CHEMISTRY: ATOMS FIRST VOL 1 W/CONNECT
14th Edition
ISBN: 9781259327933
Author: Burdge
Publisher: MCG
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Textbook Question
Chapter 4.4, Problem 5PPB
Explain why the EA1 for Ge is greater than the EA1 for As.
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What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Chapter 4 Solutions
CHEMISTRY: ATOMS FIRST VOL 1 W/CONNECT
Ch. 4.1 - Prob. 4.1WECh. 4.1 - Prob. 1PPACh. 4.1 - Prob. 1PPBCh. 4.1 - Prob. 1PPCCh. 4.1 - Prob. 4.1.1SRCh. 4.1 - Prob. 4.1.2SRCh. 4.1 - Prob. 4.1.3SRCh. 4.2 - Prob. 4.2WECh. 4.2 - Without using a periodic table, give the...Ch. 4.2 - Identify the elements represented by (a)...
Ch. 4.2 - Prob. 2PPCCh. 4.2 - Prob. 4.2.1SRCh. 4.2 - Prob. 4.2.2SRCh. 4.4 - Referring only to a periodic table, arrange the...Ch. 4.4 - Prob. 3PPACh. 4.4 - Prob. 3PPBCh. 4.4 - Prob. 3PPCCh. 4.4 - Prob. 4.4WECh. 4.4 - Which element. Mg or Al, will have the higher...Ch. 4.4 - Explain why Rb has a lower IE1 than Sr, but Sr has...Ch. 4.4 - Imagine an arrangement of atomic orbitals in an...Ch. 4.4 - For each pair of elements, indicate which one you...Ch. 4.4 - Prob. 5PPACh. 4.4 - Explain why the EA1 for Ge is greater than the EA1...Ch. 4.4 - In the same hypothetical arrangement described in...Ch. 4.4 - For carbon and nitrogen, use the effective nuclear...Ch. 4.4 - Between which two charges is the attractive force...Ch. 4.4 - What must the distance be between charges of +2.25...Ch. 4.4 - Rank these pairs of charged objects in order of...Ch. 4.4 - Prob. 4.4.1SRCh. 4.4 - Prob. 4.4.2SRCh. 4.4 - Prob. 4.4.3SRCh. 4.4 - Prob. 4.4.4SRCh. 4.4 - Prob. 4.4.5SRCh. 4.4 - Prob. 4.4.6SRCh. 4.5 - Write electron configurations for the following...Ch. 4.5 - Write electron configurations for (a) O2, (b)...Ch. 4.5 - Prob. 7PPBCh. 4.5 - Prob. 7PPCCh. 4.5 - Prob. 4.8WECh. 4.5 - Prob. 8PPACh. 4.5 - Prob. 8PPBCh. 4.5 - Select the correct valence orbital diagram for the...Ch. 4.5 - Prob. 4.5.1SRCh. 4.5 - Prob. 4.5.2SRCh. 4.5 - Prob. 4.5.3SRCh. 4.5 - Prob. 4.5.4SRCh. 4.5 - Prob. 4.5.5SRCh. 4.6 - Identify the isoelectronic series in the following...Ch. 4.6 - Arrange the following isoelectronic series in...Ch. 4.6 - List all the common ions that are isoelectronic...Ch. 4.6 - Prob. 9PPCCh. 4.6 - Prob. 4.6.1SRCh. 4.6 - Prob. 4.6.2SRCh. 4.6 - Prob. 4.6.3SRCh. 4.6 - Prob. 4.6.4SRCh. 4 - Briefly describe the significance of Mendeleevs...Ch. 4 - What is Moseleys contribution to the modem...Ch. 4 - Describe the general layout of a modern periodic...Ch. 4 - What is the most important relationship among...Ch. 4 - Prob. 4.5QPCh. 4 - Prob. 4.6QPCh. 4 - Prob. 4.7QPCh. 4 - Prob. 4.8QPCh. 4 - Without referring to a periodic table, write the...Ch. 4 - Prob. 4.10QPCh. 4 - Prob. 4.11QPCh. 4 - Prob. 4.12QPCh. 4 - For centuries, arsenic has been the poison of...Ch. 4 - In the periodic table, the element hydrogen is...Ch. 4 - An atom of a certain clement has 16 electrons....Ch. 4 - Prob. 4.16QPCh. 4 - Prob. 4.17QPCh. 4 - Prob. 4.18QPCh. 4 - Prob. 4.19QPCh. 4 - For each of the following ground-state electron...Ch. 4 - Determine what element is designated by each of...Ch. 4 - Prob. 4.22QPCh. 4 - Explain why there is a greater increase in...Ch. 4 - The election configuration of B is1s22s22p1. (a)...Ch. 4 - The election configuration of C is1s22s22p1. (a)...Ch. 4 - Prob. 4.26QPCh. 4 - Prob. 4.27QPCh. 4 - Equation 4.2 is used to calculate the force...Ch. 4 - Use the second period of the periodic table as an...Ch. 4 - Prob. 4.30QPCh. 4 - Prob. 4.31QPCh. 4 - Prob. 4.32QPCh. 4 - Prob. 4.33QPCh. 4 - Prob. 4.34QPCh. 4 - Prob. 4.35QPCh. 4 - Prob. 4.36QPCh. 4 - Prob. 4.37QPCh. 4 - Prob. 4.38QPCh. 4 - Prob. 4.39QPCh. 4 - Consider two ions with opposite charges separated...Ch. 4 - Prob. 4.41QPCh. 4 - Prob. 4.42QPCh. 4 - Prob. 4.43QPCh. 4 - On the basis of their positions in the periodic...Ch. 4 - Prob. 4.45QPCh. 4 - Prob. 4.46QPCh. 4 - Prob. 4.47QPCh. 4 - Prob. 4.48QPCh. 4 - Prob. 4.49QPCh. 4 - Prob. 4.50QPCh. 4 - Prob. 4.51QPCh. 4 - Prob. 4.52QPCh. 4 - In general, the first ionization energy increases...Ch. 4 - Prob. 4.54QPCh. 4 - Prob. 4.55QPCh. 4 - Prob. 4.56QPCh. 4 - Prob. 4.57QPCh. 4 - Prob. 4.58QPCh. 4 - Specify which of the following elements you would...Ch. 4 - Considering their electron affinities, do you...Ch. 4 - Prob. 4.61QPCh. 4 - Prob. 4.62QPCh. 4 - Prob. 4.63QPCh. 4 - Prob. 4.64QPCh. 4 - Prob. 4.65QPCh. 4 - Prob. 4.66QPCh. 4 - Prob. 4.67QPCh. 4 - Prob. 4.68QPCh. 4 - Prob. 4.69QPCh. 4 - Write the ground-state electron configurations of...Ch. 4 - Write the ground-state electron configurations of...Ch. 4 - Prob. 4.72QPCh. 4 - Prob. 4.73QPCh. 4 - Identify the ions, each with a net charge of +1,...Ch. 4 - Prob. 4.75QPCh. 4 - Prob. 4.76QPCh. 4 - Group the species that are isoelectronic: Be2+, F,...Ch. 4 - For each pair of ions, determine which will have...Ch. 4 - Rank the following ions in order of increasing...Ch. 4 - Prob. 4.80QPCh. 4 - Prob. 4.81QPCh. 4 - Prob. 4.82QPCh. 4 - A metal ion with a net +3 charge has five...Ch. 4 - Identify the atomic ground-state electron...Ch. 4 - Each of the following ground-state electron...Ch. 4 - Prob. 4.86QPCh. 4 - Prob. 4.87QPCh. 4 - Prob. 4.88QPCh. 4 - Indicate which one of the two species in each of...Ch. 4 - Prob. 4.90QPCh. 4 - Prob. 4.91QPCh. 4 - Prob. 4.92QPCh. 4 - Prob. 4.93QPCh. 4 - Prob. 4.94QPCh. 4 - Prob. 4.95QPCh. 4 - Prob. 4.96QPCh. 4 - Prob. 4.97QPCh. 4 - Prob. 4.98QPCh. 4 - Prob. 4.99QPCh. 4 - Prob. 4.100QPCh. 4 - Arrange the following species in isoelectronic...Ch. 4 - Prob. 4.102QPCh. 4 - Prob. 4.103QPCh. 4 - Prob. 4.104QPCh. 4 - Prob. 4.105QPCh. 4 - Prob. 4.106QPCh. 4 - Prob. 4.107QPCh. 4 - Prob. 4.108QPCh. 4 - Contrary to the generalized trend that atomic...Ch. 4 - Prob. 4.110QPCh. 4 - Prob. 4.111QPCh. 4 - Prob. 4.112QPCh. 4 - Prob. 4.113QPCh. 4 - Prob. 4.114QPCh. 4 - Prob. 4.115QPCh. 4 - Prob. 4.116QPCh. 4 - Prob. 4.117QPCh. 4 - Prob. 4.118QPCh. 4 - Prob. 4.119QPCh. 4 - The energy needed for the following process is...Ch. 4 - Using your knowledge of the periodic trends with...Ch. 4 - Prob. 4.122QPCh. 4 - Prob. 4.123QPCh. 4 - Prob. 4.124QPCh. 4 - Explain, in terms of their electron...Ch. 4 - Prob. 4.126QPCh. 4 - Prob. 4.127QPCh. 4 - This graph charts the first six ionization...Ch. 4 - Prob. 4.129QPCh. 4 - Prob. 4.130QPCh. 4 - Prob. 4.131QPCh. 4 - Prob. 4.132QPCh. 4 - Predict the atomic number and ground-state...Ch. 4 - Prob. 4.134QPCh. 4 - Prob. 4.135QPCh. 4 - Prob. 4.136QPCh. 4 - The first six ionizations of a gaseous atom can be...Ch. 4 - Prob. 4.138QPCh. 4 - Prob. 4.139QPCh. 4 - Prob. 4.1KSPCh. 4 - Prob. 4.2KSPCh. 4 - Prob. 4.3KSPCh. 4 - Prob. 4.4KSP
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