Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 3.11, Problem 34P
Draw 1,2,3,4,5,6-hexachlorocyclohexane with
- a. all the chloro groups in axial positions.
- b. all the chloro groups in equatorial positions.
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H3C.
CH3
What is the systematic IUPAC name of this compound?
H;C
Select one:
a. 1-(3-isopropylcyclohexene-6-yl)ethane
b. 3-ethyl-6-(propan-2-yl)cyclohex-1-ene
O c. 6-ethyl-3-isopropylcyclohex-1-ene
d. 2-(3-ethylcyclohexene-6-yl)propane
e. 3-ethyl-6-isopropylcyclohex-1-ene
Consider 1,2-dimethylcyclohexane.
a.Draw structures for the cis and trans isomers using a hexagon for the sixmembered ring.
b. Draw the two possible chair conformations for the cis isomer. Which conformation, if either, is more stable?
c. Draw the two possible chair conformations for the trans isomer. Which conformation, if either, is more stable?
d.Which isomer, cis or trans, is more stable and why?
What is the IUPAC name for the following compound?
A. (2E, 4Z)-2,4-hexadiene
B. (2E, 4Z)-1,4-dimethyl-1,3-butadiene
(2Z, 4Z)-1,4-dimethyl-1,3-butadiene
(2Z, 4Z)-2,4-hexadiene
ABCD
C.
D.
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Chapter 3 Solutions
Essential Organic Chemistry, Global Edition
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Draw the structure for each of the following...Ch. 3.1 - Name the following compounds:Ch. 3.1 - Prob. 7PCh. 3.2 - What is each compounds systematic name?Ch. 3.2 - Prob. 11PCh. 3.3 - Prob. 12PCh. 3.3 - Convert the following condensed structures into...Ch. 3.3 - The molecular formula for ethyl alcohol (CH3CH2OH)...
Ch. 3.3 - Draw a condensed and a skeletal structure for the...Ch. 3.3 - What is each compounds systematic name?Ch. 3.4 - Prob. 17PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.5 - Are the following compounds primary, secondary, or...Ch. 3.5 - Name the following amines and tell whether they...Ch. 3.5 - Draw the structures and provide systematic names...Ch. 3.6 - Predict the approximate size of the following bond...Ch. 3.7 - What is the smallest straight-chain alkane that is...Ch. 3.7 - Prob. 24PCh. 3.7 - Prob. 25PCh. 3.7 - Prob. 26PCh. 3.7 - List the compounds in each set from highest...Ch. 3.8 - Rank the following compounds in each set from most...Ch. 3.8 - In which solvent would cyclohexane have the lowest...Ch. 3.8 - Prob. 30PCh. 3.9 - Prob. 31PCh. 3.9 - a. Draw the three staggered conformations and the...Ch. 3.9 - a. Draw the most stable conformation of pentane...Ch. 3.11 - Draw 1,2,3,4,5,6-hexachlorocyclohexane with a. all...Ch. 3.12 - At any one time, would you expect there to be more...Ch. 3.13 - Prob. 36PCh. 3 - a. How many hydrogens does an alkane with 17...Ch. 3 - Prob. 2PCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Name the following amines and tell whether they...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - What is each compounds name? a. CH3CH2CH2OCH2CH3Ch. 3 - Draw the structural formula for an alkane that has...Ch. 3 - Which has a. the higher boiling point:...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 51PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - Prob. 53PCh. 3 - For rotation about the C-3 8 C-4 bond of...Ch. 3 - Prob. 55PCh. 3 - What is each compounds systematic name?Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Draw the nine constitutional isomers with...Ch. 3 - Prob. 59PCh. 3 - Prob. 60PCh. 3 - Prob. 61PCh. 3 - Using Newman projections, draw the most stable...Ch. 3 - For each of the following disubstituted...Ch. 3 - Prob. 64PCh. 3 - Prob. 65PCh. 3 - What is each compounds systematic name?Ch. 3 - Prob. 67PCh. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Prob. 69PCh. 3 - Prob. 70PCh. 3 - a. Draw a potential energy diagram for rotation...
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- 1. Answer the following: a) What is the IUPAC name of the acyclic unbranched alkane that contains six carbons? b) How are structural isomers best defined? i. compounds with the same molecular formula whose atoms are bonded together in different arrangements ii. compounds with the same molecular formula whose atoms are bonded together in the same arrangement, but drawn differently iii. compounds with similar structural formulas, but different numbers of hydrogens iv. none of the above c) Which of the following statements is false concerning line structures of alkanes? i. Each carbon atom has 4 bonds, although they may not all be shown explicitly ii. The lines represent bonds between the carbon atoms. iii. Hydrogen atoms are not shown because they are not present in the molecule iv. none of the abovearrow_forwardTRUE OR FALSE. Write T if True, F if False. 1. In numbering the longest chain, the first substituent should have the higher number. 2. Alphabetize the names of the substituents, ignoring all prefixes except iso, as in isopropyl and isobutyl. 3. A number is always designated to indicate the location of a single substituent in cyclohexane. 4. For rings with two different substituents, number the ring to assign the lower number to the substituents alphabetically. 5. In naming alkenes, the longest carbon chain is always used as the parent name. 6. Toluene is an IUPAC name. 7. A benzyl group differs from a phenyl group only by an extra CH2 group. 8. Naming of branched molecules depend on the type of C atom removed from the parent chain. 9. An unbranched alkane with a chain of 50 carbons is called pentacontane. 10. Heterocyclic amines still…arrow_forward1. Draw the structure for each compound. a.(3R)-3-methylhexane b. (3R,5S,6R)-5-ethyl-3,6-dimethylnonanearrow_forward
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