Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 30, Problem 65P
Interpretation Introduction
Interpretation: The challenge of using an isolated envelope protein from HIV as a vaccine needs to be determined.
Concept Introduction: Antigen can be defined as the substance which trigger the immune system and causes the production of an antibody. Here antibody is formed as a defence system for infection and diseases.
Vaccine is a mild form of bacteria or virus stain to induce anti-bodies in the human body.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 30 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 30.1 - Prob. 30.1QCCh. 30.2 - Prob. 30.2QCCh. 30.3 - Prob. 30.3QCCh. 30.4 - Prob. 30.4QCCh. 30.5 - Prob. 30.5QCCh. 30.6 - Prob. 30.6QCCh. 30.7 - Prob. 30.7QCCh. 30.8 - Prob. 30.8QCCh. 30 - Give two examples of external innate immunity in...Ch. 30 - Prob. 2P
Ch. 30 - Prob. 3PCh. 30 - Prob. 4PCh. 30 - Prob. 5PCh. 30 - Prob. 6PCh. 30 - Prob. 7PCh. 30 - 31-8 What are memory cells? What is their...Ch. 30 - Prob. 9PCh. 30 - Prob. 10PCh. 30 - Prob. 11PCh. 30 - Prob. 12PCh. 30 - Prob. 13PCh. 30 - Prob. 14PCh. 30 - Prob. 15PCh. 30 - Prob. 16PCh. 30 - When a foreign substance is injected in a rabbit,...Ch. 30 - Prob. 18PCh. 30 - (a) Which immunoglobulin has the highest...Ch. 30 - Prob. 20PCh. 30 - Prob. 21PCh. 30 - Prob. 22PCh. 30 - Prob. 23PCh. 30 - Prob. 24PCh. 30 - Prob. 25PCh. 30 - Prob. 26PCh. 30 - What accounts for antibody diversity?Ch. 30 - Prob. 28PCh. 30 - Prob. 29PCh. 30 - Prob. 30PCh. 30 - Prob. 31PCh. 30 - Prob. 32PCh. 30 - Prob. 33PCh. 30 - Prob. 34PCh. 30 - Prob. 35PCh. 30 - Prob. 36PCh. 30 - Prob. 37PCh. 30 - Prob. 38PCh. 30 - Prob. 39PCh. 30 - Prob. 40PCh. 30 - Prob. 41PCh. 30 - Prob. 42PCh. 30 - Prob. 43PCh. 30 - Prob. 44PCh. 30 - Prob. 45PCh. 30 - Prob. 46PCh. 30 - Prob. 47PCh. 30 - Prob. 48PCh. 30 - Prob. 49PCh. 30 - Prob. 50PCh. 30 - Prob. 51PCh. 30 - Prob. 52PCh. 30 - Prob. 53PCh. 30 - Prob. 54PCh. 30 - Prob. 55PCh. 30 - Prob. 56PCh. 30 - Prob. 57PCh. 30 - Prob. 58PCh. 30 - Prob. 59PCh. 30 - Prob. 60PCh. 30 - Prob. 61PCh. 30 - Prob. 62PCh. 30 - Prob. 63PCh. 30 - Prob. 64PCh. 30 - Prob. 65PCh. 30 - Prob. 66PCh. 30 - Prob. 67PCh. 30 - Prob. 68PCh. 30 - Prob. 69PCh. 30 - Prob. 70PCh. 30 - How are researchers attempting to use gene therapy...Ch. 30 - Prob. 72PCh. 30 - (Chemical Connections 30A ) Why are monoclonal...Ch. 30 - Prob. 74PCh. 30 - Prob. 75PCh. 30 - Prob. 76PCh. 30 - Prob. 77PCh. 30 - Prob. 78PCh. 30 - Prob. 79PCh. 30 - Prob. 80PCh. 30 - Prob. 81PCh. 30 - Prob. 82PCh. 30 - Prob. 83PCh. 30 - Prob. 84PCh. 30 - Prob. 85PCh. 30 - Prob. 86PCh. 30 - Prob. 87PCh. 30 - Prob. 88PCh. 30 - Prob. 89PCh. 30 - Prob. 90PCh. 30 - Prob. 91PCh. 30 - Prob. 92PCh. 30 - Prob. 93PCh. 30 - Prob. 94PCh. 30 - Prob. 95PCh. 30 - Prob. 96PCh. 30 - Prob. 97PCh. 30 - Prob. 98PCh. 30 - Prob. 99PCh. 30 - Prob. 100PCh. 30 - Prob. 101PCh. 30 - Prob. 102PCh. 30 - Prob. 103PCh. 30 - Prob. 104P
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