Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 4, Problem 4.18P
Interpretation Introduction

Interpretation:

Whether the given sets of measurements gives equivalent results are not has to be explained using spreadsheet calculations.

Concept Introduction:

Comparison of Standard Deviation with F Test:

For the comparison of mean values of two sets of measurements, we decide whether the standard deviations of the two sets are “statistically different”. This is done by F test.

The F test with quotient F is given as:

Fcalculated=s12s22

Where, s1 and s2 are standard deviations for the set of measurements using original instrument and substitute instrument.

If Fcalculated>Ftable , then the difference is significant.

Degrees of Freedom:

For a n set of measurement, the degrees of freedom will be (n1)

Comparing replicate measurements:

When the standard deviations of two sets of measurements are significantly different, the equations used are:

tcalculated =|x1¯x2¯|(s12/n1+s22/n2)Degrees of freedom =(s12/n1+s22/n2)2(s12/n1)2n11+(s22/n2)2n21 =(u12+u22)2u14n11+u24n21

To Give: Whether the given sets of measurements gives equivalent results using spreadsheet calculations.

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