CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
4th Edition
ISBN: 9781260562620
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 4.2, Problem 4.2PP
Draw a Lewis structure for each covalent molecule.
- HBr
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 4 Solutions
CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
Ch. 4.1 - Use electron-dot symbols to show how a hydrogen...Ch. 4.1 - Use electron-dot symbols to show how two chlorine...Ch. 4.1 - How many covalent bonds are predicted for each...Ch. 4.1 - Fill in the lone pairs on each atom to give every...Ch. 4.1 - Prob. 4.4PCh. 4.2 - Draw a Lewis structure for each covalent molecule....Ch. 4.2 - Draw a Lewis structure for dimethyl ether (C2H6O)...Ch. 4.2 - Prob. 4.4PPCh. 4.2 - Prob. 4.5PCh. 4.2 - Prob. 4.6P
Ch. 4.3 - Prob. 4.7PCh. 4.3 - Prob. 4.8PCh. 4.4 - Prob. 4.5PPCh. 4.4 - Draw resonance structures for each polyatomic...Ch. 4.4 - Nitrous oxide, N2O, is a sweet-smelling gas...Ch. 4.5 - Name each compound: (a) CS2; (b) SO2; (c) PCl5;...Ch. 4.5 - Prob. 4.6PPCh. 4.6 - What is the shape around the indicated atom in...Ch. 4.6 - NaNH2, sodium amid, is a salt that contains a...Ch. 4.6 - Prob. 4.13PCh. 4.7 - Using the trends in the periodic table, rank the...Ch. 4.7 - Use electronegativity values to classify the...Ch. 4.8 - Label the polar bonds in each molecule, and then...Ch. 4.9 - Label the polar bonds in each molecule, and then...Ch. 4.9 - Use the ball-and-stick model of dihydrocapsaicin...Ch. 4 - For each pair of compounds, classify the bonding...Ch. 4 - For each pair of compounds, classify the bonding...Ch. 4 - Prob. 17PCh. 4 - How many bonds and lone pairs are typically...Ch. 4 - Prob. 19PCh. 4 - Fill in the lone pairs needed to give the main...Ch. 4 - Prob. 21PCh. 4 - Convert the 3-D model of the general anesthetic...Ch. 4 - Draw a valid Lewis structure for each molecule. Hl...Ch. 4 - Draw a valid Lewis structure for each molecule....Ch. 4 - Prob. 25PCh. 4 - Prob. 26PCh. 4 - Draw a valid Lewis structure for...Ch. 4 - Draw a valid Lewis structure for phosgene, CCl2O ,...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Prob. 31PCh. 4 - Keeping in mind that some elements violate the...Ch. 4 - Prob. 33PCh. 4 - Prob. 34PCh. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - Prob. 37PCh. 4 - Label each pair of compounds are resonance...Ch. 4 - Prob. 39PCh. 4 - Draw three resonance structures for the nitrate...Ch. 4 - Name each covalent compound. PBr3 SO3 NCl3 P2S5Ch. 4 - Name each covalent compound. SF6 CBr4 N2O P4O10Ch. 4 - Prob. 43PCh. 4 - Prob. 44PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 47PCh. 4 - Match each compound with one of the molecular...Ch. 4 - Prob. 49PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 51PCh. 4 - Considering each of the given ball-and stick...Ch. 4 - Prob. 53PCh. 4 - Prob. 54PCh. 4 - Prob. 55PCh. 4 - Predict the bond angles around the indicated atoms...Ch. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - Rank the atoms in each group in order of...Ch. 4 - Prob. 60PCh. 4 - Prob. 61PCh. 4 - Identify elements D, E, and F and rank them in...Ch. 4 - Prob. 63PCh. 4 - Using electronegativity values, classify the bond...Ch. 4 - Label the bond formed between carbon and each of...Ch. 4 - Label the bond formed between fluroine and each of...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Prob. 69PCh. 4 - Prob. 70PCh. 4 - Label the polar bonds and then decide if each...Ch. 4 - Label the polar bonds and then decide if each...Ch. 4 - Prob. 73PCh. 4 - Explain why H2O is a polar molecule but H2S is...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Answer the following questions about the molecule...Ch. 4 - Answer the following question about the molecule...Ch. 4 - Prob. 79PCh. 4 - Lactic acid gives sour milk its distinctive taste....Ch. 4 - Use the ball-and-stick model of zingerone, a...Ch. 4 - Prob. 82PCh. 4 - Prob. 83PCh. 4 - Prob. 84PCh. 4 - Isobutyl cyanoacrylate is used in medical glues to...Ch. 4 - Prob. 86PCh. 4 - Cyclopropane is a stable compound that contains...Ch. 4 - Prob. 88CPCh. 4 - Prob. 89CPCh. 4 - Prob. 90CP
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