The general trend in radii of rare earth metals should be reported and the reason behind the trend should be explained. Concept introduction: Lanthanoid contraction is the steady decrease in the size of the atoms and ions of the rare earth elements with increasing atomic number from lanthanum( Z equal to57) through lutetium( Z equal to71). For each atom across period the nuclear charge increases with unit positive charge, accompanied by increase in count of electrons present in 4 f orbitals. 4 f electrons poorly shield each other from increased charge of nucleus so that Z eff that attracts each electron steadily increases through rare earth elements, which results in successive decrease of atomic and ionic radii.
The general trend in radii of rare earth metals should be reported and the reason behind the trend should be explained. Concept introduction: Lanthanoid contraction is the steady decrease in the size of the atoms and ions of the rare earth elements with increasing atomic number from lanthanum( Z equal to57) through lutetium( Z equal to71). For each atom across period the nuclear charge increases with unit positive charge, accompanied by increase in count of electrons present in 4 f orbitals. 4 f electrons poorly shield each other from increased charge of nucleus so that Z eff that attracts each electron steadily increases through rare earth elements, which results in successive decrease of atomic and ionic radii.
Solution Summary: The author explains that the general trend in radii of rare earth metals should be reported and the reason behind the trend.
Definition Definition Number of protons in the nucleus of an atom. It uniquely identifies an element, as the number of protons determines the element's properties. The periodic table of elements is arranged based on increasing atomic numbers, allowing scientists to easily locate and study elements.
Chapter 5, Problem 52AP
a)
Interpretation Introduction
Interpretation: The general trend in radii of rare earth metals should be reported and the reason behind the trend should be explained.
Concept introduction: Lanthanoid contraction is the steady decrease in the size of the atoms and ions of the rare earth elements with increasing atomic number from lanthanum( Z equal to57) through lutetium( Z equal to71). For each atom across period the nuclear charge increases with unit positive charge, accompanied by increase in count of electrons present in 4forbitals. 4f electrons poorly shield each other from increased charge of nucleus so that Zeff that attracts each electron steadily increases through rare earth elements, which results in successive decrease of atomic and ionic radii.
b)
Interpretation Introduction
Interpretation: The two elements that are exception to the general trend of radii of rare earth metals should be reported.
Concept introduction: Lanthanoid contraction is the steady decrease in the size of the atoms and ions of the rare earth elements with increasing atomic number from lanthanum( Z equal to57) through lutetium( Z equal to71). For each atom across period the nuclear charge increases with unit positive charge, accompanied by increase in count of electrons present in 4forbitals. 4f electrons poorly shield each other from increased charge of nucleus so that Zeff that attracts each electron steadily increases through rare earth elements, which results in successive decrease of atomic and ionic radii.
Question
Suggest a mechanism for the following reactions. Each will require multiple
types of concerted pericyclic reactions (cycloaddition, electrocyclic, and
sigmatropic. Classify each reaction type.
CN
a.
NC
180 °C
Don't used Ai solution and don't used hand raiting
Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell