Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
Question
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Chapter 4, Problem 4.EE

(a)

Interpretation Introduction

Interpretation:

The mean, standard deviation and standard uncertainty for each of the given analysis has to be calculated.

Concept Introduction:

Mean:

The Mean or the arithmetic mean ( x¯ ) is given as the summation of measured values divided by the number of measurements (n). Mean is also called as average.

x¯=ixin

Standard deviation:

Standard deviation measures how closely the data are clustered about the mean.

The standard deviation (s) is given by the formula:

s=i(xix¯)2n1

Standard deviation of the mean: (Standard uncertainty)

Standard deviation of the mean of sets of n values is:

σn=σn

To Compute: The mean and standard deviation of a given column of numbers in two different ways using spreadsheet.

(b)

Interpretation Introduction

Interpretation:

Whether the standard deviation differ significantly at the 95% confidence level has to be given.

Concept Introduction:

Comparison of Standard Deviation with F Test:

For the comparison of mean values of two sets of measurements, we decide whether the standard deviations of the two sets are “statistically different”. This is done by F test.

The F test with quotient F is given as:

Fcalculated=s12s22

Where, s1 and s2 are standard deviations for the set of measurements using original instrument and substitute instrument.

If Fcalculated>Ftable , then the difference is significant.

Degrees of Freedom:

For a n set of measurement, the degrees of freedom will be (n1)

To Give: Whether the standard deviation differ significantly at the 95% confidence level

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