Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 30, Problem 94P
Interpretation Introduction
Interpretation: The role of histamine during its part of an inflammatory response should be explained.
Concept Introduction: A disorder in the immune system results in dysfunction of the immune system. The dysfunction of the immune system, an autoimmune disorder can affect the membrane inside the body and attack one's own body resulting in inflammation in joints.
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Consider the reaction below to answer the following questions:
Acetoacetic ester can be prepared by the Claisen self-condensation reaction of ethyl acetate.
1. NaOEt, EtOH
H&C
OCH CH3 2 H30
H3C
CH2
OCH2CH3
A. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and
draw all intermediate structures.
B. Ethyl acetate can be prepared from ethanol as the only organic starting material. Show all reagents
and structures for all intermediates in this preparation.
C. Give the structures of the ester precursors for the following Claisen condensation product and
formulate the reaction.
OEt
Use the phase diagram of Substance X below to find the temperature at which X turns to a gas, if the pressure above the solid is 3.7 atm.
pressure (atm)
32
16
solid
liquid
gas
0
0
200
temperature (K)
Note: your answer must be within 20 °C of the exact answer to be graded correct.
Шос
☑
ك
Starting from bromoethane, how could you prepare the following compounds:
a. Ethanol.
b. Acetaldehyde
f. Acetone.
e. 2-Propanol
i. Acetoacetic ester.
d. 2-Bromoacetic acid.
c. Acetic acid
g. Acetamide.
j. Ethylmalonate
k. Gama ketoacid.
h. Ethyl magnesium bromide.
Chapter 30 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 30.1 - Prob. 30.1QCCh. 30.2 - Prob. 30.2QCCh. 30.3 - Prob. 30.3QCCh. 30.4 - Prob. 30.4QCCh. 30.5 - Prob. 30.5QCCh. 30.6 - Prob. 30.6QCCh. 30.7 - Prob. 30.7QCCh. 30.8 - Prob. 30.8QCCh. 30 - Give two examples of external innate immunity in...Ch. 30 - Prob. 2P
Ch. 30 - Prob. 3PCh. 30 - Prob. 4PCh. 30 - Prob. 5PCh. 30 - Prob. 6PCh. 30 - Prob. 7PCh. 30 - 31-8 What are memory cells? What is their...Ch. 30 - Prob. 9PCh. 30 - Prob. 10PCh. 30 - Prob. 11PCh. 30 - Prob. 12PCh. 30 - Prob. 13PCh. 30 - Prob. 14PCh. 30 - Prob. 15PCh. 30 - Prob. 16PCh. 30 - When a foreign substance is injected in a rabbit,...Ch. 30 - Prob. 18PCh. 30 - (a) Which immunoglobulin has the highest...Ch. 30 - Prob. 20PCh. 30 - Prob. 21PCh. 30 - Prob. 22PCh. 30 - Prob. 23PCh. 30 - Prob. 24PCh. 30 - Prob. 25PCh. 30 - Prob. 26PCh. 30 - What accounts for antibody diversity?Ch. 30 - Prob. 28PCh. 30 - Prob. 29PCh. 30 - Prob. 30PCh. 30 - Prob. 31PCh. 30 - Prob. 32PCh. 30 - Prob. 33PCh. 30 - Prob. 34PCh. 30 - Prob. 35PCh. 30 - Prob. 36PCh. 30 - Prob. 37PCh. 30 - Prob. 38PCh. 30 - Prob. 39PCh. 30 - Prob. 40PCh. 30 - Prob. 41PCh. 30 - Prob. 42PCh. 30 - Prob. 43PCh. 30 - Prob. 44PCh. 30 - Prob. 45PCh. 30 - Prob. 46PCh. 30 - Prob. 47PCh. 30 - Prob. 48PCh. 30 - Prob. 49PCh. 30 - Prob. 50PCh. 30 - Prob. 51PCh. 30 - Prob. 52PCh. 30 - Prob. 53PCh. 30 - Prob. 54PCh. 30 - Prob. 55PCh. 30 - Prob. 56PCh. 30 - Prob. 57PCh. 30 - Prob. 58PCh. 30 - Prob. 59PCh. 30 - Prob. 60PCh. 30 - Prob. 61PCh. 30 - Prob. 62PCh. 30 - Prob. 63PCh. 30 - Prob. 64PCh. 30 - Prob. 65PCh. 30 - Prob. 66PCh. 30 - Prob. 67PCh. 30 - Prob. 68PCh. 30 - Prob. 69PCh. 30 - Prob. 70PCh. 30 - How are researchers attempting to use gene therapy...Ch. 30 - Prob. 72PCh. 30 - (Chemical Connections 30A ) Why are monoclonal...Ch. 30 - Prob. 74PCh. 30 - Prob. 75PCh. 30 - Prob. 76PCh. 30 - Prob. 77PCh. 30 - Prob. 78PCh. 30 - Prob. 79PCh. 30 - Prob. 80PCh. 30 - Prob. 81PCh. 30 - Prob. 82PCh. 30 - Prob. 83PCh. 30 - Prob. 84PCh. 30 - Prob. 85PCh. 30 - Prob. 86PCh. 30 - Prob. 87PCh. 30 - Prob. 88PCh. 30 - Prob. 89PCh. 30 - Prob. 90PCh. 30 - Prob. 91PCh. 30 - Prob. 92PCh. 30 - Prob. 93PCh. 30 - Prob. 94PCh. 30 - Prob. 95PCh. 30 - Prob. 96PCh. 30 - Prob. 97PCh. 30 - Prob. 98PCh. 30 - Prob. 99PCh. 30 - Prob. 100PCh. 30 - Prob. 101PCh. 30 - Prob. 102PCh. 30 - Prob. 103PCh. 30 - Prob. 104P
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- - The pressure above a pure sample of solid Substance X at 60. °C is raised. At what pressure will the sample melt? Use the phase diagram of X below to find your answer. pressure (atm) 02 0.4 solid Hliquid gas 0 0 200 400 600 temperature (K) Note: your answer must be within 0.025 atm of the exact answer to be graded correct. ☐ atmarrow_forward15. What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first) 0 O H3C COC CH3 H₂C C N(CH3)2 H3C C OCH3 A. a. I, 11, 111, b. I, III, IV, II C. II, IV, III, I ° (CH3)2CH C OCH3 IV d. II, I, III, IV B. R COCR 0 0 0 13= RC NH2 RC OR RC CI === IV a. I, III, II, IV b. II, III, I, IV C. III, II, I, IV d. IV, I, III, IIarrow_forwardDraw the formula of the product obtained by reacting D-Tallose with bromine water.arrow_forward
- Choose the best reagent(s) for carrying out the following conversions from the list below. Place the letter corresponding to the best choice in the blank to the left of the conversion. a. KMnO4, H3O+ b. Tollens' Reagent [oxidizing reagent] C. NaBH4, ethanol d. 1. BH3 2. H3O+ e. 1. CH3MgBr, ether 2. H3O+ f. CrO3, H2SO4, H₂O g. 1. Mg, ether 2. CO2 3. H3O+ h. 1. NaCN 2. H2SO4, H2, heat i. O3, then Zn and HOAC j. CH₂I A. B. C. CH CH=CHCH2COOH Br CEN CH COOH + HOOCCH COOH COOH 010 CH3arrow_forwardDraw the structures for each of the intermediates in the boxes provided for the synthesis below. OCH3 Fe HO HNO (CHOO pynding H₂504 LHNO2 NACH-I Fa H₂O HCL HNO 180arrow_forwardProvide structure(s) for the starting material(s), reagent(s) or the major organic product(s) of each of the following reactions or sequences of reactions. Show all relevant stereochemistry [three only] A. o 11 (CH3)CH — C— C ether (CH3)2CH-C-O-C-CH3 B. CH3 CHy CI Staf OH C. HC OCHS + H₂Oarrow_forward
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