14. Which one of the compounds below is the major organic product obtained from the following series of reactions? Br OH OH CH3O™ Na+ H*, H₂O SN2 HO OH A B C D 0 E
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- An important step in one synthesis of carboxylic acids is the deprotonation of diethyl malonate and its alkyl-substituted derivative: Base CH;CH2O OCH,CH3 CH;CH,0 OCH2CH3 H2 Diethyl malonate Base CH;CH,0 °C `OCH,CH3 CH;CH,O OCH,CH3 R Alkyl substituted diethyl malonate NaOH can deprotonate diethyl malonate effectively, but NaOC(CH3)3 is typically used to deprotonate the alkyl-substituted derivative. Explain why.Write the chemical formula for diarsenic trioxide 14- 3+ 4+ 1 4 9. (s) (1) (g) (aq) As An Ar Ox Reset • x H2O Delete 3, 2.The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?
- Provide reactants, reagents, and/or products for the followin NH2 + HWhich of the following reactions will not yield a carboxylic acid as a product? он (B) owool CrO3/H,0 (1) Oz/CH;Ch, -78°C (1) Mg, ether, A (A) Br (C) (2) H20 (2) CO2 (3) H* (dil /H¿O он H* /H2O A (D) Reaction D Reaction A Reaction CClaisen condensation between diethyl phthalate and ethyl acetate followed by saponifi- cation, acidification, and decarboxylation forms a diketone, C,H,O,. COOEt 1. EtO Na+ HCI, H,O B NaOH, H,O + CH3COOEt C,H,O2 2. НС, Н,О heat heat COOEt Diethyl phthalate Ethyl acetate Propose structural formulas for compounds A and B and the diketone.
- Give the major organic product(s) for each of the following reactions. Write NR if a reaction will not occur.Methyllithium (CH3Li) is often used as a base in organic reactions. Predict the products of the following acid-base reaction.CH3CH2¬OH + CH3¬Li ¡Draw the organic products of the following reaction