ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Question
Chapter 30, Problem 30.16P
Interpretation Introduction
Interpretation: The structure of PEF, polyethylene furanoate, a
Concept introduction: In Step-growth
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Draw the structure of PEF, polyethylene furanoate, a condensation polymer formed from furandicarboxylic acid and ethylene glycol. PEF, which can be synthesized from precursors that are obtained from renewable resources, has many of the same properties as polyethylene terephthalate (PET).
Draw the structure of the polymer formed from ring-opening metathesis polymerization (ROMP) of each monomer.
Poly(vinyl alcohol), a hydrophilic polymer used in aqueous adhesives, is made by polymerizing vinyl acetate and then hydrolyzing the ester linkages. Give the structures of poly(vinyl acetate) and poly(vinyl alcohol)
Chapter 30 Solutions
ORGANIC CHEMISTRY
Ch. 30 - Prob. 30.1PCh. 30 - Prob. 30.2PCh. 30 - Prob. 30.3PCh. 30 - Draw the mechanism for the radical polymerization...Ch. 30 - Prob. 30.5PCh. 30 - Prob. 30.6PCh. 30 - Prob. 30.7PCh. 30 - Prob. 30.8PCh. 30 - Prob. 30.9PCh. 30 - Prob. 30.10P
Ch. 30 - Prob. 30.11PCh. 30 - Problem 30.12
What polymer is formed by anionic...Ch. 30 - Prob. 30.13PCh. 30 - Prob. 30.14PCh. 30 - Problem 30.15
What polyamide is formed from each...Ch. 30 - Prob. 30.16PCh. 30 - Prob. 30.17PCh. 30 - Prob. 30.18PCh. 30 - Prob. 30.19PCh. 30 - Prob. 30.20PCh. 30 - Prob. 30.21PCh. 30 - Prob. 30.22PCh. 30 - Prob. 30.23PCh. 30 - Prob. 30.24PCh. 30 - Prob. 30.25PCh. 30 - 30.26 Draw the structure of the polymer formed by...Ch. 30 - Prob. 30.27PCh. 30 - Prob. 30.28PCh. 30 - Prob. 30.29PCh. 30 - 30.30 Draw each polymer in Problem 30.29 using the...Ch. 30 - Prob. 30.31PCh. 30 - Prob. 30.32PCh. 30 - Prob. 30.33PCh. 30 - Prob. 30.34PCh. 30 - Prob. 30.35PCh. 30 - Prob. 30.36PCh. 30 - Prob. 30.37PCh. 30 - Prob. 30.38PCh. 30 - 30.39 Draw a stepwise mechanism for the...Ch. 30 - 30.40 Cationic polymerization of 3-phenylpropene ...Ch. 30 - Prob. 30.41PCh. 30 - Prob. 30.42PCh. 30 - 30.43 Although styrene undergoes both cationic and...Ch. 30 - 30.44 Rank the following compounds in order of...Ch. 30 - Prob. 30.45PCh. 30 - Prob. 30.46PCh. 30 - 30.47 Draw a stepwise mechanism for the following...Ch. 30 - 30.48 Draw a stepwise mechanism for the reaction...Ch. 30 - 30.49 Draw the products of each reaction.
a. e....Ch. 30 - Prob. 30.50PCh. 30 - Prob. 30.51PCh. 30 - 30.52 (a) Explain why poly (vinyl alcohol) cannot...Ch. 30 - 30.53 Devise a synthesis of terephthalic acid and...Ch. 30 - Prob. 30.54PCh. 30 - Prob. 30.55PCh. 30 - 30.56 Compound A is a novel poly (ester amide)...Ch. 30 - 30.57 Researchers at Rutgers University have...Ch. 30 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 30 - 30.59 Although chain branching in radical...Ch. 30 - Prob. 30.60P
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Similar questions
- Briefly explain each of the polymers. Indicate whether the polymer is a natural polymer or synthetic polymer. - Nylon - Polystyrene - Polyester - Poly (Vinyl Acetate) - Poly (Vinylidene Chloride)arrow_forwardPoly(vinyl alcohol), a hydrophilic polymer used in aqueous adhesives, is made by polymerizing vinyl acetate and then hydrolyzing the ester linkages. We have seen that basic hydrolysis destroys the Dacron polymer. Poly(vinyl acetate) is converted to poly(vinyl alcohol) by a basic hydrolysis of the ester groups. Why doesn’t the hydrolysis destroy the poly(vinyl alcohol)polymer?arrow_forwardExplain with more details, how you can prepare poly(propylene oxide) by using Anionic and Cationic polymerizations?arrow_forward
- Draw the structure of the monomer for each polymer. - Nylon - Polyester - Polystyrene - Poly (Vinyl Acetate) - Poly (Vinylidene Chloride)arrow_forwardBriefly explain each of the polymers. Indicate either the polymer is produced by condensation or addition polymerization. - Nylon - Polystyrene - Polyester - Poly (Vinyl Acetate) - Poly (Vinylidene Chloride)arrow_forwardglyptal polymer is obtained from glycol by reacting with which acid?arrow_forward
- Poly(trimethylene carbamate) is used in high-quality synthetic leather. What type of polymer is poly(trimethylene carbamate)?arrow_forwardPolymer: Poly(vinylidene chloride) Indicate whether the polymer is a natural polymer or synthetic polymer. Indicate whether the polymer is produced by condensation or addition polymerization. Give the structure of the monomer used to produce the polymer. Discuss how the polymer is produced, its chemical and physical properties, factors that effecting their properties and their major application.arrow_forward1) Draw the structure for the polymer (repeat unit only) produced from the monomer vinylidene dichloride (CH₂=CCl₂). 2) One of the most common consumer plastics is PET (polyethylene terephthalate), which is used extensively in containers for food and beverage products. Coca-Cola has recently come up with a biobased source of ethylene glycol for synthesizing this polymer, however, the terephthalic acid is still derived from petroleum sources. A sustainable source of terephthalic acid is therefore highly desired. One candidate is 2,5-furandioic acid. Draw the repeat unit for the resulting sustainable polyester derived from 2,5- furandioic acid and ethylene glycol.arrow_forward
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