Interpretation: The structure of the polymer formed on reaction of
Concept introduction: In Step-growth
The polymers which can be melted and moulded to different shapes on heating are thermoplastic polymers. The highly crossed linked polymers which cannot be melted and moulded to different shapes are thermosetting polymers.
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Chapter 30 Solutions
ORGANIC CHEMISTRY
- A thermosetting material called polyester is made when a carboxylic acid reacts with dialcohol. Write the condensation polymerization with byproduct. The monomers of carboxylic acid and dialcohol are respectively: HO-C -C-OH HO-CH,CH,-OHarrow_forwardKodel is a condensation polymer made from terphthalic acid and 1,4-cyclohexandethanol. Write the structure of the resulting polymer.arrow_forwardWhat monomer is needed to form each polymer? COOEt COOEt cOOEt Et = CH,CH3 polyisobutylene (used to make basketballs) poly(ethyl acrylate) (used in latex paints)arrow_forward
- What polymer is formed when methyl α-methylacrylate [CH 2 C(CH 3)CO2CH 3] is polymerized? This polymer is used in Lucite and Plexiglas, transparent materials that are lighter but more impact resistant than glass.arrow_forwardWhat monomer is used to form poly(vinyl acetate), a polymer used in paints and adhesives?arrow_forwardDraw the structure of the polymer formed from ring-opening metathesis polymerization (ROMP) of each monomer.arrow_forward
- Poly(vinyl alcohol), a hydrophilic polymer used in aqueous adhesives, is made by polymerizing vinyl acetate and then hydrolyzing the ester linkages. We have seen that basic hydrolysis destroys the Dacron polymer. Poly(vinyl acetate) is converted to poly(vinyl alcohol) by a basic hydrolysis of the ester groups. Why doesn’t the hydrolysis destroy the poly(vinyl alcohol)polymer?arrow_forwardPoly(vinyl alcohol), PVA, is produced from poly(vinyl acetate) by converting the acetate groups into hydroxyl groups (Section 26.6a.1). As the number of hydroxyl groups in PVA increases, the solubility of the polymer in water decreases. How do you explain this behavior?arrow_forwardWhat is the structure of the monomer from which the following polymer is made? Select one O a. H2C CH, O b. HC-CH OC. Oe. CH3arrow_forward
- Write the chemical equation for the reaction of ethanoic acid with N-methylethanamine. Which is formula of this rule of reaction?arrow_forwardExplain the effects the addition of glycerol (a triol) will have on the molecular architecture of the following polymerization reactions: a) Condensation polymerization of terephthalic acid + ethylene glycol b) Condensation polymerization of 6-hydroxyhexanoic acidarrow_forward(a) Draw the structure of polystyrene, which is formed by polymerizing the monomer styrene, C6H5CH=CH2. (b) What monomer is used to form poly(vinyl acetate), a polymer used in paints and adhesives?arrow_forward
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