EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Textbook Question
Chapter 3.14, Problem 46P
Using the data in Table 3.9, calculate the percentage of molecules of cyclohexanol that have the OH group in an equatorial position at 25°C.
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. A compound has one cyclohexane ring and one
cyclohexene ring connected to a 4 carbon chain. One of
the rings has an OH substituent; one of the rings is a
cyclohexanone and the four carbon chain contains a
triple bond. The number of hydrogens in this molecule is
In problem 1.30 letter f my structure is different than the one in the book . I don’t know why
Identify the different functional groups in the following molecules using names from the table below.
(If there are fewer than 3 different functional groups, leave an appropriate number of answer boxes empty.)
a)
b)
HO
Name
Alkene
Arene
Alkyne -c=c-
Halide
Alcohol
Ether
Amine
Structures of Some Common Functional Groups
Structure
Nitrile
X
(X=F, Cl, Br, I)
OH
-C=N;
Nitro
Thiol
Aldehyde
Ketone
Name
Carboxylic Acid
Ester
Amide
Carboxylic Acid Chloride
Structure
SH
X
Yo
0=ú
010
0=U
Chapter 3 Solutions
EBK ORGANIC CHEMISTRY
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structure of a compound with molecular...Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Prob. 6PCh. 3.1 - Draw the structure for each of the following: a....Ch. 3.1 - Name the following compounds: a. CH3OCH2CH3 b....Ch. 3.2 - Prob. 9PCh. 3.2 - Draw the structure for each of the following: a....Ch. 3.2 - Give each substituent on the nine-carbon chain a...Ch. 3.2 - Prob. 14P
Ch. 3.3 - What is each compounds systematic name?Ch. 3.3 - Prob. 16PCh. 3.3 - Prob. 17PCh. 3.3 - Prob. 18PCh. 3.3 - Prob. 19PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 21PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Prob. 25PCh. 3.6 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Draw condensed and skeletal structures for each of...Ch. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 32PCh. 3.9 - Prob. 33PCh. 3.9 - Prob. 34PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.10 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - Prob. 38PCh. 3.10 - Prob. 39PCh. 3.11 - a. Draw all the staggered and eclipsed conformers...Ch. 3.11 - Prob. 41PCh. 3.11 - Using Newman projections, draw the most stable...Ch. 3.12 - The bond angles in a regular polygon with n sides...Ch. 3.12 - Prob. 44PCh. 3.13 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.14 - Using the data in Table 3.9, calculate the...Ch. 3.14 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.15 - Prob. 48PCh. 3.15 - Which has a higher percentage of the...Ch. 3.15 - a. Draw the more stable chair conformer of...Ch. 3.15 - For each of the following disubstituted...Ch. 3.15 - a. Draw Newman projections of the two conformers...Ch. 3.15 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 56PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 66PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 69PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 72PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - What is each compound s systematic name?Ch. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 88PCh. 3 - Using the data obtained in Problem 85, calculate...Ch. 3 - Draw the conformers for the following...
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- 1. The six compounds below may be the unknowns in the exercise. Draw their structures in the boxes below. (You may have to look up the structure of glucose). Hexane Ethanol Benzaldehyde Cyclohexanone Acetone (Propanone) Glucosearrow_forwardWhat are these 2?arrow_forwardBromine is a larger atom than chlorine, but the equilibrium constants in Table 3.9 indicate that a chloro substituent has a greater preference for the equatorial position than does a bromo substituent. Suggest an explanation for this fact.arrow_forward
- Draw the structural formulas of compounds A, C, D, E and F in the boxes provided above.arrow_forwardArrange these compounds in order of increasing boiling point (values in C are 42, 24, 78, and 118). (a) CH3CH2OH (b) CH3OCH3 (c) CH3CH2CH3 (d) CH3COOHarrow_forwardI Review You may want to reference (Pages 399 - 404) Section 12.1 while completing this problem. Enter the IUPAC name for each of the following. Part A OH Spell out the full name of the compound. Submit Request Answer • Part B CH3 ÇH3 CH3-CH-CH2-CH–CH2-OH Spell out the full name of the compound. Submit Request Answer • Part C OH CH2-CH3 Spell out the full name of the compound. Submit Request Answerarrow_forward
- Write the systematic name of each organic molecule: structure OH H-C-CH-CH-CH₂-OH I CH3 CH3 I CH,—CH–CH2−CH O || H—C–CH–CH3 I CH3 name 0 0 Xarrow_forwardWhich intermolecular force(s) do the following pairs of molecules experience? (Consider asking yourself which molecule in each pair is dominant?) Between acetone and ethanol? Between pentane and hexane? Between pentol and water?arrow_forwardName the following compounds using the IUPAC systemarrow_forward
- Draw the expanded structural formula for 1,3-dichlorocyclopentane.An expanded structural formula shows all the atoms of the molecule and all the bonds between the atoms in the molecule.arrow_forwardMatch the following organic compounds with their correct pair.arrow_forwardA short summary would be nice to help me understand. Thank you.arrow_forward
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