Thermodynamics, Statistical Thermodynamics, & Kinetics
Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Chapter 3, Problem 3.13NP
Interpretation Introduction

Interpretation:

From equation Cp= Cv+ TV(β2/K)  , the relation between Cp − Cv for an ideal gas needs to be identified.

Concept Introduction :

The relationship between Cp and Cv with β and K

is represented as follows:

Cp= Cv+ TV(β2/κ) 

Here, Cp is the specific heat capacity at constant pressure, Cv is the specific heat capacity at constant volume, T is temperature, V is volume, β is the coefficient of volumetric thermal expansion at constant pressure.

and κ is isothermal compressibility.

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Assume N₂ behaves as perfect gas. It expands reversibly and adiabatically from Vi to Vf with the pressure change from pi to pf. (a) Derive the temperature versus volume relationship and the pressure and volume relationship for this expansion. (b) When a sample of N₂ of mass 3.12 g at 23.0 °C is allowed to expand reversibly and adiabatically from 4.00 × 10² cm3 to 2.00 dm3, what is the work done by the gas?
4. The heat capacity of solid lead oxide is given by the equation: Cp(T) = 44.35 + 1.47 × 10-3 xT with T in units of K and the resulting Cp(T) in units of K-mol Calculate the change in enthalpy of 1 mole of PbO(s) if it is heated from 200 to 600 K at constant pressure. (Assume no phase transitions take place during this process.)
Calculate V−1(∂V/∂T)p,n for an ideal gas?

Chapter 3 Solutions

Thermodynamics, Statistical Thermodynamics, & Kinetics

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