Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 4.4, Problem 4.12E

(a)

Interpretation Introduction

Interpretation:

Both the chair conformations for cis-1,2-dimethylcyclohexane is to be drawn and the compounds (compared with other given compounds) having equal numbers of axial and equatorial substituents are to be determined.

Concept Introduction:

The isomers are drawn on the basis of cis and trans-positions of the given compound, also in certain conformations, C-H bonds exist in two forms: vertical with the ring (axial) and peripheral with the ring (equatorial).

(b)

Interpretation Introduction

Interpretation:Both the chair conformations for trans-1,2-dimethylcyclohexane is to be drawn and should identify the compounds (compared with other given compounds) having equal numbers of axial and equatorial substituents.

Concept Introduction:The isomers are drawn on the basis of cis and trans-positions of the given compound, also in certain conformations, C-H bonds exist in two forms: vertical with the ring (axial) and peripheral with the ring (equatorial).

(c)

Interpretation Introduction

Interpretation:Both the chair conformations for cis-1,3-dimethylcyclohexane are to be drawn and the compounds (compared with other given compounds) having equal numbers of axial and equatorial substituents are to be determined.

Concept Introduction:The isomers are drawn on the basis of cis and trans-positions of the given compound, also in certain conformations, C-H bonds exist in two forms: vertical with the ring (axial) and peripheral with the ring (equatorial).

(d)

Interpretation Introduction

Interpretation:Both the chair conformations for trans-1,3-dimethylcyclohexane are to be drawn andthe compounds (compared with other given compounds) having equal numbers of axial and equatorial substituents are to be determined.

Concept Introduction:The isomers are drawn on the basis of cis and trans-positions of the given compound, also in certain conformations, C-H bonds exist in two forms: vertical with the ring (axial) and peripheral with the ring (equatorial).

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