Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 2.8, Problem 2.2ACP
Salvarsan was long thought to be a single substance. Recently, however, a mass spectrometry study of the compound shows it to be a mixture of two molecules with the same empirical formula. Each has the composition 39.37% C, 3.304% H, 8.741% O, 7.652% N, and 40.932% As. One has a molar mass of 549 g/mol and the other has a molar mass of 915 g/mol. What are the molecular formulas of the compounds?
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Q2. Consider the hydrogenation of ethylene
C2H4 + H2 = C2H6
The heats of combustion and molar entropies for the three gases at 298 K are given by:
C2H4
C2H6
H2
AH comb/kJ mol¹
-1395
-1550
-243
Sº / J K¹ mol-1
220.7
230.4
131.1
The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is
10.9 J K¹ mol¹. Using these data, determine:
(a) the standard enthalpy change at 800 K
(b) the standard entropy change at 800 K
(c) the equilibrium constant at 800 K.
Chapter 2 Solutions
Chemistry & Chemical Reactivity
Ch. 2.1 - 1. What is the mass of an iron atom with 30...Ch. 2.2 - Verify that the atomic weight of chlorine is...Ch. 2.2 - Neon has three stable isotopes, one with a small...Ch. 2.5 - Give the number and identity of the constituent...Ch. 2.5 - (a) Write the formulas of all neutral ionic...Ch. 2.6 - What mass of gold, Au, contains 2.6 1024 atoms?Ch. 2.6 - If you have 454 g of citric acid (H3C6H5O7), what...Ch. 2.7 - 1. Express the composition of ammonium carbonate,...Ch. 2.7 - 1. What is the empirical formula of naphthalene,...Ch. 2.7 - Gallium oxide, GaxOy forms when gallium is combine...
Ch. 2.7 - Hydrated nickel(II) chloride is a beautiful green,...Ch. 2.8 - Prob. 2.12CYUCh. 2.8 - Prob. 1.1ACPCh. 2.8 - Prob. 1.2ACPCh. 2.8 - Prob. 2.1ACPCh. 2.8 - Salvarsan was long thought to be a single...Ch. 2.8 - To determine the density of atmospheric nitrogen....Ch. 2.8 - The density of a mixture of gases may be...Ch. 2.8 - Atmospheric argon is a mixture of three stable...Ch. 2.8 - Given that the density of argon is 1.78 g/L under...Ch. 2 - Prob. 1PSCh. 2 - Define mass number. What is the difference between...Ch. 2 - An atom has a very small nucleus surrounded by an...Ch. 2 - A gold atom has a radius of 145 pm. If you could...Ch. 2 - Give the complete symbol(ZAX), including atomic...Ch. 2 - Give the complete symbol(ZAX), including atomic...Ch. 2 - Prob. 7PSCh. 2 - Atomic structure. 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POF3, is...Ch. 2 - The mass spectrum of CH3Cl is illustrated here....Ch. 2 - Prob. 100PSCh. 2 - Fill in the blanks in the table (one column per...Ch. 2 - Potassium has three naturally occurring isotopes...Ch. 2 - Crossword Puzzle: In the 2 2 box shown here, each...Ch. 2 - The following chart shows a general decline in...Ch. 2 - Copper atoms. 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(a) You are...Ch. 2 - A piece of nickel foil, 0.550 mm thick and 1.25 cm...Ch. 2 - Uranium is used as a fuel, primarily in the form...Ch. 2 - In an experiment, you need 0.125 mol of sodium...Ch. 2 - Mass spectrometric analysis showed that there are...Ch. 2 - If Epsom salt, MgSO4 x H2O, is heated to 250 C,...Ch. 2 - The alum used in cooking is potassium aluminum...Ch. 2 - Tin metal (Sn) and purple iodine (I2) combine to...Ch. 2 - When analyzed, an unknown compound gave these...Ch. 2 - Two general chemistry students working together in...Ch. 2 - To find the empirical formula of tin oxide, you...Ch. 2 - Prob. 165SCQCh. 2 - Prob. 166SCQCh. 2 - The photo here depicts what happens when a coil of...Ch. 2 - A jar contains some number of jelly beans. To find...
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