Physics for Scientists and Engineers with Modern, Revised Hybrid (with Enhanced WebAssign Printed Access Card for Physics, Multi-Term Courses)
9th Edition
ISBN: 9781305266292
Author: Raymond A. Serway, John W. Jewett
Publisher: Cengage Learning
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Chapter 43, Problem 5P
(a)
To determine
The separation distance at which the energy of the molecule is minimum.
(b)
To determine
The energy required to break up the
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One description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential, U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. For the H2 molecule, take A = 0.124 x 10-120 eV ⋅ m12 and B = 1.488 x 10-60 eV ⋅ m6. Find (a) the separation distance r0 at which the energy of the molecule is a minimum and (b) the energy E required to break up theH2 molecule.
One model for the potential energy of a two-atom molecule, where the atoms are separated by a distance r, is
U(r) = Uo[(¹) ¹2 – ( )²]
where ro = 0.8 nm and U₁ = 6.1 eV.
Note: 1 eV = 1.6 × 10-19 J.
Some helpful units:
[Force] = eV/nm
[Energy] = eV
[distance] = nm
Equilibrium Distance
What is the distance between the atoms when the molecule is in stable equilibrium?
Click here for a hint
T'eq
Hint:
Hint:
Hint:
Hint:
Hint:
Hint:
Force
If the distance between the atoms increases from equilibrium by r₁ = 0.35 nm, then what is the force from one atom on the other associated with this potential energy? (Enter your answer as postive if they repel each other, and negative if they attract.)
Fr(req+r₁)
Hint:
Hint:
0.89105934nm
Kinetic Energy
Hint:
The atoms are oscillating back and forth. The maximum separation of the atoms is r₂ = 2 nm. What is the kinetic energy of the atoms when they are separated by the equilibrium distance?
Click here for a hint
K(req)
Hint:
Hint:
= -1.288eV/nm
3.99eV
One model for the potential energy of a two-atom molecule, where the atoms are separated by a distance r, is
U(r) = U₁[(¹)¹² – ()]
where ro = 0.8 nm and ₹₁ = 6.1 eV.
19
Note: 1 eV = 1.6 × 10-¹⁹ J.
Some helpful units:
[Force] = eV/nm
[Energy] = eV
[distance] = nm
Equilibrium Distance
What is the distance between the atoms when the molecule is in stable equilibrium?
Click here for a hint
req
Hint:
Hint:
Hint:
Hint:
Hint:
Force
If the distance between the atoms increases from equilibrium by r₁ = 0.35 nm, then what is the force from one atom on the other associated with this potential energy? (Enter your answer as
postive if they repel each other, and negative if they attract.)
Fr(req+r₁)
Hint:
0.89105934nm
Hint:
Chapter 43 Solutions
Physics for Scientists and Engineers with Modern, Revised Hybrid (with Enhanced WebAssign Printed Access Card for Physics, Multi-Term Courses)
Ch. 43.1 - For each of the following atoms or molecules,...Ch. 43.2 - Prob. 43.2QQCh. 43.2 - Prob. 43.3QQCh. 43 - Prob. 1OQCh. 43 - Prob. 2OQCh. 43 - Prob. 3OQCh. 43 - Prob. 4OQCh. 43 - Prob. 5OQCh. 43 - Prob. 6OQCh. 43 - Prob. 7OQ
Ch. 43 - Prob. 1CQCh. 43 - Prob. 2CQCh. 43 - Prob. 3CQCh. 43 - Prob. 4CQCh. 43 - Prob. 5CQCh. 43 - Prob. 6CQCh. 43 - Prob. 7CQCh. 43 - Prob. 8CQCh. 43 - Discuss models for the different types of bonds...Ch. 43 - Prob. 10CQCh. 43 - Prob. 1PCh. 43 - Prob. 2PCh. 43 - Prob. 3PCh. 43 - Prob. 4PCh. 43 - Prob. 5PCh. 43 - Prob. 6PCh. 43 - Prob. 7PCh. 43 - Prob. 8PCh. 43 - Prob. 9PCh. 43 - Prob. 10PCh. 43 - Prob. 12PCh. 43 - Prob. 13PCh. 43 - Prob. 14PCh. 43 - Prob. 15PCh. 43 - Prob. 16PCh. 43 - The nuclei of the O2 molecule are separated by a...Ch. 43 - Prob. 18PCh. 43 - Prob. 19PCh. 43 - Prob. 20PCh. 43 - Prob. 21PCh. 43 - Prob. 22PCh. 43 - Prob. 23PCh. 43 - Prob. 24PCh. 43 - Prob. 25PCh. 43 - Prob. 27PCh. 43 - Prob. 28PCh. 43 - Prob. 29PCh. 43 - Prob. 30PCh. 43 - Prob. 31PCh. 43 - Prob. 32PCh. 43 - Prob. 33PCh. 43 - Prob. 34PCh. 43 - Prob. 35PCh. 43 - Prob. 36PCh. 43 - Prob. 37PCh. 43 - Prob. 38PCh. 43 - Prob. 39PCh. 43 - Prob. 40PCh. 43 - Prob. 41PCh. 43 - Prob. 42PCh. 43 - Prob. 43PCh. 43 - Prob. 44PCh. 43 - Prob. 45PCh. 43 - Prob. 46PCh. 43 - Prob. 47PCh. 43 - Prob. 49PCh. 43 - Prob. 50PCh. 43 - Prob. 51PCh. 43 - A direct and relatively simple demonstration of...Ch. 43 - Prob. 53PCh. 43 - Prob. 54APCh. 43 - Prob. 55APCh. 43 - Prob. 56APCh. 43 - Prob. 57APCh. 43 - Prob. 58APCh. 43 - Prob. 59APCh. 43 - Prob. 61APCh. 43 - Prob. 62APCh. 43 - Prob. 63CPCh. 43 - As an alternative to Equation 43.1, another useful...
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