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Concept explainers
(a)
Interpretation: Reagents are needed to convert 2-methylpropene
Concept introduction: Dihalocarbenes can be formed from the reaction of chloroform with a strong base. They are electron deficient molecules which can attack an electron rich molecule like
(b)
Interpretation: Reagents are needed to convert 2-methylpropene
Concept introduction: Dihalocarbenes can be formed from the reaction of chloroform with a strong base. They are electron deficient molecules which can attack an electron rich molecule like alkene. The product of this reaction is a cyclopropane substituted alkene.
(c)
Interpretation: Reagents are needed to convert 2-methylpropene
Concept introduction: Dihalocarbenes can be formed from the reaction of chloroform with a strong base. They are electron deficient molecules which can attack an electron rich molecule like alkene. The product of this reaction is a cyclopropane substituted alkene.
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Chapter 26 Solutions
Organic Chemistry
- Draw the organic products formed when cyclopentene is treated withfollowing reagent. [1] LiAlH4; [2] H2Oarrow_forwardDraw the constitutional isomer formed when the attached alkenes are treated with each set of reagents: [1] H2O, H2SO4; or [2] BH3 followed by H2O2, −OH.arrow_forwardDraw the organic products formed when cyclopentene is treated withfollowing reagent. [1] CH3CO3H; [2] H2O, HO−arrow_forward
- Draw the products formed when ethylene oxide is treated with following reagent. [1] HC=C−; [2] H2Oarrow_forwardDraw the products formed when alkene reacts with these reagents: (i) H2 in the presence of Pd catalyst, (ii) HCl.arrow_forwarddraw the two possible carbocations that can form when this alkene reacts with a strong acid (such as HBr or H3O+). of the two structures you drew, circle the more stable carbocationarrow_forward
- (a) Give the IUPAC name for A and B. (b) Draw the product formed when A or B is treated with each reagent: [1] NaBH4, CH3OH; [2] CH3MgBr, then H2O; [3] Ph3P=CHOCH3; [4] CH3CH2CH2NH2, mild acid; [5] HOCH2CH2CH2OH, H+.arrow_forward(a) Give the IUPAC name for A and B. (b) Draw the product formed when A or B is treated with each reagent: [1] NaBH4, CH3OH; [2] CH3MgBr, then H2O; [3] Ph3P = CHOCH3; [4] CH3CH2CH2NH2, mild acid; [5] HOCH2CH2CH2OH, H+.arrow_forward║? What is the structure of the alkene that would produce CH3─ C─ CH2CH3 and H─C─H when treated with ozone and then with zinc and acetic acid? ║ Oarrow_forward
- Draw the products formed when ethylene oxide is treated with following reagent. [1] CH3S−; [2] H2Oarrow_forwardDraw all the alkyl halides with molecular formula C 5H 11Cl formed when pentane (CH 3CH 2CH 2CH 2CH 3) is heated with Cl 2.arrow_forwardA 2-bromobutane react with methanol and form a enantiomeric pair of 2-methoxybutane. Draw the structures of the enntiomeric pairs of ethers.arrow_forward
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