
Concept explainers
(a)
Interpretation: The given number
Concept Introduction: Rules used for rounding off numbers are as follows:
If the digit to be removed:
- Is less than 5, then digit before it remains the same.
- Is greater than 5, then digit before it is increased by 1 unit.
- Is equal to five, then if the digit before it is odd then it is increased by 1 unit and if the digit is even then it remains the same.
(a)

Answer to Problem 26A
Explanation of Solution
At first, the number is written as follows:
The number is rounded off to two significant figures, so, look at the digit which is to be removed. The digit to be removed is 6 that is greater than 5. Hence, the digit before it is increased by 1. Therefore,
(b)
Interpretation: The given number
Concept Introduction: Rules used for rounding off numbers are as follows:
If the digit to be removed:
- Is less than 5, then digit before it remains the same.
- Is greater than 5, then digit before it is increased by 1 unit.
- Is equal to five, then if the digit before it is odd then it is increased by 1 unit and if the digit is even then it remains the same.
(b)

Answer to Problem 26A
Explanation of Solution
To round off the given number to two significant figures, first look for the digit which is to be removed. In this case, the digit to be removed is larger than 5. Thus, the number becomes
(c)
Interpretation: The given number
Concept Introduction: Rules used for rounding off numbers are as follows:
If the digit to be removed:
- Is less than 5, then digit before it remains the same.
- Is greater than 5, then digit before it is increased by 1 unit.
- Is equal to five, then if the digit before it is odd then it is increased by 1 unit and if the digit is even then it remains the same.
(c)

Answer to Problem 26A
Explanation of Solution
The number
Firstly, look for the digit which is to be removed. The digit to be removed is smaller than 5. Hence, no change takes place in the digit before it. Therefore,
(d)
Interpretation: The given number
Concept Introduction: Rules used for rounding off numbers are as follows:
If the digit to be removed:
- Is less than 5, then digit before it remains the same.
- Is greater than 5, then digit before it is increased by 1 unit.
- Is equal to five, then if the digit before it is odd then it is increased by 1 unit and if the digit is even then it remains the same.
(d)

Answer to Problem 26A
Explanation of Solution
First, look at the digit which is to be removed. In this case, the digit to be removed is smaller than 5. Hence, no change in the digit before it takes place. Therefore,
Chapter 5 Solutions
World of Chemistry
- 23.34 Show how to convert each starting material into isobutylamine in good yield. ཅ ནད ཀྱི (b) Br OEt (c) (d) (e) (f) Harrow_forwardPlease help me Please use https://app.molview.com/ to draw this. I tried, but I couldn't figure out how to do it.arrow_forwardPropose a synthesis of 1-butanamine from the following: (a) a chloroalkane of three carbons (b) a chloroalkane of four carbonsarrow_forward
- Select the stronger base from each pair of compounds. (a) H₂CNH₂ or EtzN (b) CI or NH2 NH2 (c) .Q or EtzN (d) or (e) N or (f) H or Harrow_forward4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HOarrow_forwardb. H3C CH3 H3O+ ✓ H OHarrow_forward
- 2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. CH3arrow_forwardIdentify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.arrow_forwardIdentify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.arrow_forward
- Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.arrow_forwardе. Д CH3 D*, D20arrow_forwardC. NaOMe, Br Brarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





