Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 30, Problem 30.25P
Interpretation Introduction
Interpretation:
The difference in protein digestion by trypsin and by HCl, should be explained.
Concept Introduction:
- HCl is present in the stomach while trypsin is present in the small intestine.
- While HCl breaks down peptides at random position, trypsin catalyses hydrolysis of peptide bonds at specific position.
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 30 Solutions
Introduction to General, Organic and Biochemistry
Ch. 30 - Are nutrient requirements uniform for everyone?Ch. 30 - Is banana flavoring, isopentyl acetate, a...Ch. 30 - If sodium benzoate, a food preservative, is...Ch. 30 - Prob. 30.4PCh. 30 - Prob. 30.5PCh. 30 - Prob. 30.6PCh. 30 - Prob. 30.7PCh. 30 - Can a chemical that, in essence, goes through the...Ch. 30 - Prob. 30.9PCh. 30 - Prob. 30.10P
Ch. 30 - Prob. 30.11PCh. 30 - Prob. 30.12PCh. 30 - Prob. 30.13PCh. 30 - Humans cannot digest wood; termites do so with the...Ch. 30 - Prob. 30.15PCh. 30 - Prob. 30.16PCh. 30 - Prob. 30.17PCh. 30 - Which nutrient provides energy in its most...Ch. 30 - Prob. 30.19PCh. 30 - Prob. 30.20PCh. 30 - Prob. 30.21PCh. 30 - Prob. 30.22PCh. 30 - Is it possible to get a sufficient supply of...Ch. 30 - Prob. 30.24PCh. 30 - Prob. 30.25PCh. 30 - 30-26 Which one will be digested faster: (a) a raw...Ch. 30 - Prob. 30.27PCh. 30 - Prob. 30.28PCh. 30 - Prob. 30.29PCh. 30 - Prob. 30.30PCh. 30 - Prob. 30.31PCh. 30 - Prob. 30.32PCh. 30 - Prob. 30.33PCh. 30 - Prob. 30.34PCh. 30 - Prob. 30.35PCh. 30 - Prob. 30.36PCh. 30 - What are the nonspecific effects of vitamin E, C,...Ch. 30 - Prob. 30.38PCh. 30 - Prob. 30.39PCh. 30 - Prob. 30.40PCh. 30 - Prob. 30.41PCh. 30 - Why would many athletes believe that taking large...Ch. 30 - Prob. 30.43PCh. 30 - (Chemical Connections 30A) What is a...Ch. 30 - Prob. 30.45PCh. 30 - Prob. 30.46PCh. 30 - Prob. 30.47PCh. 30 - Prob. 30.48PCh. 30 - Prob. 30.49PCh. 30 - Prob. 30.50PCh. 30 - Prob. 30.51PCh. 30 - Prob. 30.52PCh. 30 - Prob. 30.53PCh. 30 - Prob. 30.54PCh. 30 - Prob. 30.55PCh. 30 - Prob. 30.56PCh. 30 - Prob. 30.57PCh. 30 - Prob. 30.58PCh. 30 - Prob. 30.59PCh. 30 - Prob. 30.60PCh. 30 - Prob. 30.61PCh. 30 - Prob. 30.62PCh. 30 - Prob. 30.63PCh. 30 - Prob. 30.64PCh. 30 - Prob. 30.65PCh. 30 - Prob. 30.66PCh. 30 - Prob. 30.67PCh. 30 - Prob. 30.68PCh. 30 - Prob. 30.69PCh. 30 - Prob. 30.70PCh. 30 - Prob. 30.71PCh. 30 - Prob. 30.72PCh. 30 - Prob. 30.73PCh. 30 - Prob. 30.74PCh. 30 - Prob. 30.75PCh. 30 - Prob. 30.76PCh. 30 - Why is it necessary to have protein in our diets?Ch. 30 - Prob. 30.78PCh. 30 - Prob. 30.79PCh. 30 - Prob. 30.80PCh. 30 - Prob. 30.81PCh. 30 - Prob. 30.82PCh. 30 - Egg yolk contains a lot of lecithin (a...Ch. 30 - Prob. 30.84PCh. 30 - Prob. 30.85PCh. 30 - Prob. 30.86P
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