Chemistry: The Molecular Nature of Matter and Change - Standalone book
7th Edition
ISBN: 9780073511177
Author: Martin Silberberg Dr., Patricia Amateis Professor
Publisher: McGraw-Hill Education
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Question
Chapter 3, Problem 3.66P
Interpretation Introduction
Interpretation:
A road map for a reaction between reactant A and reactant B to form a product C is to be drawn. Also, a plan to find the mass of C in grams is to be written.
Concept introduction:
In a balanced chemical equation, the total mass of reactants and products are equal in a balanced chemical equation, thus, it obeyed the law of conservation of mass. Also, the amounts of substances in a balanced
A limiting reagent is the one that is completely consumed in a chemical reaction. The amount of product formed in any chemical reaction has to be in accordance with the limiting reagent of the reaction.
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Give reason(s) for six from the followings [using equations if possible] a. Addition of sodium carbonate to sulfanilic acid in the Methyl Orange preparation. b. What happened if the diazotization reaction gets warmed up by mistake. c. Addition of sodium nitrite in acidified solution in MO preparation through the diazotization d. Using sodium dithionite dihydrate in the second step for Luminol preparation. e. In nitroaniline preparation, addition of the acid mixture (nitric acid and sulfuric acid) to the product of step I. f. What is the main reason of the acylation step in nitroaniline preparation g. Heating under reflux. h. Fusion of an organic compound with sodium.
HAND WRITTEN PLEASE
edict the major products of the following organic reaction:
u
A
+
?
CN
Some important notes:
• Draw the major product, or products, of the reaction in the drawing area below.
• If there aren't any products, because no reaction will take place, check the box below the drawing area instead.
Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
Explanation
Check
Click and drag to start drawing a structure.
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© 2025 McGraw Hill LLC. All Rights Reserved. Te
LMUNDARY
Sketch the intermediates for A,B,C & D.
Chapter 3 Solutions
Chemistry: The Molecular Nature of Matter and Change - Standalone book
Ch. 3.1 - Graphite is the crystalline form of carbon used in...Ch. 3.1 - Prob. 3.1BFPCh. 3.1 - At rest, a person inhales 9.72×1021 nitrogen...Ch. 3.1 - Prob. 3.2BFPCh. 3.1 - Prob. 3.3AFPCh. 3.1 - Prob. 3.3BFPCh. 3.1 - Fluoride ion is added to drinking water to prevent...Ch. 3.1 - Calcium chloride is applied to highways in winter...Ch. 3.1 - Tetraphosphorus decoxide reacts with water to form...Ch. 3.1 - Prob. 3.5BFP
Ch. 3.1 - Prob. 3.6AFPCh. 3.1 - For many years, compounds known as...Ch. 3.1 - Use the information in Follow-up Problem 3.6A to...Ch. 3.1 - Prob. 3.7BFPCh. 3.2 - Prob. 3.8AFPCh. 3.2 - A sample of an unknown compound contains 6.80 mol...Ch. 3.2 - A sample of an unknown compound is found to...Ch. 3.2 - Prob. 3.9BFPCh. 3.2 - Prob. 3.10AFPCh. 3.2 - Prob. 3.10BFPCh. 3.2 - A dry-cleaning solvent (ℳ = 146.99 g/mol) that...Ch. 3.2 - Prob. 3.11BFPCh. 3.3 - Prob. 3.12AFPCh. 3.3 - Prob. 3.12BFPCh. 3.3 - Prob. 3.13AFPCh. 3.3 - Prob. 3.13BFPCh. 3.4 - Prob. 3.14AFPCh. 3.4 - The tarnish that forms on objects made of silver...Ch. 3.4 - Prob. 3.15AFPCh. 3.4 - In the reaction that removes silver tarnish (see...Ch. 3.4 - Prob. 3.16AFPCh. 3.4 - Prob. 3.16BFPCh. 3.4 - Prob. 3.17AFPCh. 3.4 - Prob. 3.17BFPCh. 3.4 - Prob. 3.18AFPCh. 3.4 - Prob. 3.18BFPCh. 3.4 - In the reaction in Follow-up Problem 3.18A, how...Ch. 3.4 - Prob. 3.19BFPCh. 3.4 - Prob. 3.20AFPCh. 3.4 - Prob. 3.20BFPCh. 3.4 - Marble (calcium carbonate) reacts with...Ch. 3.4 - Prob. 3.21BFPCh. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Why might the expression “1 mol of chlorine” be...Ch. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Calculate the molar mass of each of the...Ch. 3 - Prob. 3.10PCh. 3 - Prob. 3.11PCh. 3 - Calculate each of the following quantities:
Mass...Ch. 3 - Calculate each of the following quantities:
Amount...Ch. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Calculate each of the following:
Mass % of H in...Ch. 3 - Calculate each of the following:
Mass % of I in...Ch. 3 - Calculate each of the following:
Mass fraction of...Ch. 3 - Calculate each of the following:
Mass fraction of...Ch. 3 - Oxygen is required for the metabolic combustion of...Ch. 3 - Cisplatin (right), or Platinol, is used in the...Ch. 3 - Allyl sulfide (below) gives garlic its...Ch. 3 - Iron reacts slowly with oxygen and water to form a...Ch. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - The mineral galena is composed of lead(II) sulfide...Ch. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - List three ways compositional data may be given in...Ch. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - What is the molecular formula of each...Ch. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Find the empirical formula of each of the...Ch. 3 - An oxide of nitrogen contains 30.45 mass % N. (a)...Ch. 3 - Prob. 3.45PCh. 3 - A sample of 0.600 mol of a metal M reacts...Ch. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.57PCh. 3 - Prob. 3.58PCh. 3 - Prob. 3.59PCh. 3 - Prob. 3.60PCh. 3 - Prob. 3.61PCh. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - Prob. 3.64PCh. 3 - Prob. 3.65PCh. 3 - Prob. 3.66PCh. 3 - Prob. 3.67PCh. 3 - Prob. 3.68PCh. 3 - Prob. 3.69PCh. 3 - Prob. 3.70PCh. 3 - Prob. 3.71PCh. 3 - Prob. 3.72PCh. 3 - Prob. 3.73PCh. 3 - Elemental phosphorus occurs as tetratomic...Ch. 3 - Prob. 3.75PCh. 3 - Solid iodine trichloride is prepared in two steps:...Ch. 3 - Prob. 3.77PCh. 3 - Prob. 3.78PCh. 3 - Prob. 3.79PCh. 3 - Prob. 3.80PCh. 3 - Prob. 3.81PCh. 3 - Prob. 3.82PCh. 3 - Prob. 3.83PCh. 3 - Prob. 3.84PCh. 3 - Prob. 3.85PCh. 3 - Prob. 3.86PCh. 3 - Prob. 3.87PCh. 3 - Prob. 3.88PCh. 3 - Prob. 3.89PCh. 3 - When 20.5 g of methane and 45.0 g of chlorine gas...Ch. 3 - Prob. 3.91PCh. 3 - Prob. 3.92PCh. 3 - Prob. 3.93PCh. 3 - Prob. 3.94PCh. 3 - Prob. 3.95PCh. 3 - Sodium borohydride (NaBH4) is used industrially in...Ch. 3 - Prob. 3.97PCh. 3 - The first sulfur-nitrogen compound was prepared in...Ch. 3 - Prob. 3.99PCh. 3 - Prob. 3.100PCh. 3 - Prob. 3.101PCh. 3 - Serotonin () transmits nerve impulses between...Ch. 3 - In 1961, scientists agreed that the atomic mass...Ch. 3 - Prob. 3.104PCh. 3 - Isobutylene is a hydrocarbon used in the...Ch. 3 - The multistep smelting of ferric oxide to form...Ch. 3 - Prob. 3.107PCh. 3 - Prob. 3.108PCh. 3 - Prob. 3.109PCh. 3 - Prob. 3.110PCh. 3 - Prob. 3.111PCh. 3 - Prob. 3.112PCh. 3 - Prob. 3.113PCh. 3 - Prob. 3.114PCh. 3 - Prob. 3.115PCh. 3 - For the reaction between solid tetraphosphorus...Ch. 3 - Prob. 3.117PCh. 3 - Prob. 3.118PCh. 3 - Prob. 3.119PCh. 3 - Prob. 3.120PCh. 3 - Prob. 3.121PCh. 3 - Prob. 3.122PCh. 3 - Prob. 3.123PCh. 3 - Ferrocene, synthesized in 1951, was the first...Ch. 3 - Prob. 3.125PCh. 3 - Prob. 3.126PCh. 3 - Citric acid (below) is concentrated in citrus...Ch. 3 - Prob. 3.128PCh. 3 - Nitrogen monoxide reacts with elemental oxygen to...Ch. 3 - Prob. 3.130PCh. 3 - Prob. 3.131PCh. 3 - Manganese is a key component of extremely hard...Ch. 3 - The human body excretes nitrogen in the form of...Ch. 3 - Aspirin (acetylsalicylic acid, C9H8O4) is made by...Ch. 3 - Prob. 3.135PCh. 3 - Prob. 3.136PCh. 3 - Prob. 3.137PCh. 3 - When powdered zinc is heated with sulfur, a...Ch. 3 - Cocaine (C17H21O4N) is a natural substance found...Ch. 3 - Prob. 3.140P
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Similar questions
- Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? O ? A . If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. . If your answer is no, check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. ㅇ 80 F5 F6 A 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Cente FIGarrow_forwardIn methyl orange preparation, if the reaction started with 0.5 mole of sulfanilic acid to form the diazonium salt of this compound and then it converted to methyl orange [0.2 mole]. If the efficiency of the second step was 50%, Calculate: A. Equation(s) of Methyl Orange synthesis: Diazotization and coupling reactions. B. How much diazonium salt was formed in this reaction? C. The efficiency percentage of the diazotization reaction D. Efficiency percentage of the whole reaction.arrow_forwardHand written equations pleasearrow_forward
- Hand written equations pleasearrow_forward> each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that: 1. the rate of substitution doesn't depend on nucleophile concentration and 2. the products are a roughly 50/50 mixture of enantiomers. Substrate A Substrate B Faster Rate X Ś CI (Choose one) (Choose one) CI Br Explanation Check Br (Choose one) © 2025 McGraw Hill LLC. All Rights Farrow_forwardNMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at 4.1 ppm? Select the single best answer. The H O HỌC—C—0—CH, CH, 2 A ethyl acetate H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm Check OA B OC ch B C Save For Later Submit Ass © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center |arrow_forward
- How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red Note for advanced students: In this question, any multiplet is counted as one signal. 1 Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. Check For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. O ✓ No additional Hs to color in top molecule ง No additional Hs to color in bottom…arrow_forwardin the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstantarrow_forwardtrue or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forward
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