CHEMISTRY: ATOMS FIRST VOL 1 W/CONNECT
14th Edition
ISBN: 9781259327933
Author: Burdge
Publisher: MCG
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Question
Chapter 4.5, Problem 4.5.4SR
Interpretation Introduction
Interpretation:
Ground-state electronic configuration for
Concept introduction:
The electron configuration of an atomic species (neutral or ionic) is to understand the shape and energy of its electrons.
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Question 19
0/2 pts 3
Details
You have a mixture of sodium chloride (NaCl) and potassium chloride (KCl) dissolved in water
and want to separate out the Cl- ions by precipitating them out using silver ions (Ag+). The
chemical equation for the net ionic reaction of NaCl and KCl with silver nitrate, AgNO3, is shown
below.
Ag+(aq) + Cl(aq) → AgCl(s)
The total mass of the NaCl/KCl mixture is 1.299 g. Adding 50.42 mL of 0.381 M solution
precipitates out all of the Cl-.
What are the masses of NaCl and KCl in the mixture?
Atomic masses:
g: Mass of NaCl
g: Mass of KCL
Ag = 107.868 g
mol-
1
Cl = 35.453 g mol-
1
K = 39.098 g mol-
N = 14.007 g mol−1
Na = 22.99 g mol−1
0 = 15.999 g mol
1
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Part 1. Draw monomer units of the following products and draw their reaction mechanism (with arrow pushing)
Polyester fiber
Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol
B)pthalic anhydride + anhydrous sodium acetate + glycerol
Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any.
If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers).
If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products.
If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each)
Chapter 4 Solutions
CHEMISTRY: ATOMS FIRST VOL 1 W/CONNECT
Ch. 4.1 - Prob. 4.1WECh. 4.1 - Prob. 1PPACh. 4.1 - Prob. 1PPBCh. 4.1 - Prob. 1PPCCh. 4.1 - Prob. 4.1.1SRCh. 4.1 - Prob. 4.1.2SRCh. 4.1 - Prob. 4.1.3SRCh. 4.2 - Prob. 4.2WECh. 4.2 - Without using a periodic table, give the...Ch. 4.2 - Identify the elements represented by (a)...
Ch. 4.2 - Prob. 2PPCCh. 4.2 - Prob. 4.2.1SRCh. 4.2 - Prob. 4.2.2SRCh. 4.4 - Referring only to a periodic table, arrange the...Ch. 4.4 - Prob. 3PPACh. 4.4 - Prob. 3PPBCh. 4.4 - Prob. 3PPCCh. 4.4 - Prob. 4.4WECh. 4.4 - Which element. Mg or Al, will have the higher...Ch. 4.4 - Explain why Rb has a lower IE1 than Sr, but Sr has...Ch. 4.4 - Imagine an arrangement of atomic orbitals in an...Ch. 4.4 - For each pair of elements, indicate which one you...Ch. 4.4 - Prob. 5PPACh. 4.4 - Explain why the EA1 for Ge is greater than the EA1...Ch. 4.4 - In the same hypothetical arrangement described in...Ch. 4.4 - For carbon and nitrogen, use the effective nuclear...Ch. 4.4 - Between which two charges is the attractive force...Ch. 4.4 - What must the distance be between charges of +2.25...Ch. 4.4 - Rank these pairs of charged objects in order of...Ch. 4.4 - Prob. 4.4.1SRCh. 4.4 - Prob. 4.4.2SRCh. 4.4 - Prob. 4.4.3SRCh. 4.4 - Prob. 4.4.4SRCh. 4.4 - Prob. 4.4.5SRCh. 4.4 - Prob. 4.4.6SRCh. 4.5 - Write electron configurations for the following...Ch. 4.5 - Write electron configurations for (a) O2, (b)...Ch. 4.5 - Prob. 7PPBCh. 4.5 - Prob. 7PPCCh. 4.5 - Prob. 4.8WECh. 4.5 - Prob. 8PPACh. 4.5 - Prob. 8PPBCh. 4.5 - Select the correct valence orbital diagram for the...Ch. 4.5 - Prob. 4.5.1SRCh. 4.5 - Prob. 4.5.2SRCh. 4.5 - Prob. 4.5.3SRCh. 4.5 - Prob. 4.5.4SRCh. 4.5 - Prob. 4.5.5SRCh. 4.6 - Identify the isoelectronic series in the following...Ch. 4.6 - Arrange the following isoelectronic series in...Ch. 4.6 - List all the common ions that are isoelectronic...Ch. 4.6 - Prob. 9PPCCh. 4.6 - Prob. 4.6.1SRCh. 4.6 - Prob. 4.6.2SRCh. 4.6 - Prob. 4.6.3SRCh. 4.6 - Prob. 4.6.4SRCh. 4 - Briefly describe the significance of Mendeleevs...Ch. 4 - What is Moseleys contribution to the modem...Ch. 4 - Describe the general layout of a modern periodic...Ch. 4 - What is the most important relationship among...Ch. 4 - Prob. 4.5QPCh. 4 - Prob. 4.6QPCh. 4 - Prob. 4.7QPCh. 4 - Prob. 4.8QPCh. 4 - Without referring to a periodic table, write the...Ch. 4 - Prob. 4.10QPCh. 4 - Prob. 4.11QPCh. 4 - Prob. 4.12QPCh. 4 - For centuries, arsenic has been the poison of...Ch. 4 - In the periodic table, the element hydrogen is...Ch. 4 - An atom of a certain clement has 16 electrons....Ch. 4 - Prob. 4.16QPCh. 4 - Prob. 4.17QPCh. 4 - Prob. 4.18QPCh. 4 - Prob. 4.19QPCh. 4 - For each of the following ground-state electron...Ch. 4 - Determine what element is designated by each of...Ch. 4 - Prob. 4.22QPCh. 4 - Explain why there is a greater increase in...Ch. 4 - The election configuration of B is1s22s22p1. (a)...Ch. 4 - The election configuration of C is1s22s22p1. (a)...Ch. 4 - Prob. 4.26QPCh. 4 - Prob. 4.27QPCh. 4 - Equation 4.2 is used to calculate the force...Ch. 4 - Use the second period of the periodic table as an...Ch. 4 - Prob. 4.30QPCh. 4 - Prob. 4.31QPCh. 4 - Prob. 4.32QPCh. 4 - Prob. 4.33QPCh. 4 - Prob. 4.34QPCh. 4 - Prob. 4.35QPCh. 4 - Prob. 4.36QPCh. 4 - Prob. 4.37QPCh. 4 - Prob. 4.38QPCh. 4 - Prob. 4.39QPCh. 4 - Consider two ions with opposite charges separated...Ch. 4 - Prob. 4.41QPCh. 4 - Prob. 4.42QPCh. 4 - Prob. 4.43QPCh. 4 - On the basis of their positions in the periodic...Ch. 4 - Prob. 4.45QPCh. 4 - Prob. 4.46QPCh. 4 - Prob. 4.47QPCh. 4 - Prob. 4.48QPCh. 4 - Prob. 4.49QPCh. 4 - Prob. 4.50QPCh. 4 - Prob. 4.51QPCh. 4 - Prob. 4.52QPCh. 4 - In general, the first ionization energy increases...Ch. 4 - Prob. 4.54QPCh. 4 - Prob. 4.55QPCh. 4 - Prob. 4.56QPCh. 4 - Prob. 4.57QPCh. 4 - Prob. 4.58QPCh. 4 - Specify which of the following elements you would...Ch. 4 - Considering their electron affinities, do you...Ch. 4 - Prob. 4.61QPCh. 4 - Prob. 4.62QPCh. 4 - Prob. 4.63QPCh. 4 - Prob. 4.64QPCh. 4 - Prob. 4.65QPCh. 4 - Prob. 4.66QPCh. 4 - Prob. 4.67QPCh. 4 - Prob. 4.68QPCh. 4 - Prob. 4.69QPCh. 4 - Write the ground-state electron configurations of...Ch. 4 - Write the ground-state electron configurations of...Ch. 4 - Prob. 4.72QPCh. 4 - Prob. 4.73QPCh. 4 - Identify the ions, each with a net charge of +1,...Ch. 4 - Prob. 4.75QPCh. 4 - Prob. 4.76QPCh. 4 - Group the species that are isoelectronic: Be2+, F,...Ch. 4 - For each pair of ions, determine which will have...Ch. 4 - Rank the following ions in order of increasing...Ch. 4 - Prob. 4.80QPCh. 4 - Prob. 4.81QPCh. 4 - Prob. 4.82QPCh. 4 - A metal ion with a net +3 charge has five...Ch. 4 - Identify the atomic ground-state electron...Ch. 4 - Each of the following ground-state electron...Ch. 4 - Prob. 4.86QPCh. 4 - Prob. 4.87QPCh. 4 - Prob. 4.88QPCh. 4 - Indicate which one of the two species in each of...Ch. 4 - Prob. 4.90QPCh. 4 - Prob. 4.91QPCh. 4 - Prob. 4.92QPCh. 4 - Prob. 4.93QPCh. 4 - Prob. 4.94QPCh. 4 - Prob. 4.95QPCh. 4 - Prob. 4.96QPCh. 4 - Prob. 4.97QPCh. 4 - Prob. 4.98QPCh. 4 - Prob. 4.99QPCh. 4 - Prob. 4.100QPCh. 4 - Arrange the following species in isoelectronic...Ch. 4 - Prob. 4.102QPCh. 4 - Prob. 4.103QPCh. 4 - Prob. 4.104QPCh. 4 - Prob. 4.105QPCh. 4 - Prob. 4.106QPCh. 4 - Prob. 4.107QPCh. 4 - Prob. 4.108QPCh. 4 - Contrary to the generalized trend that atomic...Ch. 4 - Prob. 4.110QPCh. 4 - Prob. 4.111QPCh. 4 - Prob. 4.112QPCh. 4 - Prob. 4.113QPCh. 4 - Prob. 4.114QPCh. 4 - Prob. 4.115QPCh. 4 - Prob. 4.116QPCh. 4 - Prob. 4.117QPCh. 4 - Prob. 4.118QPCh. 4 - Prob. 4.119QPCh. 4 - The energy needed for the following process is...Ch. 4 - Using your knowledge of the periodic trends with...Ch. 4 - Prob. 4.122QPCh. 4 - Prob. 4.123QPCh. 4 - Prob. 4.124QPCh. 4 - Explain, in terms of their electron...Ch. 4 - Prob. 4.126QPCh. 4 - Prob. 4.127QPCh. 4 - This graph charts the first six ionization...Ch. 4 - Prob. 4.129QPCh. 4 - Prob. 4.130QPCh. 4 - Prob. 4.131QPCh. 4 - Prob. 4.132QPCh. 4 - Predict the atomic number and ground-state...Ch. 4 - Prob. 4.134QPCh. 4 - Prob. 4.135QPCh. 4 - Prob. 4.136QPCh. 4 - The first six ionizations of a gaseous atom can be...Ch. 4 - Prob. 4.138QPCh. 4 - Prob. 4.139QPCh. 4 - Prob. 4.1KSPCh. 4 - Prob. 4.2KSPCh. 4 - Prob. 4.3KSPCh. 4 - Prob. 4.4KSP
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