Physics for Scientists and Engineers with Modern, Revised Hybrid (with Enhanced WebAssign Printed Access Card for Physics, Multi-Term Courses)
9th Edition
ISBN: 9781305266292
Author: Raymond A. Serway, John W. Jewett
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 43, Problem 7OQ
To determine
To arrange the given energies from the largest in magnitude to smallest in magnitude for a typical material composed of covalently bonded diatomic molecules.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The potential energy of two atoms in a diatomic molecule is approximated by U(r) = a/r12-b/r6, where r is the spacing between atoms and a and b are positive constants.
Suppose the distance between the two atoms is equal to the equilibrium distance found in part A. What minimum energy must be added to the molecule to dissociate it -
that is, to separate the two atoms to an infinite distance apart? This is called the dissociation energy of the molecule. Express your answer in terms of the variables a and b.
For the molecule CO, the equilibrium distance between the carbon and oxygen atoms is 1.13\times 10-10m and the dissociation energy is 1.54\times 10-18J per
molecule. Find the value of the constant a. Express your answer in joules times meter in the twelth power. Find the value of the constant b. Express your answer in joules
times meter in the sixth power.
Q3: The potential energy function for the force between two atoms in
a diatomic molecule is approximately given by
U(x) = -
읆 옮
, where a and b are constant and x is the distance between the atoms. If the
dissociation energy of the molecule is (U(x= ∞) -U at equilibrium), D is
(a) b²/6a
(b) b²/2a
(c) b²/12a
(d) b²/4a
Nitrogen molecules are made of two nitrogen atoms with atomic weight of 14 each. Water molecules are made of one oxygen of 16 atomic mass units and two hydrogens of 1 atomic mass unit each. If you have one gram of each substance in vapor form, at high enough temperature that all molecular vibration and rotation modes are accessible, and the two substances are at the same temperature, what is the ratio of the total energy content of the nitrogen to that of the water?
Chapter 43 Solutions
Physics for Scientists and Engineers with Modern, Revised Hybrid (with Enhanced WebAssign Printed Access Card for Physics, Multi-Term Courses)
Ch. 43.1 - For each of the following atoms or molecules,...Ch. 43.2 - Prob. 43.2QQCh. 43.2 - Prob. 43.3QQCh. 43 - Prob. 1OQCh. 43 - Prob. 2OQCh. 43 - Prob. 3OQCh. 43 - Prob. 4OQCh. 43 - Prob. 5OQCh. 43 - Prob. 6OQCh. 43 - Prob. 7OQ
Ch. 43 - Prob. 1CQCh. 43 - Prob. 2CQCh. 43 - Prob. 3CQCh. 43 - Prob. 4CQCh. 43 - Prob. 5CQCh. 43 - Prob. 6CQCh. 43 - Prob. 7CQCh. 43 - Prob. 8CQCh. 43 - Discuss models for the different types of bonds...Ch. 43 - Prob. 10CQCh. 43 - Prob. 1PCh. 43 - Prob. 2PCh. 43 - Prob. 3PCh. 43 - Prob. 4PCh. 43 - Prob. 5PCh. 43 - Prob. 6PCh. 43 - Prob. 7PCh. 43 - Prob. 8PCh. 43 - Prob. 9PCh. 43 - Prob. 10PCh. 43 - Prob. 12PCh. 43 - Prob. 13PCh. 43 - Prob. 14PCh. 43 - Prob. 15PCh. 43 - Prob. 16PCh. 43 - The nuclei of the O2 molecule are separated by a...Ch. 43 - Prob. 18PCh. 43 - Prob. 19PCh. 43 - Prob. 20PCh. 43 - Prob. 21PCh. 43 - Prob. 22PCh. 43 - Prob. 23PCh. 43 - Prob. 24PCh. 43 - Prob. 25PCh. 43 - Prob. 27PCh. 43 - Prob. 28PCh. 43 - Prob. 29PCh. 43 - Prob. 30PCh. 43 - Prob. 31PCh. 43 - Prob. 32PCh. 43 - Prob. 33PCh. 43 - Prob. 34PCh. 43 - Prob. 35PCh. 43 - Prob. 36PCh. 43 - Prob. 37PCh. 43 - Prob. 38PCh. 43 - Prob. 39PCh. 43 - Prob. 40PCh. 43 - Prob. 41PCh. 43 - Prob. 42PCh. 43 - Prob. 43PCh. 43 - Prob. 44PCh. 43 - Prob. 45PCh. 43 - Prob. 46PCh. 43 - Prob. 47PCh. 43 - Prob. 49PCh. 43 - Prob. 50PCh. 43 - Prob. 51PCh. 43 - A direct and relatively simple demonstration of...Ch. 43 - Prob. 53PCh. 43 - Prob. 54APCh. 43 - Prob. 55APCh. 43 - Prob. 56APCh. 43 - Prob. 57APCh. 43 - Prob. 58APCh. 43 - Prob. 59APCh. 43 - Prob. 61APCh. 43 - Prob. 62APCh. 43 - Prob. 63CPCh. 43 - As an alternative to Equation 43.1, another useful...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, physics and related others by exploring similar questions and additional content below.Similar questions
- The v = 0 to v = 1 vibrational transition of the HI molecule occurs at a frequency of 6.69 × 1013 Hz. The same transition for the NO molecule occurs at a frequency of 5.63 × 1013 Hz. Calculate (a) the effective force constant and (b) the amplitude of vibration for each molecule. (c) Explain why the force constant of the NO molecule is so much larger than that of the HI molecule.arrow_forwardOne description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential, U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. Find, in terms of A and B, (a) the value r0 at which the energy is a minimum and (b) the energy E required to break up a diatomic molecule.arrow_forwardAn isolated LiCl molecule has its chloride ion (mass = 35 u) at x= 0 pm , and its lithium ion (7 u) at x = 202 pm. Where is the LiCl molecule's mass centered? 40.4 pm O 101 pm O o pm O +33.7 pm O 202 pm cannot determine with the information givenarrow_forward
- The binding energy of an electron in a hydrogen atom is 13.6 electron volts. At what temperature will the hydrogen atom’s adiabatic index start to rise, due to the electron and proton being two particles?arrow_forwardMost of the mass of an atom is in its nucleus. Model the mass distribution in a diatomic molecule as two spheres of uniform density, each of radius 2.00 x 10-15 m and mass 1.00 x 10-26 kg, located at points along the y axis as in 42.5a, and separated by 2.00 x 10-10 m. Rotation about the axis joining the nuclei in the diatomic molecule is ordinarily ignored because the first excited state would have an energy that is too high to access. To see why, calculate the ratio of the energy of the first excited state for rotation about the y axis to the energy of the first excited state for rotation about the x axis.arrow_forwardQ2. Transistors are manufactured by doping semiconductors. The diffusion coefficient of phosphorus in Si is D = 6.5 x 10-11 mm2/s at a temperature of 950°C. Assume the source provides a surface concentration of 1020 atoms/cm3 and the diffusion time is one hour. Assume that the silicon wafer initially contains no phosphorus. Calculate the depth at which the concentration of phosphorus will be 1018 atoms/cm3.arrow_forward
- A rigid tank of volume V = 0.02 m3 contains carbon monoxide at a temperature of T0 = 25° C and a pressure of P0 = 9.00 × 105 Pa. This molecule should be treated as a diatomic ideal gas with active vibrational modes. a)The temperature of the gas increases by 10° C. Calculate the pressure of the gas in pascal at this increased temperature. b)Calculate the change to the internal energy of the gas in joules. c)Calculate the change in the entropy of the gas in joules per kelvin.arrow_forwardWhat is the mean free path of molecules in an ideal gas in which the mean collision time is 4.00 × 10-10 s, the temperature is 294K, and the mass of the molecules is 6.00 × 10-25 kg? Assume that the molecules are moving at their root-mean-square speeds. The Boltzmann constant is 1.38 × 10-23 J/K. GIve your answer in Angstroms ( 1 Angstrom = 10-10 m)arrow_forwardThe average thermal energy for a mono-atomic gas is: (kB is Boltzmann constant and T, absolute temperature) kBT kBT kBTarrow_forward
- the vibrational frequency of I2 is 214.5 cm-1. (i) Using the harmonic oscillator model, evaluate the vibrational partition function and the mean vibrational energy of I2 at 1000K. (ii) What is the characteristic vibrational temperature of I2? (iii) At 1000K, assuming high-temperature approximation, evaluate the vibrational partition function and the mean vibrational energy of I2. (iv) Comparing (i) and (iii), is the high-temperature approximation good for I2 at 1000K?arrow_forwardOne description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential, U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. For the H2 molecule, take A = 0.124 x 10-120 eV ⋅ m12 and B = 1.488 x 10-60 eV ⋅ m6. Find (a) the separation distance r0 at which the energy of the molecule is a minimum and (b) the energy E required to break up theH2 molecule.arrow_forwardThe temperature of 2.00 moles of argon gas is lowered from 2.60 102 K to 2.30 102 K. (a) Find the change in the internal energy, ΔU, of the gas. ____________ J(b) Find the change in the average kinetic energy per atom. ____________ Jarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physics for Scientists and Engineers with Modern ...PhysicsISBN:9781337553292Author:Raymond A. Serway, John W. JewettPublisher:Cengage LearningPrinciples of Physics: A Calculus-Based TextPhysicsISBN:9781133104261Author:Raymond A. Serway, John W. JewettPublisher:Cengage LearningPhysics for Scientists and Engineers: Foundations...PhysicsISBN:9781133939146Author:Katz, Debora M.Publisher:Cengage Learning
- Modern PhysicsPhysicsISBN:9781111794378Author:Raymond A. Serway, Clement J. Moses, Curt A. MoyerPublisher:Cengage LearningCollege PhysicsPhysicsISBN:9781285737027Author:Raymond A. Serway, Chris VuillePublisher:Cengage Learning
Physics for Scientists and Engineers with Modern ...
Physics
ISBN:9781337553292
Author:Raymond A. Serway, John W. Jewett
Publisher:Cengage Learning
Principles of Physics: A Calculus-Based Text
Physics
ISBN:9781133104261
Author:Raymond A. Serway, John W. Jewett
Publisher:Cengage Learning
Physics for Scientists and Engineers: Foundations...
Physics
ISBN:9781133939146
Author:Katz, Debora M.
Publisher:Cengage Learning
Modern Physics
Physics
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Cengage Learning
College Physics
Physics
ISBN:9781285737027
Author:Raymond A. Serway, Chris Vuille
Publisher:Cengage Learning