Thermodynamics, Statistical Thermodynamics, & Kinetics
Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Chapter 3, Problem 3.39NP
Interpretation Introduction

Interpretation:

The following relation needs to be derived for an ideal gas and a Van der Waal gas.

  ( C v V)T=0

Concept Introduction:

The specific heat capacity is defined as the heat required per unit mass to raise the temperature by 1°C at constant volume.

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(*), (*): P Use the Euler and reciprocal relations to show that it is equivalent to Cp - Cy = T Ср - Cv = −T. Сү = -Т. Әр ат av 2 T (1) (2) Use this expression to evaluate Cр - Cv for (1) an ideal gas, and (2) for a van der Waals gas.
(a) Derive, given that dU = dq+ dw, and considering that dU is an exact differential, a general relation between Cy and Cp. (b) Consequently, assume ideal gas behaviour and simplify your result.
2. Evaluate the following integrals. ● -5 dx 5x • S√1 + x dx 3. The pressure of one mole of a van der Waals gas is a function of volume and temperature. Determine if dP is an exact or inexact differential. P ---- RT V-b a V2

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Thermodynamics, Statistical Thermodynamics, & Kinetics

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