The structures of A and B are to be predicted. Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C 2 of a product.

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Answer 1

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Chapter 28, Problem 28.28P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Name Section Score Date EXERCISE B pH, pOH, pка, AND PKD CALCULATIONS 1. Complete the following table. Solution [H+] [OH-] PH РОН Nature of Solution A 2 x 10-8 M B 1 x 10-7 M C D 12.3 6.8 2. The following table contains the names, formulas, ka or pka for some common acids. Fill in the blanks in the table. (17 Points) Acid Name Formula Dissociation reaction Ka pka Phosphoric acid H₂PO₁ H3PO4 H++ H₂PO 7.08 x 10-3 Dihydrogen H₂PO H₂PO H+ HPO 6.31 x 10-6 phosphate Hydrogen HPO₁ 12.4 phosphate Carbonic acid H2CO3 Hydrogen HCO 6.35 10.3 carbonate or bicarbonate Acetic acid CH,COOH 4.76 Lactic acid CH₂CHOH- COOH 1.38 x 10 Ammonium NH 5.63 x 10-10 Phenol CH₂OH 1 x 10-10 Protonated form CH3NH3* 3.16 x 10-11 of methylamine

Answer 2

Question

Chapter 28, Problem 28.28P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Answer 3

Question

Chapter 28, Problem 28.28P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Answer 4

Question

Chapter 28, Problem 28.28P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Answer 5

Chapter 28, Problem 28.28P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

Answer 6

Chapter 28, Problem 28.28P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

Answer 7

Chapter 28, Problem 28.28P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 28 - Prob. 28.1P Ch. 28 - Prob. 28.2P Ch. 28 - Label each stereogenic center as R or S. a. b. c....Ch. 28 - Convert the ball-and-stick model to a Fischer...Ch. 28 - Prob. 28.5P Ch. 28 - Prob. 28.6P Ch. 28 - Prob. 28.7P Ch. 28 - Prob. 28.8P Ch. 28 - Prob. 28.9P Ch. 28 - Prob. 28.10P

The structures of A and B are to be predicted. Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C 2 of a product.

Solution Summary: The author explains Kiliani–Fischer synthesis, which is used for the elongation of the carbon chain in aldoses.

Concept explainers

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Chapter 28 Solutions

The structures of A and B are to be predicted. Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C 2 of a product.

Solution Summary: The author explains Kiliani–Fischer synthesis, which is used for the elongation of the carbon chain in aldoses.

Concept explainers

Interpretation: The structures of A and B are to be predicted. Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Chapter 28 Solutions

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.