Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 4, Problem 4.17P
Interpretation Introduction

Interpretation:

Whether the given standard deviations and given means of two methods are significantly different or not has to be given.

Concept Introduction:

Comparison of Standard Deviation with F Test:

For the comparison of mean values of two sets of measurements, we decide whether the standard deviations of the two sets are “statistically different”. This is done by F test.

The F test with quotient F is given as:

Fcalculated=s12s22

Where, s1 and s2 are standard deviations for the set of measurements using original instrument and substitute instrument.

If Fcalculated>Ftable , then the difference is significant.

Degrees of Freedom:

For a n set of measurement, the degrees of freedom will be (n1)

Comparing Means of replicate measurements:

When the two standard deviations are not significantly different from each other, the equation used is:

t test for comparison of means: t=|x1¯x2¯|(spooled)n1n2n1+n2 (since spooled=s12(n11)+s22(n21)n1+n22)

To Give: Whether the given standard deviations and given means of two methods are significantly different or not.

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