1 Matter: Its Properties And Measurement 2 Atoms And The Atomic Theory 3 Chemical Compounds 4 Chemical Reactions 5 Introduction To Reactions In Aqueous Solutions 6 Gases 7 Thermochemistry 8 Electrons In Atoms 9 The Periodic Table And Some Atomic Properties 10 Chemical Bonding I: Basic Concepts 11 Chemical Bonding Ii: Valence Bond And Molecular Orbital Theories 12 Intermolecular Forces: Liquids And Solids 13 Spontaneous Change: Entropy And Gibbs Energy 14 Solutions And Their Physical Properties 15 Principles Of Chemical Equilibrium 16 Acids And Bases 17 Additional Aspects Of Acid–base Equilibria 18 Solubility And Complex-ion Equilibria 19 Electrochemistry 20 Chemical Kinetics 21 Chemistry Of The Main-group Elements I: Groups 1, 2, 13, And 14 22 Chemistry Of The Main-group Elements Ii: Groups 18, 17, 16, 15, And Hydrogen 23 The Transition Elements 24 Complex Ions And Coordination Compounds 25 Nuclear Chemistry 26 Structures Of Organic Compounds 27 Reactions Of Organic Compounds expand_more
Chapter Questions expand_more
Problem 1E: Balance the following equations by inspection. a. SO2SO2+O2 b. CI2O7+H2OHCIO4 c. NO2+H2OHNO2+NO d.... Problem 2E: Balance the following equations by inspection. a. P2H4PH2+P4 b. P4+Cl2PCl2 c. FeCl3+H2SFe2S3+HCl d.... Problem 3E: Balance the following equations by inspection. a. PbO+NH2Pb+N2+H2O b. FeSO4Fe2O2+SO2+O2 c.... Problem 4E: Balance the following equations by inspection. a. SO2CI2+HIH2S+H2O+HCI+I2 b.... Problem 5E: Write balanced equations based on the information given. a. solid magnesium + oxygen gas solid... Problem 6E: Write balanced equations based on the information given. a. solid magnesium + nitrogen gas solid... Problem 7E: Write balanced equations to represent the complete combustion of each of following in excess oxygen:... Problem 8E: Write balanced equations to represent the complete combustion of each of the following in excess... Problem 9E: Write balanced equations to represent a. the decomposition, by heating, of solid ammonium nitrate to... Problem 10E: Write balanced equations to represent: a. the reaction of dioxide gas oxygen gas to produce sulfur... Problem 11E: Write a balanced chemical equation for the reaction depicted below. Problem 12E: Write a balanced chemical equation for the reaction depicted below. Problem 13E Problem 14E: A 3.104 g sample of an oxide of manganese contains 1.142 grams of oxygen. Write a balanced chemical... Problem 15E: Iron metal reacts with chlorine gas. How many grams of FeCI2 are obtained when 515 g Cl2 reacts with... Problem 16E: If 75.8gPCI2 is produced by the reaction 6C12(g)+P4(s)4PCls(I) how many grams each of Cl2 and P4 are... Problem 17E: A laboratory method of preparing O2g involves the decomposition of KCIO2s).2KCIO3(s)2KCI(s)3O2(g) a.... Problem 18E: A commercial method of manufacturing hydrogen involves the reaction of iron and steam.... Problem 19E: How many grams of Ag2CO2 are decomposed to yield 75.1 g Ag this reaction?... Problem 20E: How many kilograms of HNO2 are consumed to produce 125 kg Ca(H2 PO4)2+Ca( NO3)2 in this reaction?... Problem 21E: The reaction of calcium hydride with water can be used to prepare small quantities of gas, as is... Problem 22E: The reaction of potassium superoxide, KO2, is used in life-support systems to replace CO2(g) in... Problem 23E Problem 24E: Sold silver oxide, Ag2O (s), decomposes at temperatures in excess of 300 C, yielding metallic silver... Problem 25E: Decarborane, B10H14, was used as a fuel for rockets in the 1950s. It reacts violently with oxygen,... Problem 26E: The rocket boosters of the space shuttle Discovery, launched on July 26, 2005. Useda fuel mixture... Problem 27E Problem 28E: An excess of aluminum foil is allowed to react with 225 mL of an aqueous solution of... Problem 29E Problem 30E Problem 31E: What are the molarities of the following solutes when dissolved in water? a. 2.92 mol CH2OH in 7.16... Problem 32E Problem 33E: What are the molarities of the following solutes? a. sucrose (C12H22O11) if 150.0 g is dissolved per... Problem 34E: What ere the molarities of the following solutes? a. asp-artic (H2C4H2NO4) if 0.405 g is dissolved... Problem 35E: How much a. glucose, C5H12O5, in grams, must be dissolved in water to produce 75.0 mL of 0.350 M... Problem 36E Problem 37E Problem 38E: In many communities, water is fluoridated to prevent tooth decay. In the United States. for example,... Problem 39E Problem 40E Problem 41E Problem 42E Problem 43E: A 10.00 mL sample of 2.05MKNO2 is diluted to a volume of 250.0 mL. What is the concentration of the... Problem 44E: What volume of 2.00MAgNO2 must be diluted with water to prepare 500.0 mL of 0.350MAgNO2 ? Problem 45E: Water is evaporated from 125 mL of 0.198MK2SO4 solution until the volume becomes 105mL. What is the... Problem 46E: A 25.0 mL sample of HCl(aq) is diluted to a volume of 500.0 mL. If the concentration of the diluted... Problem 47E Problem 48E Problem 49E Problem 50E: Excess NaHCO2 is added to 525 mL of 0.220MCu( NO2)2. These Substances react as follows: Cu(... Problem 51E: How many milliliters of 0.650MK2CrO4 are needed to precipitate all the silver in 415 mL of... Problem 52E: Consider the reaction below. Ca(OH)2(s)+2HC1(aq)CaCl2(aq)+2H2O(I) a. How many grams of Ca(OH)2 are... Problem 53E: Exactly 1.00 mL of an aqueous solution of HNO2 is diluted to 100.0 mL. It takes 29.78 mL of 0.0142 M... Problem 54E: A 5.00 mL sample of an aqueous solution of H2PO4 requires 49.1 mL of 0.217 M NaOH to convert all of... Problem 55E Problem 56E Problem 57E: How many grams of Ag2CrO4 will precipitate if excess K2CrO4(aq) is added to the 415 mL of... Problem 58E: What volume of MKMnO4 is necessary to convert 12.5 g KI to I2 in the reaction below? Assume that... Problem 59E Problem 60E: A method of lowering the concentration of HCI(aq) is to allow the solution to react with a small... Problem 61E Problem 62E: A 25.00 mL sample of HCI(aq) was to a 0.1000 g sample of CaCO2. All the CaCO2 reacted, leaving some... Problem 63E: How many moles of NO(g) can be produced in the reaction of 3.00 mol NH2(g) and 4.00 mol O2g ?... Problem 64E: The reaction of calcium hydride and water produces calcium hydroxide and hydrogen as products. How... Problem 65E: A 0.696 mol sample of Cu is added to 136 mL of 6.0MHNO2 . Assuming the following reaction is the... Problem 66E: How many grams of H2O are produced by the reaction of 1.84 g Al with 75.0 mL of 2.95 M HCI? (Hint:... Problem 67E Problem 68E: Lithopone is a brilliant white pigment used in water-based interior paints. It is a mixture of BaSO4... Problem 69E: Ammonia can be generated by heating together he solids NH4CI and Ca(OH)2 . CaCl2 and H2O are also... Problem 70E: Chlorine can be generated by heating together calcium hypochlorite and hydrochloric acid. Calcium... Problem 71E: Chromium(II) sulfate. CrSO4, is a reagent that has been used in certain applications to help reduce... Problem 72E: Titanium tetrachloride, TiCl4 , is prepared by the reaction below.... Problem 73E: In the reaction of 277 g CCI4 an excess of HF, 187gCCI2F2 is obtained. What are (a) theoretical, (b)... Problem 74E: In the reaction shown, 100.0gC5H10OH yielded 64.0 g C5CH10. (a) What is the theoretical yield of the... Problem 75E Problem 76E: Nitrogen gas, N2 can be prepared by passing gaseous ammonia over solid copper(II) oxide, CuO, at... Problem 77E: The reactionof 15.0 g C4H2OH, 22.4 g NaBr, and 32.7 g H2SO4 yields 17.1 g C4HBr in the reaction... Problem 78E Problem 79E: How many grams of commercial acetic acid (97% CH2COOH by mass) must be allowed to react with an... Problem 80E: Suppose that reactions (a) and (b) each have a 92% yield. Starting 112 g CH4 reaction (a) and an... Problem 81E: An essentially 100% yield is necessary for a chemical reaction used to analyze a compound, but it is... Problem 82E Problem 83E: How many grams of HCI are consumed the reaction of 425 g of e mixture containing 35.2% MgCO2 and... Problem 84E: How many grams of CO2 are produced in the complete combustion of 406 g of a bottled gas that... Problem 85E: Dichlorodifluoromethane, once widely used a refrigerant, can be prepared by the reactions shown. How... Problem 86E Problem 87E Problem 88E: Sodium bromide, used to produce silver bromide for use in photography, can be prepared as shown. How... Problem 89E Problem 90E: The following set of reactions is to be used as the basis of a method for producing nitric acid,... Problem 91E Problem 92E: A mixture of Fe2O2 and FeO was analyzed and found to be 72.0% Fe by mass. What is the percentage by... Problem 93IAE Problem 94IAE Problem 95IAE Problem 96IAE Problem 97IAE: Hydrogen gas, H2O, is passed over Fe2O2(s) at 400 (C. Water vapor is formed together with a black... Problem 98IAE: A sulfide of iron, 36.5% S by mass, is heated in O2g, and the products are sulfur dioxide and an... Problem 99IAE Problem 100IAE Problem 101IAE: What volume of 0.149 M HCI must be added to 1.00 × 102mL of 0.285 M HCI so that the resulting... Problem 102IAE Problem 103IAE Problem 104IAE Problem 105IAE Problem 106IAE Problem 107IAE Problem 108IAE Problem 109IAE Problem 110IAE Problem 111IAE Problem 112IAE: A 0.155 g sample of an Al-Mg alloy reacts with an excess of HC(aq) to 0.0163 gH2. What is the... Problem 113IAE Problem 114IAE: The following chemical equation represents the decomposition of hydrogen peroxide, H2O2 .... Problem 115IAE Problem 116IAE Problem 117IAE Problem 118IAE Problem 119IAE: Write a chemical equation to represent the complete combustion of malonic acid, a compound with... Problem 120IAE Problem 121IAE Problem 122IAE: When sulfur (S5) and chlorine are mixed in a reaction vessel, disulfur dichloride is the sole... Problem 123IAE Problem 124IAE Problem 125IAE Problem 126IAE Problem 127IAE Problem 128IAE: Melamine, C2N2( NH2)2, is used in adhesives and resins. It is manufactured in a two-step process... Problem 129IAE Problem 130IAE: A fundamental principle green chemistry is atom economy (AE). AE is a measure of how many atoms from... Problem 131IAE: The industrial productionof hydrazine (N2H2) by the Ranching process is the topic of the Focus On... Problem 132IAE Problem 133FP Problem 134FP Problem 135SAE Problem 136SAE Problem 137SAE Problem 138SAE Problem 139SAE Problem 140SAE Problem 141SAE: In the decomposition of silver carbonate to form metallic silver, carbon dioxide gas, and oxygen... Problem 142SAE Problem 143SAE: What is the volume (in ML) of 0.160MKNO2 that must be added to 200.0 mL of 0.240 MK2SO4 to produce a... Problem 144SAE: To prepare a solution that is 0.50 M KCI starting with 100.0 mL of 0.40 M KCI, you should (a) add... Problem 145SAE: An aqueous solution that is 5.30% LiBr by mass density of 1.040 g/mL. What is the molarity of this... Problem 146SAE Problem 147SAE: Consider the reaction 2Fe2O2+3C4Fe+3CO2 . What is the maximum mass of Fe that can be obtained from a... Problem 148SAE Problem 149SAE: The incomplete combustion of gasoline produces CO(g) as well as CO2(g) . Write an equation for (a)... Problem 150SAE Problem 151SAE Problem 152SAE Problem 153SAE: For each of the following compounds,write a balanced chemical equation for forming the compound from... Problem 154SAE: Appendix E descries a useful study aid known as concept mapping. Using the method presented in... format_list_bulleted