EBK GENERAL CHEMISTRY
11th Edition
ISBN: 8220103631259
Author: Bissonnette
Publisher: YUZU
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Textbook Question
Chapter 26, Problem 2E
Draw a structural formula for each of the following compounds and provide the preferred IUPAC name
a. 3-isopropyloctane;
b. 2-chloro-3-methylpentane;
c. 2-pentene;
d. dipropyl ether
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
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Aa
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V
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SFCC
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Chapter 26 Solutions
EBK GENERAL CHEMISTRY
Ch. 26 - Prob. 1ECh. 26 - Draw a structural formula for each of the...Ch. 26 - Prob. 3ECh. 26 - Write structural formulas corresponding to these...Ch. 26 - Prob. 5ECh. 26 - Prob. 6ECh. 26 - Prob. 7ECh. 26 - Prob. 8ECh. 26 - What is the relationship, if any, between the...Ch. 26 - Prob. 10E
Ch. 26 - Prob. 11ECh. 26 - Prob. 12ECh. 26 - Identify the chiral carbon atoms, ¡f any, in the...Ch. 26 - Prob. 14ECh. 26 - Identify the chiral carbon atoms, ¡f any, in the...Ch. 26 - Prob. 16ECh. 26 - Prob. 17ECh. 26 - Prob. 18ECh. 26 - Prob. 19ECh. 26 - By name or formula, give one example of each of...Ch. 26 - Prob. 21ECh. 26 - Prob. 22ECh. 26 - Prob. 23ECh. 26 - Prob. 24ECh. 26 - Prob. 25ECh. 26 - Prob. 26ECh. 26 - Prob. 27ECh. 26 - Prob. 28ECh. 26 - Prob. 29ECh. 26 - Prob. 30ECh. 26 - Prob. 31ECh. 26 - Prob. 32ECh. 26 - Prob. 33ECh. 26 - Prob. 34ECh. 26 - Does each of the following names convey sufficient...Ch. 26 - Prob. 36ECh. 26 - Prob. 37ECh. 26 - Supply condensed structural formulas for the...Ch. 26 - Prob. 39ECh. 26 - Prob. 40ECh. 26 - Classify the carbon atoms in, a. methylbutane, and...Ch. 26 - Classity the carbon atoms in a....Ch. 26 - Prob. 43ECh. 26 - Draw Newman projections for the staggered and...Ch. 26 - Draw the most stable conformation for the molecule...Ch. 26 - Prob. 46ECh. 26 - Prob. 47ECh. 26 - Prob. 48ECh. 26 - Prob. 49ECh. 26 - Prob. 50ECh. 26 - Prob. 51ECh. 26 - Prob. 52ECh. 26 - Prob. 53ECh. 26 - Prob. 54ECh. 26 - Prob. 55ECh. 26 - Prob. 56ECh. 26 - Draw suitable structural formulas to show that...Ch. 26 - Which of the following pairs of molecules are...Ch. 26 - Prob. 59ECh. 26 - Prob. 60ECh. 26 - Name the following molecules with the appropriate...Ch. 26 - Name the following molecules with the appropriate...Ch. 26 - Name the following molecules with the appropriate...Ch. 26 - Prob. 64ECh. 26 - Draw the structure for each of the following. a....Ch. 26 - Prob. 66ECh. 26 - Prob. 67ECh. 26 - Prob. 68ECh. 26 - Prob. 69ECh. 26 - Prob. 70ECh. 26 - Prob. 71ECh. 26 - Prob. 72ECh. 26 - Prob. 73ECh. 26 - Prob. 74ECh. 26 - Supply condensed or structural formulas for the...Ch. 26 - Prob. 76IAECh. 26 - Prob. 77IAECh. 26 - Prob. 78IAECh. 26 - Prob. 79IAECh. 26 - Prob. 80IAECh. 26 - Combustion of a 0.1908 g sample of a compound gave...Ch. 26 - Prob. 82IAECh. 26 - In the monochiorination of hydrocarbons, a...Ch. 26 - A particular colorless organic liquid is known to...Ch. 26 - Prob. 85IAECh. 26 - Give the systematic names, including any...Ch. 26 - Prob. 87IAECh. 26 - Prob. 88IAECh. 26 - Levomethadyl acetate (shown below) is used in the...Ch. 26 - Thiamphenicol (shown below) is an antibacterial...Ch. 26 - Prob. 91IAECh. 26 - Prob. 92IAECh. 26 - Prob. 93IAECh. 26 - Prob. 94IAECh. 26 - Prob. 95IAECh. 26 - For each of the following molecules (a) draw the...Ch. 26 - Prob. 97FPCh. 26 - Prob. 98SAECh. 26 - Explain the important distinctions between each...Ch. 26 - Describe the characteristics of each of the...Ch. 26 - The compound isoheptane is best represented by the...Ch. 26 - Prob. 102SAECh. 26 - Prob. 103SAECh. 26 - Prob. 104SAECh. 26 - Assign configurations, R or S, to the chiral...Ch. 26 - Consider the following pairs of structures In each...Ch. 26 - Prob. 107SAECh. 26 - Prob. 108SAECh. 26 - Prob. 109SAECh. 26 - Prob. 110SAECh. 26 - Prob. 111SAE
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