EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
3rd Edition
ISBN: 9780133858501
Author: Bruice
Publisher: PEARSON CO
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Chapter 5, Problem 40P
- a. The ΔG° for conversion of “axial” fluorocyclohexane to “equatorial” fluorocyclohexane at 25 °C is −0.25 kcal/mol. Calculate the percentage of fluorocyclohexane molecules that have the fluoro substituent in an equatorial position at equilibrium.
- b. Do the same calculation for isopropylcyclohexane (its ΔG ° value at 25 °C is −2.1 kcal/mol).
- c. Why is the percentage of molecules with the substituent in an equatorial position greater for isopropylcyclohexane?
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Complete these reactions:
b. CH2= CH2© + Hcl (room temperature).
C CH 2= CH 2+H2>
d.n(CHa =CH2)(high tem perature >
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f. CHECH +2Na->
9. n CCtl2z CH2)->
h. HC E CH + H2->
i HC E CH 2H2.>
J. CH2CH2 + cla -s
K CH3 CH = CH CH3 +Hz=>
L. CH3 C=CCH3 t 2 H2/Ni ->
M. LCHュ= CH2 + H2->
Which of the following aldehydes has the highest solubility in water?
A) CH₃CH₂C(=O)H
B) CH₃CH₂CH₂CH₂C(=O)H
C) CH₃(CH₂)₅C(=O)H
D) CH₃(CH₂)₁₀C(=O)H
E) All of these have equal solubility.
Reagents
a. CeHsCHO
b. NaOH, ethanol
c. Pyrrolidine, cat. H* j. Brz, H*
d. H2C=CHCN
e. H3O*
f.
h. BRCH2CH=CH2
i. Na* OEt, ethanol
k. K* t-Buo
I. CH2(CO,Et)2
m. heat
CH2CH2CN
LDA
g. ELOC(=0)COEt
Select reagents from the table to synthesize this compound from cyclopentanone.
Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).
Chapter 5 Solutions
EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
Ch. 5.1 - Prob. 1PCh. 5.1 - Draw the structure for each of the following: a....Ch. 5.1 - What is each compounds systematic name?Ch. 5.3 - Prob. 4PCh. 5.3 - Prob. 5PCh. 5.3 - Prob. 7PCh. 5.4 - a. For which reaction in each set below will S be...Ch. 5.6 - Prob. 9PCh. 5.6 - How many different alkenes can be hydrogenated to...Ch. 5.6 - The same alkane is obtained from the catalytic...
Ch. 5.6 - Prob. 12PCh. 5.6 - Rank the following compounds in order from most...Ch. 5.7 - The rate constant for a reaction can be increased...Ch. 5.7 - Prob. 15PCh. 5.7 - Prob. 16PCh. 5.9 - Draw a reaction coordinate diagram for a two-step...Ch. 5.9 - Prob. 18PCh. 5.9 - Draw a reaction coordinate diagram for the...Ch. 5.10 - Which of the following parameters would be...Ch. 5 - What is each compounds systematic name?Ch. 5 - Draw the structure of a hydrocarbon that has six...Ch. 5 - Which of the following compounds is the most...Ch. 5 - Prob. 24PCh. 5 - Prob. 25PCh. 5 - Prob. 26PCh. 5 - Prob. 27PCh. 5 - Name the following:Ch. 5 - Prob. 29PCh. 5 - Prob. 30PCh. 5 - Prob. 31PCh. 5 - Prob. 32PCh. 5 - Prob. 33PCh. 5 - Prob. 34PCh. 5 - Prob. 35PCh. 5 - Name each of the following:Ch. 5 - Prob. 38PCh. 5 - Given that the twist-boat conformer of cyclohexane...Ch. 5 - a. The G for conversion of axial fluorocyclohexane...Ch. 5 - Prob. 1PCh. 5 - Prob. 2PCh. 5 - Prob. 3PCh. 5 - Prob. 4PCh. 5 - Prob. 5PCh. 5 - Prob. 6PCh. 5 - Prob. 7PCh. 5 - Prob. 8PCh. 5 - Prob. 9PCh. 5 - Prob. 10P
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