(a) Interpretation: The R or S configuration to each of the chiral C atom in the given structure is to be assigned. Concept introduction: Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4 th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration. If the 4 th number group is in plane then follow these steps. Swap the 4 group with the group with dash line Assign R/S configuration with clockwise or anticlockwise movement Flip the configuration to get the real configuration. If the 4 th number group is in above the plane shown by wedge line then follow these steps. Swap the 4 group with the group with dash line. Assign R/S configuration with clockwise or anticlockwise movement.

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Answer 1

Question

Chapter 26, Problem 93IAE

Interpretation Introduction

(a)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure is to be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Interpretation Introduction

(b)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure should be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

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Answer 2

Question

Chapter 26, Problem 93IAE

Interpretation Introduction

(a)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure is to be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Interpretation Introduction

(b)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure should be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

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Answer 3

Question

Chapter 26, Problem 93IAE

Interpretation Introduction

(a)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure is to be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Interpretation Introduction

(b)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure should be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

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Answer 4

Question

Chapter 26, Problem 93IAE

Interpretation Introduction

(a)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure is to be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Interpretation Introduction

(b)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure should be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

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Answer 5

Chapter 26, Problem 93IAE

Interpretation Introduction

(a)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure is to be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Interpretation Introduction

(b)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure should be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Answer 6

Chapter 26, Problem 93IAE

Interpretation Introduction

(a)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure is to be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Answer 7

Chapter 26, Problem 93IAE

Interpretation Introduction

(a)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure is to be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure should be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The R or S configuration to each of the chiral C atom in the given structure should be assigned.

Concept introduction:

Enantiomers are optical isomers which can rotate the plane polarized light either clockwise or anticlockwise. These molecules must have at least one chiral C atom which is bonded with four different groups. They are assigned by R and S configuration. The R/S naming follows the Cahn-Ingold-Prelog Rules for naming the enantiomer as R or S-enantiomer. According to Cahn-Ingold-Prelog Rules assign the numbers from 1 to 4 to the groups bonded with chiral C atom on the basis of their molar mass. The essential condition is that the 4^th group or atom must be below the plane means with dash line. If 1(2(3 is clockwise it will be R-configuration and if it is anticlockwise it will be S-configuration.

If the 4^th number group is in plane then follow these steps.

Swap the 4 group with the group with dash line

Assign R/S configuration with clockwise or anticlockwise movement

Flip the configuration to get the real configuration.

If the 4^th number group is in above the plane shown by wedge line then follow these steps.

Swap the 4 group with the group with dash line.

Assign R/S configuration with clockwise or anticlockwise movement.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 26 - Prob. 1E Ch. 26 - Draw a structural formula for each of the...Ch. 26 - Prob. 3E Ch. 26 - Write structural formulas corresponding to these...Ch. 26 - Prob. 5E Ch. 26 - Prob. 6E Ch. 26 - Prob. 7E Ch. 26 - Prob. 8E Ch. 26 - What is the relationship, if any, between the...Ch. 26 - Prob. 10E

Solution Summary: The author explains the R or S configuration to each of the chiral C atom in the given structure is to be assigned.

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Chapter 26 Solutions