Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 5, Problem 43AP
In the hydrogen atom, the transition from the 2p state to the 1s state emits a photon with energy
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Principles of Modern Chemistry
Ch. 5 - Which of the following combinations of quantum...Ch. 5 - Which of the following combinations of quantum...Ch. 5 - Label the orbitals described by each of the...Ch. 5 - Label the orbitals described by each of the...Ch. 5 - Estimate the probability of finding an electron...Ch. 5 - Using Table 5.2, write down the mathematical...Ch. 5 - How many radial nodes and how many angular nodes...Ch. 5 - How many radial nodes and how many angular nodes...Ch. 5 - Use the mathematical expression for the 2pz wave...Ch. 5 - (a) Use the radial wave function for the 3p...
Ch. 5 - Calculate the average distance of the electron...Ch. 5 - The helium ion He+ is a one-electron system whose...Ch. 5 - Spectroscopic studies show that Li can have...Ch. 5 - Spectroscopic studies of Li also show that...Ch. 5 - Spectroscopic studies show that Na can have...Ch. 5 - Using data from Problems 13 and 15, calculate the...Ch. 5 - Give the ground-state electron configurations of...Ch. 5 - Give the ground-state electron configurations of...Ch. 5 - Prob. 19PCh. 5 - Write ground-state electron configurations for the...Ch. 5 - Identify the atom or ion corresponding to each of...Ch. 5 - Identify the atom or ion corresponding to each of...Ch. 5 - Predict the atomic number of the (as yet...Ch. 5 - (a) Predict the atomic number of the (as yet...Ch. 5 - Suppose that the spin quantum number did not...Ch. 5 - Suppose that the spin quantum number had three...Ch. 5 - Photoelectron spectra of mercury (Hg) atoms...Ch. 5 - Quantum mechanics predicts that the energy of the...Ch. 5 - Prob. 29PCh. 5 - Photoelectron spectroscopy studies of silicon...Ch. 5 - Photoelectron spectroscopy studies have determined...Ch. 5 - Prob. 32PCh. 5 - For each of the following pairs of atoms or ions,...Ch. 5 - For each of the following pairs of atoms or ions,...Ch. 5 - Predict the larger ion in each of the following...Ch. 5 - Prob. 36PCh. 5 - The first ionization energy of helium is...Ch. 5 - The energy needed to remove one electron from a...Ch. 5 - Without consulting any tables, arrange the...Ch. 5 - Both the electron affinity and the ionization...Ch. 5 - The cesium atom has the lowest ionization energy,...Ch. 5 - Until recently, it was thought that Ca was...Ch. 5 - In the hydrogen atom, the transition from the 2p...Ch. 5 - The energy needed to ionize an atom of element X...Ch. 5 - Suppose an atom in an excited state can return to...Ch. 5 - For the Li atom, the energy difference between the...Ch. 5 - How does the 3dxy orbital of an electron in O7+...Ch. 5 - The wave function of an electron in the lowest...Ch. 5 - An atom of sodium has the electron configuration...Ch. 5 - (a) The nitrogen atom has one electron in each of...Ch. 5 - Chromium(IV) oxide is used in making magnetic...Ch. 5 - Prob. 52APCh. 5 - Arrange the following seven atoms or ions in order...Ch. 5 - Which is higher, the third ionization energy of...Ch. 5 - The outermost electron in an alkali-metal atom is...Ch. 5 - In two-photon ionization spectroscopy, the...Ch. 5 - For the H atom, the transition from the 2p state...Ch. 5 - (a) Give the complete electron configuration...Ch. 5 - What experimental evidence does the periodic table...
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- A hydrogen atom in the ground stale absorbs a photon whose wavelength is 95.0 nm. The resulting excited atom then emits a photon of 1282 nm. What are the regions of the electromagnetic spectrum for the radiations involved in these transitions? What is the principal quantum number of the final state resulting from the emission from the excited atom?arrow_forwardSpectroscopists have observed He+ in outer space. This ion is a one-electron species like a neutral hydrogen atom. Calculate the energy of the photon emitted for the transition from the n = 5 to the n = 3 state in this ion using the equation: En = − Z2/n2 (2.179 × 10−18 J). Z is the positive charge of the nucleus and n is the principal quantum number. In what part of the electromagnetic spectrum does this radiation lie?arrow_forwardIt requires 799 kJ of energy to break one mole of carbon-oxygen double bonds in carbon dioxide. What wavelength of light does this correspond to per bond? Is there any transition in the hydrogen atom that has at least this quantity of energy to one photon?arrow_forward
- Investigating Energy Levels Consider the hypothetical atom X that has one electron like the H atom but has different energy levels. The energies of an electron in an X atom are described by the equation E=RHn3 where RH is the same as for hydrogen (2.179 1018 J). Answer the following questions, without calculating energy values. a How would the ground-state energy levels of X and H compare? b Would the energy of an electron in the n = 2 level of H be higher or lower than that of an electron in the n = 2 level of X? Explain your answer. c How do the spacings of the energy levels of X and H compare? d Which would involve the emission of a higher frequency of light, the transition of an electron in an H atom from the n = 5 to the n = 3 level or a similar transition in an X atom? e Which atom, X or H, would require more energy to completely remove its electron? f A photon corresponding to a particular frequency of blue light produces a transition from the n = 2 to the n = 5 level of a hydrogen atom. Could this photon produce the same transition (n = 12 to n = 5) in an atom of X? Explain.arrow_forwardWhat is the physical significance of the value of 2 at a particular point in an atomic orbital?arrow_forwardThe energy of a photon is 3.05 1019 J. What is the wavelength of the corresponding light? What is the color of this light?arrow_forward
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