Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
2nd Edition
ISBN: 9781337086431
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 4, Problem 25E
Interpretation Introduction
Interpretation: The molecular structure of given compound is to be predicted from given structures.
Concept introduction: Molecular structure is a three-dimensional shape of a molecule.
Bond angle is the angle between atoms of molecule.
To determine: The correct molecular structure of
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
:☐
G
x
c
olo
Ar
HE
Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
فا
Explanation
Check
Click and drag to start drawing a
structure.
Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers.
OH
OH
OH
OH
OH
OH
Chapter 4 Solutions
Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
Ch. 4 - Explain the main postulate of the VSEPR model....Ch. 4 - Explain why CF4 and Xef4 are nonpolar compounds...Ch. 4 - Consider the following compounds: CO2, SO2, KrF2,...Ch. 4 - Prob. 4RQCh. 4 - What hybridization is required for central atoms...Ch. 4 - Prob. 6RQCh. 4 - Prob. 7RQCh. 4 - What are molecular orbitals? How do they compare...Ch. 4 - Explain the difference between the and MOs for...Ch. 4 - Prob. 3ALQ
Ch. 4 - Which of the following would you expect to be more...Ch. 4 - Arrange the following molecules from most to least...Ch. 4 - Which is the more correct statement: The methane...Ch. 4 - Prob. 7ALQCh. 4 - Prob. 8ALQCh. 4 - Which of the following statements is/are true?...Ch. 4 - Give one example of a compound having a linear...Ch. 4 - In the hybrid orbital model, compare and contrast ...Ch. 4 - Prob. 13QCh. 4 - Prob. 14QCh. 4 - Prob. 15QCh. 4 - Prob. 16QCh. 4 - Compare and contrast bonding molecular orbitals...Ch. 4 - Prob. 18QCh. 4 - Why does the molecular orbital model do a better...Ch. 4 - The three NO bonds in NO3 are all equivalent in...Ch. 4 - Predict the molecular structure (including bond...Ch. 4 - Predict the molecular structure (including bond...Ch. 4 - Predict the molecular structure and bond angles...Ch. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Two variations of the octahedral geometry (see...Ch. 4 - Predict the molecular structure (including bond...Ch. 4 - Predict the molecular structure (including bond...Ch. 4 - State whether or not each of the following has a...Ch. 4 - The following electrostatic potential diagrams...Ch. 4 - Which of the molecules in Exercises 21 and 22 have...Ch. 4 - Which of the molecules in Exercises 27 and 28 have...Ch. 4 - Write Lewis structures and predict the molecular...Ch. 4 - Write Lewis structures and predict whether each of...Ch. 4 - Consider the following Lewis structure where E is...Ch. 4 - Consider the following Lewis structure where E is...Ch. 4 - The molecules BF3, CF4, CO2, PF5, and SF6 are all...Ch. 4 - Two different compounds have the formula XeF2Cl2....Ch. 4 - Use the localized electron model to describe the...Ch. 4 - Use the localized electron model to describe the...Ch. 4 - Use the localized electron model to describe the...Ch. 4 - Use the localized electron model to describe the...Ch. 4 - The space-filling models of ethane and ethanol are...Ch. 4 - The space-filling models of hydrogen cyanide and...Ch. 4 - Prob. 45ECh. 4 - Prob. 46ECh. 4 - Prob. 47ECh. 4 - Give the expected hybridization of the central...Ch. 4 - For each of the following molecules, write the...Ch. 4 - For each of the following molecules or ions that...Ch. 4 - Prob. 51ECh. 4 - The allene molecule has the following Lewis...Ch. 4 - Indigo is the dye used in coloring blue jeans. The...Ch. 4 - Prob. 54ECh. 4 - Prob. 55ECh. 4 - Many important compounds in the chemical industry...Ch. 4 - Two molecules used in the polymer industry are...Ch. 4 - Hot and spicy foods contain molecules that...Ch. 4 - One of the first drugs to be approved for use in...Ch. 4 - The antibiotic thiarubin-A was discovered by...Ch. 4 - Prob. 61ECh. 4 - Sketch the molecular orbital and label its type (...Ch. 4 - Prob. 63ECh. 4 - Which of the following are predicted by the...Ch. 4 - Prob. 65ECh. 4 - Prob. 66ECh. 4 - Prob. 67ECh. 4 - Using the molecular orbital model to describe the...Ch. 4 - Prob. 69ECh. 4 - A Lewis structure obeying the octet rule can be...Ch. 4 - Using the molecular orbital model, write electron...Ch. 4 - Using the molecular orbital model, write electron...Ch. 4 - In which of the following diatomic molecules would...Ch. 4 - In terms of the molecular orbital model, which...Ch. 4 - Prob. 75ECh. 4 - Show how a hydrogen 1s atomic orbital and a...Ch. 4 - Use Figs. 4-54 and 4-55 to answer the following...Ch. 4 - The diatomic molecule OH exists in the gas phase....Ch. 4 - Prob. 79ECh. 4 - Describe the bonding in NO+, NO, and NO, using...Ch. 4 - Describe the bonding in the O3 molecule and the...Ch. 4 - Prob. 82ECh. 4 - Prob. 83AECh. 4 - Vitamin B6 is an organic compound whose deficiency...Ch. 4 - Two structures can be drawn for cyanuric acid: a....Ch. 4 - Prob. 86AECh. 4 - What do each of the following sets of...Ch. 4 - Aspartame is an artificial sweetener marketed...Ch. 4 - Prob. 89AECh. 4 - The three most stable oxides of carbon are carbon...Ch. 4 - Prob. 91AECh. 4 - Which of the following molecules have net dipole...Ch. 4 - The strucrure of TeF5 is Draw a complete Lewis...Ch. 4 - Complete the following resonance structures for...Ch. 4 - Prob. 95AECh. 4 - Describe the bonding in the first excited state of...Ch. 4 - Using an MO energy-level diagram, would you expect...Ch. 4 - Show how a dxz. atomic orbital and a pz, atomic...Ch. 4 - What type of molecular orbital would result from...Ch. 4 - Consider three molecules: A, B, and C. Molecule A...Ch. 4 - Prob. 101CWPCh. 4 - Predict the molecular structure, bond angles, and...Ch. 4 - Draw the Lewis structures for SO2, PCl3, NNO, COS,...Ch. 4 - Draw the Lewis structures for TeCl4, ICl5, PCl5,...Ch. 4 - A variety of chlorine oxide fluorides and related...Ch. 4 - Pelargondin is the molecule responsible for the...Ch. 4 - Complete a Lewis structure for the compound shown...Ch. 4 - Prob. 108CWPCh. 4 - Consider the molecular orbital electron...Ch. 4 - Place the species B2+ , B2, and B2 in order of...Ch. 4 - The compound NF3 is quite stable, but NCl3 is very...Ch. 4 - Predict the molecular structure for each of the...Ch. 4 - Prob. 113CPCh. 4 - Cholesterol (C27liu;O) has the following...Ch. 4 - Cyanamide (H2NCN), an important industrial...Ch. 4 - As compared with CO and O2, CS and S2 are very...Ch. 4 - Prob. 117CPCh. 4 - Use the MO model to explain the bonding in BeH2....Ch. 4 - Prob. 119CPCh. 4 - Arrange the following from lowest to highest...Ch. 4 - Prob. 121CPCh. 4 - Prob. 122CPCh. 4 - Carbon monoxide (CO) forms bonds to a variety of...Ch. 4 - The space-filling model for benzoic acid, a food...Ch. 4 - As the bead engineer of your starship in charge of...Ch. 4 - A flask containing gaseous N2 is irradiated with...Ch. 4 - Determine the molecular structure and...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Using wedge-and-dash bonds, modify the bonds on the chiral carbon in the molecule below so the molecule has R stereochemical configuration. NH H Br X टेarrow_forwardProvide photos of models of the following molecules. (Include a key for identification of the atoms) 1,2-dichloropropane 2,3,3-trimethylhexane 2-bromo-3-methybutanearrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFirefly luciferin exhibits three rings. Identify which of the rings are aromatic. Identify which lone pairs are involved in establishing aromaticity. The lone pairs are labeled A-D below.arrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forward
- Given a complex reaction with rate equation v = k1[A] + k2[A]2, what is the overall reaction order?arrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forwardCHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the steady-state approximation method. Explain what it consists of.arrow_forward
- CHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the limiting or determining step approximation method. Explain what it consists of.arrow_forwardCHEMICAL KINETICS. Indicate the approximation methods for solving the rate equation.arrow_forwardTRANSMITTANCE เบบ Please identify the one structure below that is consistent with the 'H NMR and IR spectra shown and draw its complete structure in the box below with the protons alphabetically labeled as shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by the arrows. D 4000 OH LOH H₂C CH3 OH H₂C OCH3 CH3 OH 3000 2000 1500 HAVENUMBERI-11 1000 LOCH3 Draw your structure below and label its equivalent protons according to the peak labeling that is used in the NMR spectrum in order to assign the peaks. Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet 8 3Hb s m 1Hd s 3Hf m 2Hcd 2Had 1He 鄙视 m 7 7 6 5 4 3 22 500 T 1 0arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY