General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Question
Chapter 4, Problem 105IAE
Interpretation Introduction
Interpretation:
The area of the cylindrical hole produced in the aluminum foil due to reaction with 0.05 mL of 12.0 M HCl should be determined.
Concept introduction:
HCl reacts with aluminum in the foil and creates a cylindrical hole in the foil. The area of the cylindrical hole can be calculated by using the formulas of volume
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Calculating the pH at equivalence of a titration
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Using the conditions of spontaneity to deduce the signs of AH and AS
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
A
This reaction is always spontaneous, but
proceeds slower at temperatures above
120. °C.
ΔΗ is
(pick one)
AS is
(pick one)
ΔΗ is
(pick one)
B
This reaction is spontaneous except above
117. °C.
AS is
(pick one)
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AS is
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Chapter 4 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 4 - Balance the following equations by inspection. a....Ch. 4 - Balance the following equations by inspection. a....Ch. 4 - Balance the following equations by inspection. a....Ch. 4 - Balance the following equations by inspection. a....Ch. 4 - Write balanced equations based on the information...Ch. 4 - Write balanced equations based on the information...Ch. 4 - Write balanced equations to represent the complete...Ch. 4 - Write balanced equations to represent the complete...Ch. 4 - Write balanced equations to represent a. the...Ch. 4 - Write balanced equations to represent: a. the...
Ch. 4 - Write a balanced chemical equation for the...Ch. 4 - Write a balanced chemical equation for the...Ch. 4 - Prob. 13ECh. 4 - A 3.104 g sample of an oxide of manganese contains...Ch. 4 - Iron metal reacts with chlorine gas. How many...Ch. 4 - If 75.8gPCI2 is produced by the reaction...Ch. 4 - A laboratory method of preparing O2g involves the...Ch. 4 - A commercial method of manufacturing hydrogen...Ch. 4 - How many grams of Ag2CO2 are decomposed to yield...Ch. 4 - How many kilograms of HNO2 are consumed to produce...Ch. 4 - The reaction of calcium hydride with water can be...Ch. 4 - The reaction of potassium superoxide, KO2, is used...Ch. 4 - Prob. 23ECh. 4 - Sold silver oxide, Ag2O (s), decomposes at...Ch. 4 - Decarborane, B10H14, was used as a fuel for...Ch. 4 - The rocket boosters of the space shuttle...Ch. 4 - Prob. 27ECh. 4 - An excess of aluminum foil is allowed to react...Ch. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - What are the molarities of the following solutes...Ch. 4 - Prob. 32ECh. 4 - What are the molarities of the following solutes?...Ch. 4 - What ere the molarities of the following solutes?...Ch. 4 - How much a. glucose, C5H12O5, in grams, must be...Ch. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - In many communities, water is fluoridated to...Ch. 4 - Prob. 39ECh. 4 - Prob. 40ECh. 4 - Prob. 41ECh. 4 - Prob. 42ECh. 4 - A 10.00 mL sample of 2.05MKNO2 is diluted to a...Ch. 4 - What volume of 2.00MAgNO2 must be diluted with...Ch. 4 - Water is evaporated from 125 mL of 0.198MK2SO4...Ch. 4 - A 25.0 mL sample of HCl(aq) is diluted to a volume...Ch. 4 - Prob. 47ECh. 4 - Prob. 48ECh. 4 - Prob. 49ECh. 4 - Excess NaHCO2 is added to 525 mL of 0.220MCu(...Ch. 4 - How many milliliters of 0.650MK2CrO4 are needed to...Ch. 4 - Consider the reaction below....Ch. 4 - Exactly 1.00 mL of an aqueous solution of HNO2 is...Ch. 4 - A 5.00 mL sample of an aqueous solution of H2PO4...Ch. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - How many grams of Ag2CrO4 will precipitate if...Ch. 4 - What volume of MKMnO4 is necessary to convert 12.5...Ch. 4 - Prob. 59ECh. 4 - A method of lowering the concentration of HCI(aq)...Ch. 4 - Prob. 61ECh. 4 - A 25.00 mL sample of HCI(aq) was to a 0.1000 g...Ch. 4 - How many moles of NO(g) can be produced in the...Ch. 4 - The reaction of calcium hydride and water produces...Ch. 4 - A 0.696 mol sample of Cu is added to 136 mL of...Ch. 4 - How many grams of H2O are produced by the reaction...Ch. 4 - Prob. 67ECh. 4 - Lithopone is a brilliant white pigment used in...Ch. 4 - Ammonia can be generated by heating together he...Ch. 4 - Chlorine can be generated by heating together...Ch. 4 - Chromium(II) sulfate. CrSO4, is a reagent that has...Ch. 4 - Titanium tetrachloride, TiCl4 , is prepared by the...Ch. 4 - In the reaction of 277 g CCI4 an excess of HF,...Ch. 4 - In the reaction shown, 100.0gC5H10OH yielded 64.0...Ch. 4 - Prob. 75ECh. 4 - Nitrogen gas, N2 can be prepared by passing...Ch. 4 - The reactionof 15.0 g C4H2OH, 22.4 g NaBr, and...Ch. 4 - Prob. 78ECh. 4 - How many grams of commercial acetic acid (97%...Ch. 4 - Suppose that reactions (a) and (b) each have a 92%...Ch. 4 - An essentially 100% yield is necessary for a...Ch. 4 - Prob. 82ECh. 4 - How many grams of HCI are consumed the reaction of...Ch. 4 - How many grams of CO2 are produced in the complete...Ch. 4 - Dichlorodifluoromethane, once widely used a...Ch. 4 - Prob. 86ECh. 4 - Prob. 87ECh. 4 - Sodium bromide, used to produce silver bromide for...Ch. 4 - Prob. 89ECh. 4 - The following set of reactions is to be used as...Ch. 4 - Prob. 91ECh. 4 - A mixture of Fe2O2 and FeO was analyzed and found...Ch. 4 - Prob. 93IAECh. 4 - Prob. 94IAECh. 4 - Prob. 95IAECh. 4 - Prob. 96IAECh. 4 - Hydrogen gas, H2O, is passed over Fe2O2(s) at 400...Ch. 4 - A sulfide of iron, 36.5% S by mass, is heated in...Ch. 4 - Prob. 99IAECh. 4 - Prob. 100IAECh. 4 - What volume of 0.149 M HCI must be added to 1.00 ×...Ch. 4 - Prob. 102IAECh. 4 - Prob. 103IAECh. 4 - Prob. 104IAECh. 4 - Prob. 105IAECh. 4 - Prob. 106IAECh. 4 - Prob. 107IAECh. 4 - Prob. 108IAECh. 4 - Prob. 109IAECh. 4 - Prob. 110IAECh. 4 - Prob. 111IAECh. 4 - A 0.155 g sample of an Al-Mg alloy reacts with an...Ch. 4 - Prob. 113IAECh. 4 - The following chemical equation represents the...Ch. 4 - Prob. 115IAECh. 4 - Prob. 116IAECh. 4 - Prob. 117IAECh. 4 - Prob. 118IAECh. 4 - Write a chemical equation to represent the...Ch. 4 - Prob. 120IAECh. 4 - Prob. 121IAECh. 4 - When sulfur (S5) and chlorine are mixed in a...Ch. 4 - Prob. 123IAECh. 4 - Prob. 124IAECh. 4 - Prob. 125IAECh. 4 - Prob. 126IAECh. 4 - Prob. 127IAECh. 4 - Melamine, C2N2( NH2)2, is used in adhesives and...Ch. 4 - Prob. 129IAECh. 4 - A fundamental principle green chemistry is atom...Ch. 4 - The industrial productionof hydrazine (N2H2) by...Ch. 4 - Prob. 132IAECh. 4 - Prob. 133FPCh. 4 - Prob. 134FPCh. 4 - Prob. 135SAECh. 4 - Prob. 136SAECh. 4 - Prob. 137SAECh. 4 - Prob. 138SAECh. 4 - Prob. 139SAECh. 4 - Prob. 140SAECh. 4 - In the decomposition of silver carbonate to form...Ch. 4 - Prob. 142SAECh. 4 - What is the volume (in ML) of 0.160MKNO2 that must...Ch. 4 - To prepare a solution that is 0.50 M KCI starting...Ch. 4 - An aqueous solution that is 5.30% LiBr by mass...Ch. 4 - Prob. 146SAECh. 4 - Consider the reaction 2Fe2O2+3C4Fe+3CO2 . What is...Ch. 4 - Prob. 148SAECh. 4 - The incomplete combustion of gasoline produces...Ch. 4 - Prob. 150SAECh. 4 - Prob. 151SAECh. 4 - Prob. 152SAECh. 4 - For each of the following compounds,write a...Ch. 4 - Appendix E descries a useful study aid known as...
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