(a) Interpretation: The glycosidic linkage in disaccharide C is to be identified and the glycosidic linkage is to be classified as α or β and the numbers are to be used to designate the location. Concept introduction: Monosaccharides are the small units of simple sugars. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

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Answer 1

Question

Chapter 28, Problem 28.65P

Interpretation Introduction

(a)

Interpretation: The glycosidic linkage in disaccharide C is to be identified and the glycosidic linkage is to be classified as α or β and the numbers are to be used to designate the location.

Concept introduction: Monosaccharides are the small units of simple sugars. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The compounds E and F are to be identified.

Concept introduction: The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide. Glycosidic linkages are hydrolyzed in presence of acid to form cyclic hemiacetal and corresponding alcohol.

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4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).

Answer 2

Question

Chapter 28, Problem 28.65P

Interpretation Introduction

(a)

Interpretation: The glycosidic linkage in disaccharide C is to be identified and the glycosidic linkage is to be classified as α or β and the numbers are to be used to designate the location.

Concept introduction: Monosaccharides are the small units of simple sugars. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The compounds E and F are to be identified.

Concept introduction: The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide. Glycosidic linkages are hydrolyzed in presence of acid to form cyclic hemiacetal and corresponding alcohol.

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Answer 3

Question

Chapter 28, Problem 28.65P

Interpretation Introduction

(a)

Interpretation: The glycosidic linkage in disaccharide C is to be identified and the glycosidic linkage is to be classified as α or β and the numbers are to be used to designate the location.

Concept introduction: Monosaccharides are the small units of simple sugars. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The compounds E and F are to be identified.

Concept introduction: The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide. Glycosidic linkages are hydrolyzed in presence of acid to form cyclic hemiacetal and corresponding alcohol.

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Answer 4

Question

Chapter 28, Problem 28.65P

Interpretation Introduction

(a)

Interpretation: The glycosidic linkage in disaccharide C is to be identified and the glycosidic linkage is to be classified as α or β and the numbers are to be used to designate the location.

Concept introduction: Monosaccharides are the small units of simple sugars. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The compounds E and F are to be identified.

Concept introduction: The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide. Glycosidic linkages are hydrolyzed in presence of acid to form cyclic hemiacetal and corresponding alcohol.

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Answer 5

Chapter 28, Problem 28.65P

Interpretation Introduction

(a)

Interpretation: The glycosidic linkage in disaccharide C is to be identified and the glycosidic linkage is to be classified as α or β and the numbers are to be used to designate the location.

Concept introduction: Monosaccharides are the small units of simple sugars. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The compounds E and F are to be identified.

Concept introduction: The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide. Glycosidic linkages are hydrolyzed in presence of acid to form cyclic hemiacetal and corresponding alcohol.

Answer 6

Chapter 28, Problem 28.65P

Interpretation Introduction

(a)

Interpretation: The glycosidic linkage in disaccharide C is to be identified and the glycosidic linkage is to be classified as α or β and the numbers are to be used to designate the location.

Concept introduction: Monosaccharides are the small units of simple sugars. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Answer 7

Chapter 28, Problem 28.65P

Interpretation Introduction

(a)

Interpretation: The glycosidic linkage in disaccharide C is to be identified and the glycosidic linkage is to be classified as α or β and the numbers are to be used to designate the location.

Concept introduction: Monosaccharides are the small units of simple sugars. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Answer 8

Interpretation Introduction

(b)

Interpretation: The compounds E and F are to be identified.

Concept introduction: The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide. Glycosidic linkages are hydrolyzed in presence of acid to form cyclic hemiacetal and corresponding alcohol.

Answer 9

Interpretation Introduction

(b)

Interpretation: The compounds E and F are to be identified.

Concept introduction: The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide. Glycosidic linkages are hydrolyzed in presence of acid to form cyclic hemiacetal and corresponding alcohol.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 28 - Prob. 28.1P Ch. 28 - Prob. 28.2P Ch. 28 - Label each stereogenic center as R or S. a. b. c....Ch. 28 - Convert the ball-and-stick model to a Fischer...Ch. 28 - Prob. 28.5P Ch. 28 - Prob. 28.6P Ch. 28 - Prob. 28.7P Ch. 28 - Prob. 28.8P Ch. 28 - Prob. 28.9P Ch. 28 - Prob. 28.10P

Solution Summary: The author explains that the glycosidic linkage in disaccharide C is to be identified and the numbers are to designate the location.

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Chapter 28 Solutions