The volume change that occurs with transformation of cubic form of zirconia to tetragonal form should be determined. Concept introduction: Allotrope refers to existence of more than one physical form of an element. Polymorph refers to one or more crystalline form of existence of a substance.

Question

2. Consider a polymeric membrane within a 6 cm diameter stirred ultrafiltration cell. The membrane is 30 μm thick. The membrane has pores equivalent in size to a spherical molecule with a molecular weight of 100,000, a porosity of 80%, and a tortuosity of 2.5. On the feed side of the membrane, we have a solution containing a protein at a concentration of 8 g L-1 with these properties: a = 3 nm and DAB = 6.0 × 10-7 cm² s¹. The solution viscosity is 1 cP. The hydrodynamic pressure on the protein side of the membrane is 20 pounds per square inch (psi) higher than on the filtrate side of the membrane. Assume that the hydrodynamic pressure difference is much larger than the osmotic pressure difference (advection >> diffusion). Determine the convective flow rate of the solution across the membrane.

Answer 1

Question

Chapter 3, Problem 3.42P

Interpretation Introduction

Interpretation:

The volume change that occurs with transformation of cubic form of zirconia to tetragonal form should be determined.

Concept introduction:

Allotrope refers to existence of more than one physical form of an element. Polymorph refers to one or more crystalline form of existence of a substance.

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2. Consider a polymeric membrane within a 6 cm diameter stirred ultrafiltration cell. The membrane is 30 μm thick. The membrane has pores equivalent in size to a spherical molecule with a molecular weight of 100,000, a porosity of 80%, and a tortuosity of 2.5. On the feed side of the membrane, we have a solution containing a protein at a concentration of 8 g L-1 with these properties: a = 3 nm and DAB = 6.0 × 10-7 cm² s¹. The solution viscosity is 1 cP. The hydrodynamic pressure on the protein side of the membrane is 20 pounds per square inch (psi) higher than on the filtrate side of the membrane. Assume that the hydrodynamic pressure difference is much larger than the osmotic pressure difference (advection >> diffusion). Determine the convective flow rate of the solution across the membrane.

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