EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
Question
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Chapter 3.9, Problem 34P

(a)

Interpretation Introduction

Interpretation:

The water (H2O) molecule has higher boiling point when compare to other molecules of given in the statement why, this comparison must be explain in each statements.

Concept introduction:

Boiling points: The every chemical compounds is the particular temperature at which its liquid from becomes a gas or (vaporizes). For a compound to vaporize, the forces that hold the individual molecules close to each other in the liquid must be overcome.

Than the boiling point of a each compound depends on the strength of the attractive forces between the individual molecules. If the molecules are held together by strong force then a great deal of energy will be need to pull the molecules away from each other and the compound will have a high boiling point.

On the other hand, if the molecules are held together by weak forces only a small of energy be need to pull the molecules away from each other and the compound will have a low boiling point.

Dipole interaction: The boiling points of all organic molecules like (ether, alkyl halide, amines, alcohols) also increase molecular weight because in the London dispersion forces. The boling points of these compounds, however are also affected the polar (C-Z) bonds here (Z= N, O, F, Cl). Generally alcohols have higher boiling point when compare to other organic molecules, because addition of London dispersion forces and the dipole-dipole interaction of the polar C-O bond, alcohol can from hydrogen bonds.

(b)

Interpretation Introduction

Interpretation:

The water (H2O) molecule has higher boiling point when compare to other molecules of given in the statement why, this comparison must be explain in each statements.

Concept introduction:

Boiling points: The every chemical compounds is the particular temperature at which its liquid from becomes a gas or (vaporizes). For a compound to vaporize, the forces that hold the individual molecules close to each other in the liquid must be overcome.

Than the boiling point of a each compound depends on the strength of the attractive forces between the individual molecules. If the molecules are held together by strong force then a great deal of energy will be need to pull the molecules away from each other and the compound will have a high boiling point.

On the other hand, if the molecules are held together by weak forces only a small of energy be need to pull the molecules away from each other and the compound will have a low boiling point.

Dipole interaction: The boiling points of all organic molecules like (ether, alkyl halide, amines, alcohols) also increase molecular weight because in the London dispersion forces. The boling points of these compounds, however are also affected the polar (C-Z) bonds here (Z Z= N, O, F, Cl cause addition of London dispersion forces and the dipole-dipole interaction of the polar C-O bond, alcohol can from hydrogen bonds.

(c)

Interpretation Introduction

Interpretation:

The water (H2O) molecule has higher boiling point when compare to other molecules of given in the statement why, this comparison must be explain in each statements.

Concept introduction:

Boiling points: The every chemical compounds is the particular temperature at which its liquid from becomes a gas or (vaporizes). For a compound to vaporize, the forces that hold the individual molecules close to each other in the liquid must be overcome.

Than the boiling point of a each compound depends on the strength of the attractive forces between the individual molecules. If the molecules are held together by strong force then a great deal of energy will be need to pull the molecules away from each other and the compound will have a high boiling point.

On the other hand, if the molecules are held together by weak forces only a small of energy be need to pull the molecules away from each other and the compound will have a low boiling point.

Dipole interaction: The boiling points of all organic molecules like (ether, alkyl halide, amines, alcohols) also increase molecular weight because in the London dispersion forces. The boling points of these compounds, however are also affected the polar (C-Z) bonds here (Z= N, O, F, Cl). Generally alcohols have higher boiling point when compare to other organic molecules, because addition of London dispersion forces and the dipole-dipole interaction of the polar C-O bond, alcohol can from hydrogen bonds.

d)

Interpretation Introduction

Interpretation:

The H-F molecule has higher boiling point when compare to other molecules of given in the statement why, this comparison must be explain in each statements.

Concept introduction:

Boiling points: The every chemical compounds is the particular temperature at which its liquid from becomes a gas or (vaporizes). For a compound to vaporize, the forces that hold the individual molecules close to each other in the liquid must be overcome.

Than the boiling point of a each compound depends on the strength of the attractive forces between the individual molecules. If the molecules are held together by strong force then a great deal of energy will be need to pull the molecules away from each other and the compound will have a high boiling point.

On the other hand, if the molecules are held together by weak forces only a small of energy be need to pull the molecules away from each other and the compound will have a low boiling point.

Dipole interaction: The boiling points of all organic molecules like (ether, alkyl halide, amines, alcohols) also increase molecular weight because in the London dispersion forces. The boling points of these compounds, however are also affected the polar (C-Z) bonds here (Z= N, O, F, Cl). Generally alcohols have higher boiling point when compare to other organic molecules, because addition of London dispersion forces and the dipole-dipole interaction of the polar C-O bond, alcohol can from hydrogen bonds.

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Students have asked these similar questions
Explain why a. H2O (100 °C) has a higher boiling point than CH3OH (165 °C). b. H2O (100 °C) has a higher boiling point than NH3 (-33 °C). c. H2O (100 °C) has a higher boiling point than HF (120 °C). d. HF (120 °C) has a higher boiling point than NH3 (-33 °C).
Explain why a. H2O (100 °C) has a higher boiling point than CH3OH 165 °C2. b. H2O (100 °C) has a higher boiling point than NH3 (-33 °C). c. H2O (100 °C) has a higher boiling point than HF 120 °C2. d. HF 120 °C2 has a higher boiling point than NH3 (-33 °C).
Exercises: 1. Identify the functional group in each of the following molecules. Then give an acceptable name for each molecule. H₂ H3C C-CH3 H₂ H3C-CO-CH2CH3 H₂ H₂ H₂ H3CC-CO H₂ OH H3C-NC-CH2CH3 2. Which of the molecules in Exercise 1 will exhibit hydrogen bonding?

Chapter 3 Solutions

EBK ORGANIC CHEMISTRY

Ch. 3.3 - What is each compounds systematic name?Ch. 3.3 - Prob. 16PCh. 3.3 - Prob. 17PCh. 3.3 - Prob. 18PCh. 3.3 - Prob. 19PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 21PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Prob. 25PCh. 3.6 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Draw condensed and skeletal structures for each of...Ch. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 32PCh. 3.9 - Prob. 33PCh. 3.9 - Prob. 34PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.10 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - Prob. 38PCh. 3.10 - Prob. 39PCh. 3.11 - a. Draw all the staggered and eclipsed conformers...Ch. 3.11 - Prob. 41PCh. 3.11 - Using Newman projections, draw the most stable...Ch. 3.12 - The bond angles in a regular polygon with n sides...Ch. 3.12 - Prob. 44PCh. 3.13 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.14 - Using the data in Table 3.9, calculate the...Ch. 3.14 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.15 - Prob. 48PCh. 3.15 - Which has a higher percentage of the...Ch. 3.15 - a. Draw the more stable chair conformer of...Ch. 3.15 - For each of the following disubstituted...Ch. 3.15 - a. Draw Newman projections of the two conformers...Ch. 3.15 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 56PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 66PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 69PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 72PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - What is each compound s systematic name?Ch. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 88PCh. 3 - Using the data obtained in Problem 85, calculate...Ch. 3 - Draw the conformers for the following...
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