formed by the overlapping of the atomic orbitals.

Differences-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Explanation of Solution

Sigma (s) bonds- It is a type of covalent bond which is formed by the end to end overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 1

Pi (p)bonds -It is a type of covalent bond which is formed by the side wise overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 2

Therefore, differences between sigma and pi bonds are-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Conclusion

However, the only similarity between these two are that they both are chemical covalent bonds and are formed by the overlapping the atomic orbitals, and the main difference is that sigma bond is formed by the axial overlap of the atomic orbitals, whereas, pi bond is formed by the sideways overlapping of atomic orbitals.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Textbook Question

Chapter 5, Problem 1E

Explain how Ïƒ and π bonds are similar and how they are different.

Expert Solution & Answer

Interpretation Introduction

Interpretation:

The similarity and difference between s and p bonds is to be explained.

Concept Introduction:

There are two types of bonds that are formed between the atoms-

a) Covalent bond- the bond formed by the sharing of electrons between the atoms.

b) Ionic bond- When atoms gain/loss electrons and become ions, the electrostatic attraction between the oppositely charged ions is known as ionic bond.

Electron in atoms occupy atomic orbitals while in molecule, electrons occupy molecular orbitals. These molecular orbitals are formed by the combination of the atomic orbitals and they can be bonding molecular orbitals and ant-bonding molecular orbitals.
The process of mixing of atomic orbitals of similar energy to produce new molecular orbitals of equivalent energy is known as hybridization.

Answer to Problem 1E

Similarity-They both are chemical covalent bonds and are formed by the overlapping of the atomic orbitals.

Differences-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Explanation of Solution

Sigma (s) bonds- It is a type of covalent bond which is formed by the end to end overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 1

Pi (p)bonds -It is a type of covalent bond which is formed by the side wise overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 2

Therefore, differences between sigma and pi bonds are-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Conclusion

However, the only similarity between these two are that they both are chemical covalent bonds and are formed by the overlapping the atomic orbitals, and the main difference is that sigma bond is formed by the axial overlap of the atomic orbitals, whereas, pi bond is formed by the sideways overlapping of atomic orbitals.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Textbook Question

Answer 6

Textbook Question

Answer 7

Expert Solution & Answer

Interpretation Introduction

Interpretation:

The similarity and difference between s and p bonds is to be explained.

Concept Introduction:

There are two types of bonds that are formed between the atoms-

a) Covalent bond- the bond formed by the sharing of electrons between the atoms.

b) Ionic bond- When atoms gain/loss electrons and become ions, the electrostatic attraction between the oppositely charged ions is known as ionic bond.

Electron in atoms occupy atomic orbitals while in molecule, electrons occupy molecular orbitals. These molecular orbitals are formed by the combination of the atomic orbitals and they can be bonding molecular orbitals and ant-bonding molecular orbitals.
The process of mixing of atomic orbitals of similar energy to produce new molecular orbitals of equivalent energy is known as hybridization.

Answer to Problem 1E

Similarity-They both are chemical covalent bonds and are formed by the overlapping of the atomic orbitals.

Differences-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Explanation of Solution

Sigma (s) bonds- It is a type of covalent bond which is formed by the end to end overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 1

Pi (p)bonds -It is a type of covalent bond which is formed by the side wise overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 2

Therefore, differences between sigma and pi bonds are-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Conclusion

However, the only similarity between these two are that they both are chemical covalent bonds and are formed by the overlapping the atomic orbitals, and the main difference is that sigma bond is formed by the axial overlap of the atomic orbitals, whereas, pi bond is formed by the sideways overlapping of atomic orbitals.

Answer 8

Expert Solution & Answer

Interpretation Introduction

Interpretation:

The similarity and difference between s and p bonds is to be explained.

Concept Introduction:

There are two types of bonds that are formed between the atoms-

a) Covalent bond- the bond formed by the sharing of electrons between the atoms.

b) Ionic bond- When atoms gain/loss electrons and become ions, the electrostatic attraction between the oppositely charged ions is known as ionic bond.

Electron in atoms occupy atomic orbitals while in molecule, electrons occupy molecular orbitals. These molecular orbitals are formed by the combination of the atomic orbitals and they can be bonding molecular orbitals and ant-bonding molecular orbitals.
The process of mixing of atomic orbitals of similar energy to produce new molecular orbitals of equivalent energy is known as hybridization.

Answer to Problem 1E

Similarity-They both are chemical covalent bonds and are formed by the overlapping of the atomic orbitals.

Differences-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Explanation of Solution

Sigma (s) bonds- It is a type of covalent bond which is formed by the end to end overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 1

Pi (p)bonds -It is a type of covalent bond which is formed by the side wise overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 2

Therefore, differences between sigma and pi bonds are-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Conclusion

However, the only similarity between these two are that they both are chemical covalent bonds and are formed by the overlapping the atomic orbitals, and the main difference is that sigma bond is formed by the axial overlap of the atomic orbitals, whereas, pi bond is formed by the sideways overlapping of atomic orbitals.

Answer 9

Expert Solution & Answer

Answer 10

Expert Solution & Answer

Answer 11

Interpretation Introduction

Interpretation:

The similarity and difference between s and p bonds is to be explained.

Concept Introduction:

There are two types of bonds that are formed between the atoms-

a) Covalent bond- the bond formed by the sharing of electrons between the atoms.

b) Ionic bond- When atoms gain/loss electrons and become ions, the electrostatic attraction between the oppositely charged ions is known as ionic bond.

Electron in atoms occupy atomic orbitals while in molecule, electrons occupy molecular orbitals. These molecular orbitals are formed by the combination of the atomic orbitals and they can be bonding molecular orbitals and ant-bonding molecular orbitals.
The process of mixing of atomic orbitals of similar energy to produce new molecular orbitals of equivalent energy is known as hybridization.

Answer 12

Answer to Problem 1E

Similarity-They both are chemical covalent bonds and are formed by the overlapping of the atomic orbitals.

Differences-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Answer 13

Explanation of Solution

Sigma (s) bonds- It is a type of covalent bond which is formed by the end to end overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 1

Pi (p)bonds -It is a type of covalent bond which is formed by the side wise overlapping of the atomic orbitals of the atoms involved in bonding.

Chemistry Atoms First2e, Chapter 5, Problem 1E , additional homework tip 2

Therefore, differences between sigma and pi bonds are-

s- bond	?-bond
Formed by the axial overlap of the atomic orbitals.	Formed by the side-ways overlap of the atomic orbitals.
It can be formed by the overlap of s-s, s-p or p-p orbitals.	It can only be formed by the overlap of p orbitals
Oriented along the internuclear axis.	Oriented perpendicular to the internuclear axis.
Exists independently.	Exist along with sigma bond.
Stronger than pi-bond.	Weaker than sigma bond.
More reactive.	Less reactive.
Determines the shape of the molecule.	Does not determine the shape of the molecule.

Answer 14

Conclusion

However, the only similarity between these two are that they both are chemical covalent bonds and are formed by the overlapping the atomic orbitals, and the main difference is that sigma bond is formed by the axial overlap of the atomic orbitals, whereas, pi bond is formed by the sideways overlapping of atomic orbitals.

Answer 15

Ch. 5 - Explain how Ïƒ and bonds are similar and how they...Ch. 5 - Use valence bond theory to explain the bonding in...Ch. 5 - Use valence bond theory to explain the bonding in...Ch. 5 - How many and bonds are present in the molecule...Ch. 5 - A friend tell you N2 has three bonds due to...Ch. 5 - Draw the Lewis Structures for CO2andCO , and...Ch. 5 - Why is the concept of hybridization required in...Ch. 5 - Give the shape that describes each hybrid orbital...Ch. 5 - Explain why a carbon atom cannot from five bonds...Ch. 5 - What is the hybridization of the central atom in...

Explain how Ïƒ and π bonds are similar and how they are different.

Videos

Answer to Problem 1E

Explanation of Solution

Want to see more full solutions like this?

Chapter 5 Solutions