Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 25.7, Problem 8P
Locate the isoprene units in each of the monoterpenes, sesquiterpenes, and diterpenes shown in Figure
Diterpenes:
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Mineral oil and Vaseline are both mixtures of alkanes, but mineral oil is a liquid at room temperature and Vaseline is a solid. Which product is composed of alkanes that contain a larger number of carbon atoms? Explain your choice.
Organic molecules in living things have molecular weights of thousands or millions of atomic mass units (u) and are therefore referred to as:
A) macromolecues B) cyclic monomers C) esters D) kerosenes
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Chapter 25 Solutions
Organic Chemistry - Standalone book
Ch. 25.2 - What fatty acids are produced on hydrolysis of...Ch. 25.3 - Give the structure of the keto acyl-ACP formed...Ch. 25.4 - Prob. 3PCh. 25.4 - Prob. 4PCh. 25.5 - Prob. 5PCh. 25.6 - Write the structural formula and give the IUPAC...Ch. 25.6 - Prob. 7PCh. 25.7 - Locate the isoprene units in each of the...Ch. 25.7 - Prob. 9PCh. 25.9 - Prob. 10P
Ch. 25.9 - Prob. 11PCh. 25.10 - Prob. 12PCh. 25.11 - Prob. 13PCh. 25.11 - Prob. 14PCh. 25.12 - Prob. 15PCh. 25.16 - Prob. 16PCh. 25 - Prob. 17PCh. 25 - Prob. 18PCh. 25 - Prob. 19PCh. 25 - Pyrethrins are a group of naturally occurring...Ch. 25 - Prob. 21PCh. 25 - Prob. 22PCh. 25 - Prob. 23PCh. 25 - Prob. 24PCh. 25 - Prob. 25PCh. 25 - Prob. 26PCh. 25 - Prob. 27PCh. 25 - Prob. 28PCh. 25 - A synthesis of triacylglycerols has been described...Ch. 25 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - Prob. 32PCh. 25 - Prob. 33DSPCh. 25 - Prob. 34DSPCh. 25 - Prob. 35DSPCh. 25 - Prob. 36DSPCh. 25 - Prob. 37DSPCh. 25 - Prob. 38DSP
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- Distinguish between isomerism and resonance. Distinguish between structural and geometric isomerism. When writing the various structural isomers, the most difficult task is identifying which are different isomers and which are identical to a previously written structurethat is, which are compounds that differ only by the rotation of a carbon single bond. How do you distinguish between structural isomers and those that are identical? Alkenes and cycloalkanes are structural isomers of each other. Give an example of each using C4H8. Another common feature of alkenes and cycloalkanes is that both have restricted rotation about one or more bonds in the compound, so both can exhibit cis- trans isomerism. What is required for an alkene or cycloalkane to exhibit cis-trans isomerism? Explain the difference between cis and trans isomers. Alcohols and ethers are structural isomers of each other, as are aldehydes and ketones. Give an example of each to illustrate. Which functional group in Table 21-4 can be structural isomers of carboxylic acids? What is optical isomerism? What do you look for to determine whether an organic compound exhibits optical isomerism? 1-Bromo-1-chloroethane is optically active whereas 1-bromo-2-chloroethane is not optically active. Explain.arrow_forwardWhich of the following cycloalkanes could show geometric isomerism? For each that could, draw structural formulas, and name both the cis- and the trans- isomers. a. c. b. d.arrow_forwardDistinguish precisely, and in scientific terms, the differences among items in each of the following pairs or groups. a Organic chemistry, inorganic chemistry b Saturated and unsaturated hydrocarbons c Alkanes, alkenes, alkynes d Normal alkane, branched alkane e Cis and trans isomers f Structural formula, condensed line formula, molecular formula g Addition reaction, substitution reaction h Alkane, alkyl group i Monomer, polymer j Aliphatic hydrocarbon, aromatic hydrocarbon k Ortho-, meta-, para l Alcohol, aldehyde, carboxylic acid m Hydroxyl group, carbonyl group, carboxyl group n Primary, secondary, tertiary alcohols o Alcohol, ether p Aldehyde, ketone q Carboxylic acid, ester r Carboxylic acid, amide s Amine, amide t Primary, secondary, tertiary amine u Chain-growth polymer, step-growth polymerarrow_forward
- Summarize the nomenclature rules for alkanes, alkenes, alkynes, and aromatic compounds. Correct the following false statements regarding nomenclature of hydrocarbons. a. The root name for a hydrocarbon is based on the shortest continuous chain of carbon atoms. b. The suffix used to name all hydrocarbons is -ane. c. Substituent groups are numbered so as to give the largest numbers possible. d. No number is required to indicate the positions of double or triple bonds in alkenes and alkynes. e. Substituent groups get the lowest number possible in alkenes and alkynes. f. The ortho- term in aromatic hydrocarbons indicates the presence of two substituent groups bonded to carbon- 1 and carbon-3 in benzene.arrow_forwardAlkanes are hydrocarbons containing only single bonds. Acyclic alkanes have carbon atoms arranged in chains, whereas cycloalkanes have carbon atoms arranged in one or more rings. How many hydrogen atoms are in an acyclic alkane with 6 carbon atoms?arrow_forwardBranched compounds are said to have weaker intermolecular forces of attraction. Therefore, between pentane, a straight-chained compound and 2-methylbutanol which exhibits branching at carbon 2, the former has stronger IMFA. (hint: look at the structure of the two molecules) True or Falsearrow_forward
- Draw all structural isomers of C6H12 that are cyclic.arrow_forwardIn the structure of 4-isopropyl-2,4,5-trimethylheptane, identify the primary, secondary, tertiary, and quaternary carbons. Use the abbreviations: p is primary, s is secondary, t is tertiary and q is quarternary.arrow_forwardPetroleum products such as kerosene and gasoline are separated using fractional distillation. Each of them has their own properties and usage. Why can't we use one petroleum product as a substitute for the other when they are composed majority of alkanes?arrow_forward
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Lipids - Fatty Acids, Triglycerides, Phospholipids, Terpenes, Waxes, Eicosanoids; Author: The Organic Chemistry Tutor;https://www.youtube.com/watch?v=7dmoH5dAvpY;License: Standard YouTube License, CC-BY