Organic Chemistry As a Second Language: Second Semester Topics
4th Edition
ISBN: 9781119110651
Author: David R. Klein
Publisher: WILEY
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Textbook Question
Chapter 3.4, Problem 3.30P
Predict the multiplicity of each signal in the expected proton NMR spectrum of each of the following compounds:
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 3 Solutions
Organic Chemistry As a Second Language: Second Semester Topics
Ch. 3.1 - Prob. 3.2PCh. 3.1 - Prob. 3.3PCh. 3.1 - Prob. 3.4PCh. 3.1 - Prob. 3.5PCh. 3.1 - Prob. 3.6PCh. 3.1 - Prob. 3.7PCh. 3.1 - Prob. 3.8PCh. 3.1 - Prob. 3.9PCh. 3.1 - Prob. 3.10PCh. 3.1 - If you look at your answers to the previous...
Ch. 3.2 - Predict the chemical shifts for the signals in the...Ch. 3.2 - Predict the chemical shifts for the signals in the...Ch. 3.2 - Predict the chemical shifts for the signals in the...Ch. 3.2 - Predict the chemical shifts for the signals in the...Ch. 3.2 - Predict the chemical shifts for the signals in the...Ch. 3.2 - Predict the chemical shifts for the signals in the...Ch. 3.2 - Prob. 3.19PCh. 3.3 - Prob. 3.21PCh. 3.3 - Prob. 3.22PCh. 3.3 - Prob. 3.23PCh. 3.4 - Predict the multiplicity of each signal in the...Ch. 3.4 - Predict the multiplicity of each signal in the...Ch. 3.4 - Predict the multiplicity of each signal in the...Ch. 3.4 - Predict the multiplicity of each signal in the...Ch. 3.4 - Predict the multiplicity of each signal in the...Ch. 3.4 - Predict the multiplicity of each signal in the...Ch. 3.5 - Below are NMR spectra of several compounds....Ch. 3.5 - Below are NMR spectra of several compounds....Ch. 3.5 - Below are NMR spectra of several compounds....Ch. 3.8 - Calculate the degree of unsaturation for each of...Ch. 3.8 - Calculate the degree of unsaturation for each of...Ch. 3.8 - Calculate the degree of unsaturation for each of...Ch. 3.8 - Calculate the degree of unsaturation for each of...Ch. 3.8 - Calculate the degree of unsaturation for each of...Ch. 3.8 - Calculate the degree of unsaturation for each of...Ch. 3.9 - Prob. 3.43PCh. 3.9 - Propose a structure for a compound with molecular...Ch. 3.9 - Propose a structure for a compound with molecular...Ch. 3.9 - Propose a structure for a compound with molecular...Ch. 3.9 - Propose a structure for a compound with molecular...Ch. 3.9 - Prob. 3.48PCh. 3.10 - For each compound below, predict the number of...Ch. 3.10 - For each compound below, predict the number of...Ch. 3.10 - For each compound below, predict the number of...Ch. 3.10 - For each compound below, predict the number of...Ch. 3.10 - For each compound below, predict the number of...Ch. 3.10 - For each compound below, predict the number of...
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