EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
3rd Edition
ISBN: 9780133858501
Author: Bruice
Publisher: PEARSON CO
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Chapter 5, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

(b)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

(c)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

(d)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

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Part B?
2. Fill the missing reagents or products for the incomplete reaction schemes shown below (only Reagent A or Reagent B will react in significant quantities). F (1 mmol) Reagent A (1 mmol) Reagent B (1 mmol) Major Product from Reagent A Major Product from Reagent B Explain the selectivity observed in this reaction using words and drawings. Br NaNH2 Br NH3, -35 °C Вrz, FeBr3 Draw the mechanism for the transformation shown above. Be sure to draw the important resonance structures that account for the regioselectivity observed in this reaction.
Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. CH3 CH3 CH3COCI/ AICI3 H₂C. You do not have to consider stereochemistry. Include all valence lone pairs in your answer. • In cases where there is more than one answer, just draw one.

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