Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Question
Chapter 3, Problem 12Q
Interpretation Introduction
Interpretation: The Lewis structure of oxygen atom, oxygen molecule ozone, and hydroxyl radicals has to be determined.
Concept Introduction:
Lewis structure: The bonding between atoms in a molecule satisfies the octet rule of valence electrons and the lone pairs also exist in the molecule. The electron is represented as dot.
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5 (a). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 6
5 (b). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 7
6. Are there any differences between the spectra you obtained
in Beyond Labz and the predicted spectra? If so, what were
the differences?
<
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Chapter 3 Solutions
Chemistry In Context
Ch. 3.1 - Prob. 3.2YTCh. 3.1 - Using Equation 3.1, answer the following...Ch. 3.1 - Prob. 3.4YTCh. 3.1 - Prob. 3.5YTCh. 3.1 - Scientific Practices Energy from the Sun Examine...Ch. 3.2 - Skill Building Wavelength, Frequency, and Energy...Ch. 3.3 - Skill Building The ABCs of Solar UV a. Arrange...Ch. 3.3 - Prob. 3.9YTCh. 3.4 - Prob. 3.10YTCh. 3.4 - You Decide Exposure Examine the curve shown in...
Ch. 3.4 - Prob. 3.12YTCh. 3.4 - Prob. 3.13YTCh. 3.5 - Prob. 3.14YTCh. 3.5 - Prob. 3.15YTCh. 3.6 - Prob. 3.16YTCh. 3.7 - Draw the Lewis structure for each molecule. a. HBr...Ch. 3.7 - Prob. 3.18YTCh. 3.7 - Prob. 3.19YTCh. 3.7 - You Decide The Ozone Layer Based on the reactions...Ch. 3.8 - Prob. 3.21YTCh. 3.8 - Prob. 3.22YTCh. 3.8 - Prob. 3.23YTCh. 3.8 - Prob. 3.24YTCh. 3.9 - Prob. 3.25YTCh. 3.10 - Prob. 3.26YTCh. 3.10 - Prob. 3.27YTCh. 3.10 - Prob. 3.28YTCh. 3.10 - Prob. 3.29YTCh. 3.11 - Skill Building Particulate Classification An...Ch. 3.11 - Prob. 3.31YTCh. 3.11 - Prob. 3.32YTCh. 3.11 - Prob. 3.33YTCh. 3.11 - Scientific Practices UV Interactions with Matter...Ch. 3 - How does ozone differ from oxygen in its chemical...Ch. 3 - Prob. 2QCh. 3 - Prob. 3QCh. 3 - Prob. 4QCh. 3 - Prob. 5QCh. 3 - a. What is a Dobson unit? b. Does a reading of 320...Ch. 3 - Using the periodic table as a guide, specify the...Ch. 3 - Consider this representation of a periodic table....Ch. 3 - Give the name and symbol for the element with this...Ch. 3 - Prob. 10QCh. 3 - Assuming that the octet rule applies, draw the...Ch. 3 - Prob. 12QCh. 3 - Consider these two waves representing different...Ch. 3 - Use Figure 3.4 to specify the region of the...Ch. 3 - What determines the color of light? Describe the...Ch. 3 - Prob. 16QCh. 3 - Does all light travel at the same speed in a...Ch. 3 - Arrange these types of radiation in order of...Ch. 3 - The microwaves in home microwave ovens have a...Ch. 3 - Ultraviolet radiation is categorized as UVA, UVB,...Ch. 3 - Calculate the wavelength, in nanometers, of the...Ch. 3 - The distance from Earth to the Sun is about 1.50 ...Ch. 3 - Draw Lewis structures for any two different CFCs.Ch. 3 - Prob. 24QCh. 3 - Prob. 25QCh. 3 - Prob. 26QCh. 3 - The following free radicals all play a role in...Ch. 3 - a. How were the original measurements of increases...Ch. 3 - Prob. 29QCh. 3 - The EPA has used the slogan Ozone: Good Up High,...Ch. 3 - Nobel Laureate F. Sherwood Rowland referred to the...Ch. 3 - Prob. 32QCh. 3 - Prob. 33QCh. 3 - Prob. 34QCh. 3 - Prob. 35QCh. 3 - The average length of an OO single bond is 132 pm....Ch. 3 - Prob. 37QCh. 3 - Describe why ozone is more reactive than oxygen...Ch. 3 - Prob. 39QCh. 3 - Prob. 40QCh. 3 - Prob. 41QCh. 3 - All the reports of the damage caused by UV...Ch. 3 - Prob. 43QCh. 3 - Prob. 44QCh. 3 - Prob. 45QCh. 3 - Prob. 46QCh. 3 - Prob. 47QCh. 3 - Development of the stratospheric ozone hole has...Ch. 3 - Prob. 49QCh. 3 - Prob. 50QCh. 3 - Resonance structures can be used to explain the...Ch. 3 - Prob. 52QCh. 3 - Prob. 53QCh. 3 - Prob. 54QCh. 3 - Prob. 55QCh. 3 - Many different types of ozone generators...Ch. 3 - The effect a chemical substance has on the ozone...Ch. 3 - Cooking with an electric stove can have a negative...Ch. 3 - One mechanism that helps break down ozone in the...Ch. 3 - Polar stratospheric clouds (PSCs) play an...Ch. 3 - Prob. 61Q
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- Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**arrow_forward11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5arrow_forwardО δα HO- H -Br δα HO-- + + -Br [B] 8+ HO- -Br δα नarrow_forward
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