
Chemistry: The Molecular Nature of Matter and Change - Standalone book
7th Edition
ISBN: 9780073511177
Author: Martin Silberberg Dr., Patricia Amateis Professor
Publisher: McGraw-Hill Education
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Chapter 3, Problem 3.54P
Interpretation Introduction
Interpretation:
Whether the approach of student
Concept introduction:
In balancing a chemical equation, only the coefficients of chemical species may vary leaving no change in chemical species and their respective chemical formula. In a balanced chemical equation, the total mass of reactants and products are equal in a balanced chemical equation, thus, it obeyed the law of conservation of mass.
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Using the conditions of spontaneity to deduce the signs of AH and AS
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
A
This reaction is always spontaneous, but
proceeds slower at temperatures above
120. °C.
ΔΗ is
(pick one)
AS is
(pick one)
ΔΗ is
(pick one)
B
This reaction is spontaneous except above
117. °C.
AS is
(pick one)
ΔΗ is
(pick one)
This reaction is slower below 20. °C than
C
above.
AS is
|(pick one)
?
18
Ar
1
Calculating the pH at equivalence of a titration
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Your answer is incorrect.
0/5
a
A chemist titrates 70.0 mL of a 0.7089 M hydrocyanic acid (HCN) solution with 0.4574M KOH solution at 25 °C. Calculate the pH at equivalence. The pK of
hydrocyanic acid is 9.21.
Round your answer to 2 decimal places.
Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added.
pH
=
11.43]
G
00.
18
Ar
B•
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Chapter 3 Solutions
Chemistry: The Molecular Nature of Matter and Change - Standalone book
Ch. 3.1 - Graphite is the crystalline form of carbon used in...Ch. 3.1 - Prob. 3.1BFPCh. 3.1 - At rest, a person inhales 9.72×1021 nitrogen...Ch. 3.1 - Prob. 3.2BFPCh. 3.1 - Prob. 3.3AFPCh. 3.1 - Prob. 3.3BFPCh. 3.1 - Fluoride ion is added to drinking water to prevent...Ch. 3.1 - Calcium chloride is applied to highways in winter...Ch. 3.1 - Tetraphosphorus decoxide reacts with water to form...Ch. 3.1 - Prob. 3.5BFP
Ch. 3.1 - Prob. 3.6AFPCh. 3.1 - For many years, compounds known as...Ch. 3.1 - Use the information in Follow-up Problem 3.6A to...Ch. 3.1 - Prob. 3.7BFPCh. 3.2 - Prob. 3.8AFPCh. 3.2 - A sample of an unknown compound contains 6.80 mol...Ch. 3.2 - A sample of an unknown compound is found to...Ch. 3.2 - Prob. 3.9BFPCh. 3.2 - Prob. 3.10AFPCh. 3.2 - Prob. 3.10BFPCh. 3.2 - A dry-cleaning solvent (ℳ = 146.99 g/mol) that...Ch. 3.2 - Prob. 3.11BFPCh. 3.3 - Prob. 3.12AFPCh. 3.3 - Prob. 3.12BFPCh. 3.3 - Prob. 3.13AFPCh. 3.3 - Prob. 3.13BFPCh. 3.4 - Prob. 3.14AFPCh. 3.4 - The tarnish that forms on objects made of silver...Ch. 3.4 - Prob. 3.15AFPCh. 3.4 - In the reaction that removes silver tarnish (see...Ch. 3.4 - Prob. 3.16AFPCh. 3.4 - Prob. 3.16BFPCh. 3.4 - Prob. 3.17AFPCh. 3.4 - Prob. 3.17BFPCh. 3.4 - Prob. 3.18AFPCh. 3.4 - Prob. 3.18BFPCh. 3.4 - In the reaction in Follow-up Problem 3.18A, how...Ch. 3.4 - Prob. 3.19BFPCh. 3.4 - Prob. 3.20AFPCh. 3.4 - Prob. 3.20BFPCh. 3.4 - Marble (calcium carbonate) reacts with...Ch. 3.4 - Prob. 3.21BFPCh. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Why might the expression “1 mol of chlorine” be...Ch. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Calculate the molar mass of each of the...Ch. 3 - Prob. 3.10PCh. 3 - Prob. 3.11PCh. 3 - Calculate each of the following quantities:
Mass...Ch. 3 - Calculate each of the following quantities:
Amount...Ch. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Calculate each of the following:
Mass % of H in...Ch. 3 - Calculate each of the following:
Mass % of I in...Ch. 3 - Calculate each of the following:
Mass fraction of...Ch. 3 - Calculate each of the following:
Mass fraction of...Ch. 3 - Oxygen is required for the metabolic combustion of...Ch. 3 - Cisplatin (right), or Platinol, is used in the...Ch. 3 - Allyl sulfide (below) gives garlic its...Ch. 3 - Iron reacts slowly with oxygen and water to form a...Ch. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - The mineral galena is composed of lead(II) sulfide...Ch. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - List three ways compositional data may be given in...Ch. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - What is the molecular formula of each...Ch. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Find the empirical formula of each of the...Ch. 3 - An oxide of nitrogen contains 30.45 mass % N. (a)...Ch. 3 - Prob. 3.45PCh. 3 - A sample of 0.600 mol of a metal M reacts...Ch. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.57PCh. 3 - Prob. 3.58PCh. 3 - Prob. 3.59PCh. 3 - Prob. 3.60PCh. 3 - Prob. 3.61PCh. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - Prob. 3.64PCh. 3 - Prob. 3.65PCh. 3 - Prob. 3.66PCh. 3 - Prob. 3.67PCh. 3 - Prob. 3.68PCh. 3 - Prob. 3.69PCh. 3 - Prob. 3.70PCh. 3 - Prob. 3.71PCh. 3 - Prob. 3.72PCh. 3 - Prob. 3.73PCh. 3 - Elemental phosphorus occurs as tetratomic...Ch. 3 - Prob. 3.75PCh. 3 - Solid iodine trichloride is prepared in two steps:...Ch. 3 - Prob. 3.77PCh. 3 - Prob. 3.78PCh. 3 - Prob. 3.79PCh. 3 - Prob. 3.80PCh. 3 - Prob. 3.81PCh. 3 - Prob. 3.82PCh. 3 - Prob. 3.83PCh. 3 - Prob. 3.84PCh. 3 - Prob. 3.85PCh. 3 - Prob. 3.86PCh. 3 - Prob. 3.87PCh. 3 - Prob. 3.88PCh. 3 - Prob. 3.89PCh. 3 - When 20.5 g of methane and 45.0 g of chlorine gas...Ch. 3 - Prob. 3.91PCh. 3 - Prob. 3.92PCh. 3 - Prob. 3.93PCh. 3 - Prob. 3.94PCh. 3 - Prob. 3.95PCh. 3 - Sodium borohydride (NaBH4) is used industrially in...Ch. 3 - Prob. 3.97PCh. 3 - The first sulfur-nitrogen compound was prepared in...Ch. 3 - Prob. 3.99PCh. 3 - Prob. 3.100PCh. 3 - Prob. 3.101PCh. 3 - Serotonin () transmits nerve impulses between...Ch. 3 - In 1961, scientists agreed that the atomic mass...Ch. 3 - Prob. 3.104PCh. 3 - Isobutylene is a hydrocarbon used in the...Ch. 3 - The multistep smelting of ferric oxide to form...Ch. 3 - Prob. 3.107PCh. 3 - Prob. 3.108PCh. 3 - Prob. 3.109PCh. 3 - Prob. 3.110PCh. 3 - Prob. 3.111PCh. 3 - Prob. 3.112PCh. 3 - Prob. 3.113PCh. 3 - Prob. 3.114PCh. 3 - Prob. 3.115PCh. 3 - For the reaction between solid tetraphosphorus...Ch. 3 - Prob. 3.117PCh. 3 - Prob. 3.118PCh. 3 - Prob. 3.119PCh. 3 - Prob. 3.120PCh. 3 - Prob. 3.121PCh. 3 - Prob. 3.122PCh. 3 - Prob. 3.123PCh. 3 - Ferrocene, synthesized in 1951, was the first...Ch. 3 - Prob. 3.125PCh. 3 - Prob. 3.126PCh. 3 - Citric acid (below) is concentrated in citrus...Ch. 3 - Prob. 3.128PCh. 3 - Nitrogen monoxide reacts with elemental oxygen to...Ch. 3 - Prob. 3.130PCh. 3 - Prob. 3.131PCh. 3 - Manganese is a key component of extremely hard...Ch. 3 - The human body excretes nitrogen in the form of...Ch. 3 - Aspirin (acetylsalicylic acid, C9H8O4) is made by...Ch. 3 - Prob. 3.135PCh. 3 - Prob. 3.136PCh. 3 - Prob. 3.137PCh. 3 - When powdered zinc is heated with sulfur, a...Ch. 3 - Cocaine (C17H21O4N) is a natural substance found...Ch. 3 - Prob. 3.140P
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