24) A reaction proceeds by a series of elementary steps as shown below. The activation energy and heat of reaction are shown for each step. Step Number 1 Elementary Step Activation Energy Enthalpy of Reaction A+ B2 AB2 4 kJ/mol -10 kJ/mol 2 AB2C2 ABC + BC 30 kJ/mol 3 ABC + B2 → AB₂+ BC 10 kJ/mol +5.2 kJ/mol -7.8 kJ/mol a. What is the overall equation for the reaction? b. What is the heat of reaction for the overall equation? C. What is the rate determining step? d. Draw an energy profile for the overall reaction showing the enthalpies of each step, the overall enthalpy, as well as the activation energies of each step.
24) A reaction proceeds by a series of elementary steps as shown below. The activation energy and heat of reaction are shown for each step. Step Number 1 Elementary Step Activation Energy Enthalpy of Reaction A+ B2 AB2 4 kJ/mol -10 kJ/mol 2 AB2C2 ABC + BC 30 kJ/mol 3 ABC + B2 → AB₂+ BC 10 kJ/mol +5.2 kJ/mol -7.8 kJ/mol a. What is the overall equation for the reaction? b. What is the heat of reaction for the overall equation? C. What is the rate determining step? d. Draw an energy profile for the overall reaction showing the enthalpies of each step, the overall enthalpy, as well as the activation energies of each step.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 118QRT
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