Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 3, Problem 3.38AP
Interpretation Introduction

(a)

Interpretation:

An acceptable Lewis structure for N5+ cation is to be drawn. The unshared electron pairs are to be included which accounts for the shape of the molecule and its overall plus charge.

Concept introduction:

The Lewis structures are also known as electron dot structures. In the Lewis structure, electrons are denoted by dots. These dots represent the number of electrons present in the outer most shell of an element. The electron pairs shared by the atoms are termed as bonding electrons. Other electrons which do not participate in bond formation but complete the octet around each atom are termed as nonbonding electrons or lone pairs.

Interpretation Introduction

(b)

Interpretation:

The resonating structures of N5+ is to be drawn.

Concept introduction:

Resonance is the phenomena of the delocalization of pi electrons to give extra stability to the molecule. Resonating structures is defined as the structures which have localized electrons. The curved-arrow notation is used to show the transfer of electrons from one atom to another.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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