Chemistry Atoms First, Second Edition
2nd Edition
ISBN: 9781308211657
Author: Burdge
Publisher: McGraw Hill
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Textbook Question
Chapter 4, Problem 4.121QP
Using your knowledge of the periodic trends with size, identify these spheres based on their relative sizes as Rb, Rb+, Mg, F−, and F.
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B 1 of 2
Additional problems in preparation to Midterm #1:
1.) How can the following compounds be prepared using Diels-Alder reaction:
CH3 O
CN
(a)
(b)
CN
CH3
2.) What is the missing reagent in the shown reaction?
H3C
+ ?
H3C
H3C
CN
H3C
''CN
(၁)
H
3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene.
Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen.
4.) In the shown reaction, which will be the kinetic product and which will be the
thermodynamic product?
H3C
CI
H3C
HCI
H3C
+
5.) Which of the following molecules is aromatic?
(a)
(b)
(c)
H
6.) Which of the following molecules is aromatic?
(a)
(b)
(c)
7.) Write the mechanism for the shown reaction.
+
Ха
AICI 3
CI
8.) Suggest reagents that would convert benzene into the shown compounds.
CI
NO2
-8-6-6-8-a
(a)
(b)
(c)
(d)
(e)
(a)
SO3H
Br
The number of 2sp^2 hybridized atoms in is: A. 8; B. 6; C.4; D.2; E.0;
Chapter 4 Solutions
Chemistry Atoms First, Second Edition
Ch. 4.1 - Prob. 4.1WECh. 4.1 - Prob. 1PPACh. 4.1 - Prob. 1PPBCh. 4.1 - Prob. 1PPCCh. 4.1 - Prob. 4.1.1SRCh. 4.1 - Prob. 4.1.2SRCh. 4.1 - Prob. 4.1.3SRCh. 4.2 - Prob. 4.2WECh. 4.2 - Without using a periodic table, give the...Ch. 4.2 - Identify the elements represented by (a)...
Ch. 4.2 - Prob. 2PPCCh. 4.2 - Prob. 4.2.1SRCh. 4.2 - Prob. 4.2.2SRCh. 4.4 - Referring only to a periodic table, arrange the...Ch. 4.4 - Prob. 3PPACh. 4.4 - Prob. 3PPBCh. 4.4 - Prob. 3PPCCh. 4.4 - Prob. 4.4WECh. 4.4 - Which element. Mg or Al, will have the higher...Ch. 4.4 - Explain why Rb has a lower IE1 than Sr, but Sr has...Ch. 4.4 - Imagine an arrangement of atomic orbitals in an...Ch. 4.4 - For each pair of elements, indicate which one you...Ch. 4.4 - Prob. 5PPACh. 4.4 - Explain why the EA1 for Ge is greater than the EA1...Ch. 4.4 - In the same hypothetical arrangement described in...Ch. 4.4 - For carbon and nitrogen, use the effective nuclear...Ch. 4.4 - Between which two charges is the attractive force...Ch. 4.4 - What must the distance be between charges of +2.25...Ch. 4.4 - Rank these pairs of charged objects in order of...Ch. 4.4 - Prob. 4.4.1SRCh. 4.4 - Prob. 4.4.2SRCh. 4.4 - Prob. 4.4.3SRCh. 4.4 - Prob. 4.4.4SRCh. 4.4 - Prob. 4.4.5SRCh. 4.4 - Prob. 4.4.6SRCh. 4.5 - Write electron configurations for the following...Ch. 4.5 - Write electron configurations for (a) O2, (b)...Ch. 4.5 - Prob. 7PPBCh. 4.5 - Prob. 7PPCCh. 4.5 - Prob. 4.8WECh. 4.5 - Prob. 8PPACh. 4.5 - Prob. 8PPBCh. 4.5 - Select the correct valence orbital diagram for the...Ch. 4.5 - Prob. 4.5.1SRCh. 4.5 - Prob. 4.5.2SRCh. 4.5 - Prob. 4.5.3SRCh. 4.5 - Prob. 4.5.4SRCh. 4.5 - Prob. 4.5.5SRCh. 4.6 - Identify the isoelectronic series in the following...Ch. 4.6 - Arrange the following isoelectronic series in...Ch. 4.6 - List all the common ions that are isoelectronic...Ch. 4.6 - Prob. 9PPCCh. 4.6 - Prob. 4.6.1SRCh. 4.6 - Prob. 4.6.2SRCh. 4.6 - Prob. 4.6.3SRCh. 4.6 - Prob. 4.6.4SRCh. 4 - Briefly describe the significance of Mendeleevs...Ch. 4 - What is Moseleys contribution to the modem...Ch. 4 - Describe the general layout of a modern periodic...Ch. 4 - What is the most important relationship among...Ch. 4 - Prob. 4.5QPCh. 4 - Prob. 4.6QPCh. 4 - Prob. 4.7QPCh. 4 - Prob. 4.8QPCh. 4 - Without referring to a periodic table, write the...Ch. 4 - Prob. 4.10QPCh. 4 - Prob. 4.11QPCh. 4 - Prob. 4.12QPCh. 4 - For centuries, arsenic has been the poison of...Ch. 4 - In the periodic table, the element hydrogen is...Ch. 4 - An atom of a certain clement has 16 electrons....Ch. 4 - Prob. 4.16QPCh. 4 - Prob. 4.17QPCh. 4 - Prob. 4.18QPCh. 4 - Prob. 4.19QPCh. 4 - For each of the following ground-state electron...Ch. 4 - Determine what element is designated by each of...Ch. 4 - Prob. 4.22QPCh. 4 - Explain why there is a greater increase in...Ch. 4 - The election configuration of B is1s22s22p1. (a)...Ch. 4 - The election configuration of C is1s22s22p1. (a)...Ch. 4 - Prob. 4.26QPCh. 4 - Prob. 4.27QPCh. 4 - Equation 4.2 is used to calculate the force...Ch. 4 - Use the second period of the periodic table as an...Ch. 4 - Prob. 4.30QPCh. 4 - Prob. 4.31QPCh. 4 - Prob. 4.32QPCh. 4 - Prob. 4.33QPCh. 4 - Prob. 4.34QPCh. 4 - Prob. 4.35QPCh. 4 - Prob. 4.36QPCh. 4 - Prob. 4.37QPCh. 4 - Prob. 4.38QPCh. 4 - Prob. 4.39QPCh. 4 - Consider two ions with opposite charges separated...Ch. 4 - Prob. 4.41QPCh. 4 - Prob. 4.42QPCh. 4 - Prob. 4.43QPCh. 4 - On the basis of their positions in the periodic...Ch. 4 - Prob. 4.45QPCh. 4 - Prob. 4.46QPCh. 4 - Prob. 4.47QPCh. 4 - Prob. 4.48QPCh. 4 - Prob. 4.49QPCh. 4 - Prob. 4.50QPCh. 4 - Prob. 4.51QPCh. 4 - Prob. 4.52QPCh. 4 - In general, the first ionization energy increases...Ch. 4 - Prob. 4.54QPCh. 4 - Prob. 4.55QPCh. 4 - Prob. 4.56QPCh. 4 - Prob. 4.57QPCh. 4 - Prob. 4.58QPCh. 4 - Specify which of the following elements you would...Ch. 4 - Considering their electron affinities, do you...Ch. 4 - Prob. 4.61QPCh. 4 - Prob. 4.62QPCh. 4 - Prob. 4.63QPCh. 4 - Prob. 4.64QPCh. 4 - Prob. 4.65QPCh. 4 - Prob. 4.66QPCh. 4 - Prob. 4.67QPCh. 4 - Prob. 4.68QPCh. 4 - Prob. 4.69QPCh. 4 - Write the ground-state electron configurations of...Ch. 4 - Write the ground-state electron configurations of...Ch. 4 - Prob. 4.72QPCh. 4 - Prob. 4.73QPCh. 4 - Identify the ions, each with a net charge of +1,...Ch. 4 - Prob. 4.75QPCh. 4 - Prob. 4.76QPCh. 4 - Group the species that are isoelectronic: Be2+, F,...Ch. 4 - For each pair of ions, determine which will have...Ch. 4 - Rank the following ions in order of increasing...Ch. 4 - Prob. 4.80QPCh. 4 - Prob. 4.81QPCh. 4 - Prob. 4.82QPCh. 4 - A metal ion with a net +3 charge has five...Ch. 4 - Identify the atomic ground-state electron...Ch. 4 - Each of the following ground-state electron...Ch. 4 - Prob. 4.86QPCh. 4 - Prob. 4.87QPCh. 4 - Prob. 4.88QPCh. 4 - Indicate which one of the two species in each of...Ch. 4 - Prob. 4.90QPCh. 4 - Prob. 4.91QPCh. 4 - Prob. 4.92QPCh. 4 - Prob. 4.93QPCh. 4 - Prob. 4.94QPCh. 4 - Prob. 4.95QPCh. 4 - Prob. 4.96QPCh. 4 - Prob. 4.97QPCh. 4 - Prob. 4.98QPCh. 4 - Prob. 4.99QPCh. 4 - Prob. 4.100QPCh. 4 - Arrange the following species in isoelectronic...Ch. 4 - Prob. 4.102QPCh. 4 - Prob. 4.103QPCh. 4 - Prob. 4.104QPCh. 4 - Prob. 4.105QPCh. 4 - Prob. 4.106QPCh. 4 - Prob. 4.107QPCh. 4 - Prob. 4.108QPCh. 4 - Contrary to the generalized trend that atomic...Ch. 4 - Prob. 4.110QPCh. 4 - Prob. 4.111QPCh. 4 - Prob. 4.112QPCh. 4 - Prob. 4.113QPCh. 4 - Prob. 4.114QPCh. 4 - Prob. 4.115QPCh. 4 - Prob. 4.116QPCh. 4 - Prob. 4.117QPCh. 4 - Prob. 4.118QPCh. 4 - Prob. 4.119QPCh. 4 - The energy needed for the following process is...Ch. 4 - Using your knowledge of the periodic trends with...Ch. 4 - Prob. 4.122QPCh. 4 - Prob. 4.123QPCh. 4 - Prob. 4.124QPCh. 4 - Explain, in terms of their electron...Ch. 4 - Prob. 4.126QPCh. 4 - Prob. 4.127QPCh. 4 - This graph charts the first six ionization...Ch. 4 - Prob. 4.129QPCh. 4 - Prob. 4.130QPCh. 4 - Prob. 4.131QPCh. 4 - Prob. 4.132QPCh. 4 - Predict the atomic number and ground-state...Ch. 4 - Prob. 4.134QPCh. 4 - Prob. 4.135QPCh. 4 - Prob. 4.136QPCh. 4 - The first six ionizations of a gaseous atom can be...Ch. 4 - Prob. 4.138QPCh. 4 - Prob. 4.139QPCh. 4 - Prob. 4.1KSPCh. 4 - Prob. 4.2KSPCh. 4 - Prob. 4.3KSPCh. 4 - Prob. 4.4KSP
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