The reason should be explained for the given compound has four stereoisomers when it has only one asymmetric center. Concept introduction: The total number of stereoisomers can be calculated by using following formula, The total number of stereoisomers = 2 n n = number of chiral carbon Cis – trans isomerism (or) geometric isomerism or configurational isomerism: The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z -isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E -isomer). Example:

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Answer 1

Question

Chapter 4, Problem 64P

Interpretation Introduction

Interpretation:

The reason should be explained for the given compound has four stereoisomers when it has only one asymmetric center.

Concept introduction:

The total number of stereoisomers can be calculated by using following formula,

The total number of stereoisomers = 2nn = number of chiral carbon

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

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What is the maximum number of stereoisomers possible for a compound with: (a) three stereogenic centers; (b) eight stereogenic centers?

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The following compound has only one asymmetric center. Why then does it have four stereoisomers? CH3CH2CH-BrCH2CH=CHCH3

Answer 2

Question

Chapter 4, Problem 64P

Interpretation Introduction

Interpretation:

The reason should be explained for the given compound has four stereoisomers when it has only one asymmetric center.

Concept introduction:

The total number of stereoisomers can be calculated by using following formula,

The total number of stereoisomers = 2nn = number of chiral carbon

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

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Answer 3

Question

Chapter 4, Problem 64P

Interpretation Introduction

Interpretation:

The reason should be explained for the given compound has four stereoisomers when it has only one asymmetric center.

Concept introduction:

The total number of stereoisomers can be calculated by using following formula,

The total number of stereoisomers = 2nn = number of chiral carbon

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

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Answer 4

Question

Chapter 4, Problem 64P

Interpretation Introduction

Interpretation:

The reason should be explained for the given compound has four stereoisomers when it has only one asymmetric center.

Concept introduction:

The total number of stereoisomers can be calculated by using following formula,

The total number of stereoisomers = 2nn = number of chiral carbon

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

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Answer 5

Chapter 4, Problem 64P

Interpretation Introduction

Interpretation:

The reason should be explained for the given compound has four stereoisomers when it has only one asymmetric center.

Concept introduction:

The total number of stereoisomers can be calculated by using following formula,

The total number of stereoisomers = 2nn = number of chiral carbon

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

Answer 6

Chapter 4, Problem 64P

Interpretation Introduction

Interpretation:

The reason should be explained for the given compound has four stereoisomers when it has only one asymmetric center.

Concept introduction:

The total number of stereoisomers can be calculated by using following formula,

The total number of stereoisomers = 2nn = number of chiral carbon

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

Answer 7

Chapter 4, Problem 64P

Interpretation Introduction

Interpretation:

The reason should be explained for the given compound has four stereoisomers when it has only one asymmetric center.

Concept introduction:

The total number of stereoisomers can be calculated by using following formula,

The total number of stereoisomers = 2nn = number of chiral carbon

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 4.1 - Draw the cis and trans isomers for the following:...Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.1 - Prob. 6P Ch. 4.2 - Prob. 7P Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Prob. 10P Ch. 4.2 - Name each of the following:Ch. 4.2 - Draw the structure of (Z)-2,3-dimethyl-3-heptene.

Solution Summary: The author explains that the given compound has four stereoisomers when it has only one asymmetric center.

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Chapter 4 Solutions