Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 3, Problem 43Q
Interpretation Introduction
Interpretation:
Possibility for the stratospheric ozone to offer any protection from UV radiation that destroys the ozone layer has to be discussed.
Concept-Introduction:
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Draw the anti-Markovnikov product of the hydration of this alkene.
this problem.
Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 3 Solutions
Chemistry In Context
Ch. 3.1 - Prob. 3.2YTCh. 3.1 - Using Equation 3.1, answer the following...Ch. 3.1 - Prob. 3.4YTCh. 3.1 - Prob. 3.5YTCh. 3.1 - Scientific Practices Energy from the Sun Examine...Ch. 3.2 - Skill Building Wavelength, Frequency, and Energy...Ch. 3.3 - Skill Building The ABCs of Solar UV a. Arrange...Ch. 3.3 - Prob. 3.9YTCh. 3.4 - Prob. 3.10YTCh. 3.4 - You Decide Exposure Examine the curve shown in...
Ch. 3.4 - Prob. 3.12YTCh. 3.4 - Prob. 3.13YTCh. 3.5 - Prob. 3.14YTCh. 3.5 - Prob. 3.15YTCh. 3.6 - Prob. 3.16YTCh. 3.7 - Draw the Lewis structure for each molecule. a. HBr...Ch. 3.7 - Prob. 3.18YTCh. 3.7 - Prob. 3.19YTCh. 3.7 - You Decide The Ozone Layer Based on the reactions...Ch. 3.8 - Prob. 3.21YTCh. 3.8 - Prob. 3.22YTCh. 3.8 - Prob. 3.23YTCh. 3.8 - Prob. 3.24YTCh. 3.9 - Prob. 3.25YTCh. 3.10 - Prob. 3.26YTCh. 3.10 - Prob. 3.27YTCh. 3.10 - Prob. 3.28YTCh. 3.10 - Prob. 3.29YTCh. 3.11 - Skill Building Particulate Classification An...Ch. 3.11 - Prob. 3.31YTCh. 3.11 - Prob. 3.32YTCh. 3.11 - Prob. 3.33YTCh. 3.11 - Scientific Practices UV Interactions with Matter...Ch. 3 - How does ozone differ from oxygen in its chemical...Ch. 3 - Prob. 2QCh. 3 - Prob. 3QCh. 3 - Prob. 4QCh. 3 - Prob. 5QCh. 3 - a. What is a Dobson unit? b. Does a reading of 320...Ch. 3 - Using the periodic table as a guide, specify the...Ch. 3 - Consider this representation of a periodic table....Ch. 3 - Give the name and symbol for the element with this...Ch. 3 - Prob. 10QCh. 3 - Assuming that the octet rule applies, draw the...Ch. 3 - Prob. 12QCh. 3 - Consider these two waves representing different...Ch. 3 - Use Figure 3.4 to specify the region of the...Ch. 3 - What determines the color of light? Describe the...Ch. 3 - Prob. 16QCh. 3 - Does all light travel at the same speed in a...Ch. 3 - Arrange these types of radiation in order of...Ch. 3 - The microwaves in home microwave ovens have a...Ch. 3 - Ultraviolet radiation is categorized as UVA, UVB,...Ch. 3 - Calculate the wavelength, in nanometers, of the...Ch. 3 - The distance from Earth to the Sun is about 1.50 ...Ch. 3 - Draw Lewis structures for any two different CFCs.Ch. 3 - Prob. 24QCh. 3 - Prob. 25QCh. 3 - Prob. 26QCh. 3 - The following free radicals all play a role in...Ch. 3 - a. How were the original measurements of increases...Ch. 3 - Prob. 29QCh. 3 - The EPA has used the slogan Ozone: Good Up High,...Ch. 3 - Nobel Laureate F. Sherwood Rowland referred to the...Ch. 3 - Prob. 32QCh. 3 - Prob. 33QCh. 3 - Prob. 34QCh. 3 - Prob. 35QCh. 3 - The average length of an OO single bond is 132 pm....Ch. 3 - Prob. 37QCh. 3 - Describe why ozone is more reactive than oxygen...Ch. 3 - Prob. 39QCh. 3 - Prob. 40QCh. 3 - Prob. 41QCh. 3 - All the reports of the damage caused by UV...Ch. 3 - Prob. 43QCh. 3 - Prob. 44QCh. 3 - Prob. 45QCh. 3 - Prob. 46QCh. 3 - Prob. 47QCh. 3 - Development of the stratospheric ozone hole has...Ch. 3 - Prob. 49QCh. 3 - Prob. 50QCh. 3 - Resonance structures can be used to explain the...Ch. 3 - Prob. 52QCh. 3 - Prob. 53QCh. 3 - Prob. 54QCh. 3 - Prob. 55QCh. 3 - Many different types of ozone generators...Ch. 3 - The effect a chemical substance has on the ozone...Ch. 3 - Cooking with an electric stove can have a negative...Ch. 3 - One mechanism that helps break down ozone in the...Ch. 3 - Polar stratospheric clouds (PSCs) play an...Ch. 3 - Prob. 61Q
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- fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transferarrow_forward34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10arrow_forwardelow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forward
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